journal article·2021-03-17

One-Step Construction of a Hollow Au@Bimetal–Organic Framework Core–Shell Catalytic Nanoreactor for Selective Alcohol Oxidation Reaction

Nianqiao Qin, An Pan, Jun Yuan, Fei Ke, Xiaoyan Wu, Jing Zhu, Jianqiang Liu, Junfa Zhu

ACS Applied Materials & Interfaces· Volume 13· Issue 10
Publisher page

Abstract

Hollow core-shell catalytic nanoreactors have received tremendous attention due to their high mass transfer in catalysis applications. Herein, we present a novel type of well-arranged, hollow core-shell nanoreactors featured with a bimetallic porous Zn/Ni-MOF-2 shell and a tiny Au nanoparticle core. The well-designed hollow Au@Zn/Ni-MOF-2 nanoreactors were constructed through the strategy of a facile one step from a rare crystal-structure transformation without any additional template. These nanoreactors exhibit outstanding multifunctional catalysis for a broad range of alcohol oxidation under the green oxidant environment. Moreover, such hollow nanoreactors show excellent recyclability toward the selective alcohol oxidation. These findings might provide a promising platform for a general construct of various metal-organic framework-based hollow core-shell nanostructures and further highly augmented catalytic applications.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Catalytic Processes in Materials Science · Advanced Nanomaterials in Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Applied Chemistry and State Key Laboratory of Tea Plant Biology and Utilization, Anhui Agricultural University, Hefei 230036, P. R. China

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy, Guangdong Medical University, Dongguan 523808, P. R. China

National Synchrotron Radiation Laboratory and Department of Chemical Physics, University of Science and Technology of China, Hefei 230029, P. R. China

Funding

Ministry of Education of the People's Republic of China · Anhui Agriculture University · National Natural Science Foundation of China · State Key Laboratory of Tea Plant Biology and Utilization · DNL Cooperation Fund, Chinese Academy of Sciences

References (50)

Show source-provided references
1. 10.1021/acs.chemrev.8b0072610.1021/acs.chemrev.8b00726 ↗
2. 10.1016/j.jechem.2019.07.01410.1016/j.jechem.2019.07.014 ↗
3. 10.1039/c5nr00246j10.1039/c5nr00246j ↗
4. 10.1021/acs.chemrev.9b0055110.1021/acs.chemrev.9b00551 ↗
5. 10.1021/ja810045y10.1021/ja810045y ↗
6. 10.1021/cs300252g10.1021/cs300252g ↗
7. 10.1021/cs501010x10.1021/cs501010x ↗
8. 10.1039/c2cc33964a10.1039/c2cc33964a ↗
9. 10.1007/s10562-019-02949-710.1007/s10562-019-02949-7 ↗
10. 10.1021/acsami.8b1238010.1021/acsami.8b12380 ↗
11. 10.1021/acs.chemmater.9b0207010.1021/acs.chemmater.9b02070 ↗
12. 10.1002/anie.20140648410.1002/anie.201406484 ↗
13. 10.1021/jacs.8b0510710.1021/jacs.8b05107 ↗
14. 10.1039/c6cs00537c10.1039/c6cs00537c ↗
15. 10.1039/c3cs60472a10.1039/c3cs60472a ↗
16. 10.1039/c9ta07022b10.1039/c9ta07022b ↗
17. 10.1021/jacs.8b0458210.1021/jacs.8b04582 ↗
18. 10.1016/j.chemosphere.2020.12810110.1016/j.chemosphere.2020.128101 ↗
19. 10.1002/adma.20170736510.1002/adma.201707365 ↗
20. 10.1039/d0dt01882a10.1039/d0dt01882a ↗
21. 10.1002/adma.20170366310.1002/adma.201703663 ↗
22. 10.1039/c4sc01847h10.1039/c4sc01847h ↗
23. 10.1016/j.ccr.2019.03.00510.1016/j.ccr.2019.03.005 ↗
24. 10.1002/adma.20180490310.1002/adma.201804903 ↗
25. 10.1002/anie.20171160010.1002/anie.201711600 ↗
26. 10.1016/j.cej.2019.02.09610.1016/j.cej.2019.02.096 ↗
27. 10.1039/c5nr06532a10.1039/c5nr06532a ↗
28. 10.1002/anie.20170160410.1002/anie.201701604 ↗
29. 10.1021/jacs.9b0241710.1021/jacs.9b02417 ↗
30. 10.1002/adma.20130278110.1002/adma.201302781 ↗
31. 10.1021/cs501266210.1021/cs5012662 ↗
32. 10.1002/anie.20181282710.1002/anie.201812827 ↗
33. 10.1021/cm403431910.1021/cm4034319 ↗
34. 10.1002/smll.20170139510.1002/smll.201701395 ↗
35. 10.1016/s1872-2067(19)63429-710.1016/s1872-2067(19)63429-7 ↗
36. 10.1002/anie.20120990310.1002/anie.201209903 ↗
37. 10.1002/adfm.20080156610.1002/adfm.200801566 ↗
38. 10.1038/nchem.127210.1038/nchem.1272 ↗
39. 10.1021/jacs.6b0595710.1021/jacs.6b05957 ↗
40. 10.1038/4624810.1038/46248 ↗
41. 10.1038/srep0092110.1038/srep00921 ↗
42. 10.1039/c2ce25694k10.1039/c2ce25694k ↗
43. 10.1021/acscatal.7b0327010.1021/acscatal.7b03270 ↗
44. 10.1021/acsami.9b1531110.1021/acsami.9b15311 ↗
45. 10.1021/acs.chemrev.5b0073110.1021/acs.chemrev.5b00731 ↗
46. 10.1021/acs.chemrev.0c0023710.1021/acs.chemrev.0c00237 ↗
47. 10.1039/c9cp05992j10.1039/c9cp05992j ↗
48. 10.1016/j.jtice.2019.06.02110.1016/j.jtice.2019.06.021 ↗
49. 10.1016/j.jcat.2012.11.01810.1016/j.jcat.2012.11.018 ↗
50. 10.1039/b509003b10.1039/b509003b ↗