journal article·2016-01-27

A Derivative of the Blatter Radical as a Potential Metal-Free Magnet for Stable Thin Films and Interfaces

F. Ciccullo, N. M. Gallagher, O. Geladari, T. Chassé, A. Rajca, M. B. Casu

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Abstract

Organic radicals are fascinating materials because of their unique properties, which make them suitable for a variety of applications. Their synthesis may be challenging, and big efforts have focused on chemical stability. However, introducing a new material in electronics not only requires chemically stable molecules but also stable monolayers and thin films in view of their use in devices. In this work, we have investigated the thin films of a derivative of the Blatter radical that was synthesized bearing in mind the thermodynamic factors that govern thin film stability. We have proved our concept by investigating the electronic structure, the paramagnetic character, and stability of the obtained films under UHV and ambient conditions by in situ X-ray photoelectron spectroscopy, ex situ atomic force microscopy, and electron paramagnetic resonance spectroscopy.
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Research context

OpenAlex topics: Molecular Junctions and Nanostructures · Organic Light-Emitting Diodes Research · Magnetism in coordination complexes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Physical and Theoretical Chemistry, University of Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany

Department of Chemistry, University of Nebraska, Lincoln, Nebraska 68588-0304, United States

Funding

Division of Chemistry · Deutsche Forschungsgemeinschaft

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