journal article·2015-12-09

Copper Silicate Hydrate Hollow Spheres Constructed by Nanotubes Encapsulated in Reduced Graphene Oxide as Long-Life Lithium-Ion Battery Anode

Xiujuan Wei, Chunjuan Tang, Xuanpeng Wang, Liang Zhou, Qiulong Wei, Mengyu Yan, Jinzhi Sheng, Ping Hu, Bolun Wang, Liqiang Mai

Publisher page

Abstract

Hierarchical copper silicate hydrate hollow spheres-reduced graphene oxide (RGO) composite is successfully fabricated by a facile hydrothermal method using silica as in situ sacrificing template. The electrochemical performance of the composite as lithium-ion battery anode was studied for the first time. Benefiting from the synergistic effect of the hierarchical hollow structure and conductive RGO matrix, the composite exhibits excellent long-life performance and rate capability. A capacity of 890 mAh/g is achieved after 200 cycles at 200 mA/g and a capacity of 429 mAh/g is retained after 800 cycles at 1000 mA/g. The results indicate that the strategy of combining hierarchical hollow structures with conductive RGO holds the potential in addressing the volume expansion issue of high capacity anode materials.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, Hubei 430070, P. R. China

Department of Mathematics and Physics, Luoyang Institute of Science and Technology, Luoyang, Henan 471023, P. R. China

Funding

Natural Science Foundation of Hubei Province · Ministry of Science and Technology of the People's Republic of China · Natural Science Foundation of Henan Province · Henan Province · National Natural Science Foundation of China · Ministry of Education of the People's Republic of China

References (57)

Show source-provided references
1. 10.1038/451652a10.1038/451652a ↗
2. 10.1038/nature0785310.1038/nature07853 ↗
3. 10.1002/adma.20090332810.1002/adma.200903328 ↗
4. 10.1039/C0EE00281J10.1039/C0EE00281J ↗
5. 10.1021/ja034552410.1021/ja0345524 ↗
6. 10.1039/b919877f10.1039/b919877f ↗
7. 10.1002/ange.20130162210.1002/ange.201301622 ↗
8. 10.1126/science.119562810.1126/science.1195628 ↗
9. 10.1021/ja208346s10.1021/ja208346s ↗
10. 10.1038/nnano.2012.3510.1038/nnano.2012.35 ↗
11. 10.1016/j.jpowsour.2006.09.08410.1016/j.jpowsour.2006.09.084 ↗
12. 10.1002/ange.20080435510.1002/ange.200804355 ↗
13. 10.1038/nnano.2007.41110.1038/nnano.2007.411 ↗
14. 10.1016/j.jpowsour.2008.12.06810.1016/j.jpowsour.2008.12.068 ↗
15. 10.1039/c2jm33855f10.1039/c2jm33855f ↗
16. 10.1021/nn500275d10.1021/nn500275d ↗
17. 10.1039/b816751f10.1039/b816751f ↗
18. 10.1039/c2cc17234h10.1039/c2cc17234h ↗
19. 10.1007/s12274-011-0144-710.1007/s12274-011-0144-7 ↗
20. 10.1039/C4DT01325E10.1039/C4DT01325E ↗
21. 10.1021/am401309c10.1021/am401309c ↗
22. 10.1039/C5TA04680G10.1039/C5TA04680G ↗
23. 10.1039/C4NR04378B10.1039/C4NR04378B ↗
24. 10.1002/anie.20070428710.1002/anie.200704287 ↗
25. 10.1021/nn401059h10.1021/nn401059h ↗
26. 10.1021/acs.jpcc.5b0354010.1021/acs.jpcc.5b03540 ↗
27. 10.1038/nature1145810.1038/nature11458 ↗
28. 10.1021/am300557610.1021/am3005576 ↗
29. 10.1021/nn406156b10.1021/nn406156b ↗
30. 10.1021/nl200658a10.1021/nl200658a ↗
31. 10.1021/nn404713810.1021/nn4047138 ↗
32. 10.1039/c1nr10070j10.1039/c1nr10070j ↗
33. 10.1039/C5TA00621J10.1039/C5TA00621J ↗
34. 10.1002/adma.20120197810.1002/adma.201201978 ↗
35. 10.1126/science.123908910.1126/science.1239089 ↗
36. 10.1038/ncomms552610.1038/ncomms5526 ↗
37. 10.1039/C1EE02426D10.1039/C1EE02426D ↗
38. 10.1039/c2nr30841j10.1039/c2nr30841j ↗
39. 10.1002/anie.20140647610.1002/anie.201406476 ↗
40. 10.1021/nl201470j10.1021/nl201470j ↗
41. 10.1002/adfm.20140017810.1002/adfm.201400178 ↗
42. 10.1039/c3cc43867h10.1039/c3cc43867h ↗
43. 10.1002/adma.20120354710.1002/adma.201203547 ↗
44. 10.1038/ncomms555410.1038/ncomms5554 ↗
45. 10.1021/nl502569410.1021/nl5025694 ↗
46. 10.1002/aenm.20120034610.1002/aenm.201200346 ↗
47. 10.1021/nn100619m10.1021/nn100619m ↗
48. 10.1039/c2ee21380j10.1039/c2ee21380j ↗
49. 10.1016/j.jpowsour.2005.07.05110.1016/j.jpowsour.2005.07.051 ↗
50. 10.1021/nl504427d10.1021/nl504427d ↗
51. 10.1002/adma.20120518510.1002/adma.201205185 ↗
52. 10.1039/C4CP02762K10.1039/C4CP02762K ↗
53. 10.1016/0022-1902(78)80152-310.1016/0022-1902(78)80152-3 ↗
54. 10.1016/0368-2048(78)85029-410.1016/0368-2048(78)85029-4 ↗
55. 10.1002/adma.20120046910.1002/adma.201200469 ↗
56. 10.1021/nn305202310.1021/nn3052023 ↗
57. 10.1021/ja105296a10.1021/ja105296a ↗