Pd NP-Loaded and Covalently Cross-Linked COF Membrane Microreactor for Aqueous CBs Dechlorination at Room Temperature
Source abstract
Abstract
We report an allyl-decorated and hydrazine-connected covalent organic framework (COF-AO, 1), which could support Pd nanoparticles (Pd NPs) to generate Pd@COF-AO, 2. The incorporation of 2 with thiol-functionalized polysiloxane (termed as PSI-SH) via thiol-ene click reaction provided the stand-alone and elastic membrane (3). The obtained COF-involved and Pd NP-loaded covalently linked membrane of 3 is robust, permanently porous, uniform, processable, and water permeable. Moreover, it can be used to construct highly efficient membrane-based microreactor for continuous-flow operation to catalyze chlorobenzenes (CBs) dechlorination in water at room temperature. The provided approach herein allows the processability and practical application of the powdered COF materials to be feasible.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Membrane Separation and Gas Transport
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China
Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, United States
Department of Chemical and Biological Engineering, University at Buffalo (SUNY), Buffalo, New York 14260, United States
Funding
Shandong Province · National Natural Science Foundation of China · Natural Science Foundation of Shandong Province
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