Effect of Few-Layer Ti₃C₂T_x Supported Nano-Ni via Self-Assembly Reduction on Hydrogen Storage Performance of MgH₂

For the first time, few-layer Ti3C2Tx (FL-Ti3C2Tx) supporting highly dispersed nano-Ni particles with an interconnected and interlaced structure was elaborated through a self-assembly reduction process. FL-Ti3C2Tx not only acts as a supporting material but also self-assembles with Ni2+ ions through the electrostatic interaction, assisting in the reduction of nano-Ni. After ball milling with MgH2, Ni30/FL-Ti3C2Tx (few-layer Ti3C2Tx supported 30 wt % nano-Ni via self-assembly reduction) shows superior catalytic activity for MgH2. For example, MgH2-5 wt % Ni30/FL-Ti3C2Tx can release approximately 5.83 wt % hydrogen within 1800 s at 250 °C and absorb 5 wt % hydrogen within 1700 s at 100 °C. The combined effects of finely dispersed nano-Ni in situ-grown on FL-Ti3C2Tx, large specific area of FL-Ti3C2Tx, multiple-valence Ti (Ti4+, Ti3+, Ti2+, and Ti0) derived from FL-Ti3C2Tx, and the electronic interaction between Ni and FL-Ti3C2Tx can explain the superb hydrogen storage performance. Our results will attract more attention to the elaboration of the metal/FL-Ti3C2Tx composite via self-assembly reduction and provide a guideline to design high-efficiency composite catalysts with MXene in hydrogen storage fields.