DataVXACS Applied Materials & InterfacesPaper
journal article·2020-02-12

Versatile Strategy for Realizing Flexible Room-Temperature All-Solid-State Battery through a Synergistic Combination of Salt Affluent PEO and Li6.75La3Zr1.75Ta0.25O12 Nanofibers

Rong Fan, Chen Liu, Kangqiang He, Samson Ho-Sum Cheng, Dazhu Chen, Chengzhu Liao, Robert K. Y. Li, Jiaoning Tang, Zhouguang Lu

ACS Applied Materials & Interfaces· Volume 12· Issue 6
Publisher page
Source abstract

Abstract

All-solid-state lithium metal batteries are highly attractive because of their high energy density and inherent safety. However, it is still a great challenge to design the solid electrolytes with high ionic conductivity at room temperature and good electrode/electrolyte interfacial compatibility simultaneously in a facile and scalable way. In this work, for the first time, the combination of salt affluent Poly(ethylene oxide) with Li6.75La3Zr1.75Ta0.25O12 nanofibers was designed and intensively evaluated. The synergistic effect of each component in the electrolyte enhances the ionic conductivity to 2.13 × 10–4 S cm–1 at 25 °C and exhibits a high transference number of 0.57. The composite electrolyte possesses superior interfacial stability against Li metal for over 680 h in Li symmetric cells even at a relatively high current density of 2 mA cm–2. The all-solid-state batteries employing the solid electrolytes exhibit excellent cycling stability at room temperature and superior safety performance. This work proposes a brand-new strategy to design and fabricate solid electrolytes in a versatile way for room-temperature all-solid-state batteries.
Source: openalex_inverted_index · Quality: baseline

Research context

Energy storageNanomaterialsComposites

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, PR China

Department of Materials Science and Engineering, City University of Hong Kong, Kowloon, Hong Kong, PR China

Department of Materials Science and Engineering, Shenzhen Key Laboratory of Solid State Batteries, Guangdong Provincial Key Laboratory of Energy Materials for Electric Power, Southern University of Science and Technology, Shenzhen 518055, PR China

Funding

Ministry of Education of the People's Republic of China · Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Shenzhen University · Guangdong Provincial Key Laboratory of Energy Materials for Electric Power, Southern University of Science and Technology · Shenzhen Science and Technology Innovation Committee · Shenzhen Key Laboratory of Solid State Batteries, Southern University of Science and Technology

References (49)

Show source-provided references
1. 10.1038/natrevmats.2016.10310.1038/natrevmats.2016.103 ↗
2. 10.1016/j.jpowsour.2018.04.02210.1016/j.jpowsour.2018.04.022 ↗
3. 10.1016/j.nanoen.2018.10.03510.1016/j.nanoen.2018.10.035 ↗
4. 10.1016/J.ENSM.2016.07.00310.1016/J.ENSM.2016.07.003 ↗
5. 10.1021/acs.chemrev.5b0056310.1021/acs.chemrev.5b00563 ↗
6. 10.1021/acsami.8b0467210.1021/acsami.8b04672 ↗
7. 10.1002/anie.20150222810.1002/anie.201502228 ↗
8. 10.1016/J.NANOEN.2017.01.02810.1016/J.NANOEN.2017.01.028 ↗
9. 10.1016/J.PROGPOLYMSCI.2017.12.00410.1016/J.PROGPOLYMSCI.2017.12.004 ↗
10. 10.1002/anie.20171084110.1002/anie.201710841 ↗
11. 10.1021/acs.nanolett.8b0142110.1021/acs.nanolett.8b01421 ↗
12. 10.1039/C6TA02621D10.1039/C6TA02621D ↗
13. 10.1039/C7TA07741F10.1039/C7TA07741F ↗
14. 10.1002/aenm.20170123110.1002/aenm.201701231 ↗
15. 10.1021/acsami.7b0251410.1021/acsami.7b02514 ↗
16. 10.1038/362137a010.1038/362137a0 ↗
17. 10.1021/JP049195D10.1021/JP049195D ↗
18. 10.1016/j.ensm.2018.03.01510.1016/j.ensm.2018.03.015 ↗
19. 10.1149/2.0531610jes10.1149/2.0531610jes ↗
20. 10.1016/0013-4686(95)00202-p10.1016/0013-4686(95)00202-p ↗
21. 10.1016/j.electacta.2004.01.09510.1016/j.electacta.2004.01.095 ↗
22. 10.1016/S0167-2738(98)00166-010.1016/S0167-2738(98)00166-0 ↗
23. 10.1038/ncomms251310.1038/ncomms2513 ↗
24. 10.1016/S0167-2738(98)00506-210.1016/S0167-2738(98)00506-2 ↗
25. 10.1021/ja502133j10.1021/ja502133j ↗
26. 10.1021/acs.chemrev.7b0011510.1021/acs.chemrev.7b00115 ↗
27. 10.1016/J.NANOEN.2018.07.03610.1016/J.NANOEN.2018.07.036 ↗
28. 10.1016/J.ELECTACTA.2017.08.16210.1016/J.ELECTACTA.2017.08.162 ↗
29. 10.1016/J.NANOEN.2017.12.03710.1016/J.NANOEN.2017.12.037 ↗
30. 10.1021/acs.inorgchem.5b0282110.1021/acs.inorgchem.5b02821 ↗
31. 10.1002/cssc.20130010510.1002/cssc.201300105 ↗
32. 10.1016/j.compscitech.2019.02.03010.1016/j.compscitech.2019.02.030 ↗
33. 10.1021/acs.nanolett.5b0060010.1021/acs.nanolett.5b00600 ↗
34. 10.1021/acsami.7b0380610.1021/acsami.7b03806 ↗
35. 10.1021/acsami.8b0665810.1021/acsami.8b06658 ↗
36. 10.1021/acsami.7b1812310.1021/acsami.7b18123 ↗
37. 10.1073/pnas.160042211310.1073/pnas.1600422113 ↗
38. 10.1039/C7TA10517G10.1039/C7TA10517G ↗
39. 10.1016/j.compscitech.2019.10786310.1016/j.compscitech.2019.107863 ↗
40. 10.1016/J.ELECTACTA.2016.12.17210.1016/J.ELECTACTA.2016.12.172 ↗
41. 10.1021/cm401232r10.1021/cm401232r ↗
42. 10.1039/c5ta04902d10.1039/c5ta04902d ↗
43. 10.1039/c3ta11996c10.1039/c3ta11996c ↗
44. 10.1021/acs.chemmater.6b0003810.1021/acs.chemmater.6b00038 ↗
45. 10.1021/acs.jpcc.5b0358910.1021/acs.jpcc.5b03589 ↗
46. 10.1038/ncomms349110.1038/ncomms3491 ↗
47. 10.1149/2.0381712jes10.1149/2.0381712jes ↗
48. 10.1038/nenergy.2017.3510.1038/nenergy.2017.35 ↗
49. 10.1038/nenergy.2016.11410.1038/nenergy.2016.114 ↗