DataVXACS Applied Materials & InterfacesPaper
journal article·2017-05-24Open access

Sn Nanoparticles Encapsulated in 3D Nanoporous Carbon Derived from a Metal–Organic Framework for Anode Material in Lithium-Ion Batteries

Yuanyuan Guo, Xiaoqiao Zeng, Yu Zhang, Zhengfei Dai, Haosen Fan, Ying Huang, Weina Zhang, Hua Zhang, Jun Lu, Fengwei Huo, Qingyu Yan

ACS Applied Materials & Interfaces· Volume 9· Issue 20
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Source abstract

Abstract

Three-dimensional nanoporous carbon frameworks encapsulated Sn nanoparticles (Sn@3D-NPC) are developed by a facile method as an improved lithium ion battery anode. The Sn@3D-NPC delivers a reversible capacity of 740 mAh g –1 after 200 cycles at a current density of 200 mA g –1, corresponding to a capacity retention of 85% (against the second capacity) and high rate capability (300 mAh g –1 at 5 A g –1 ). Compared to the Sn nanoparticles (SnNPs), such improvements are attributed to the 3D porous and conductive framework. The whole structure can provide not only the high electrical conductivity that facilities the electron transfer but also the elasticity that will suppress the volume expansion and aggregation of SnNPs during the charge and discharge process. This work opens a new application of metal–organic frameworks in energy storage.
Source: openalex_inverted_index · Quality: baseline

Research context

Energy storageNanomaterials

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Extraction and Separation Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439, United States

Key Laboratory of Flexible Electronics & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211816, P. R. China

Funding

Ministry of Science and Technology of the People's Republic of China · Ministry of Education - Singapore · Natural Science Foundation of Jiangsu Province · Vehicle Technologies Program · U.S. Department of Energy · National Natural Science Foundation of China · Science and Engineering Research Council · Central Committee of the Communist Party of China · Jiangsu Province

References (51)

Show source-provided references
1. 10.1021/ar800229g10.1021/ar800229g ↗
2. 10.1021/ar300094m10.1021/ar300094m ↗
3. 10.1038/nmat136810.1038/nmat1368 ↗
4. 10.1039/c0ee00699h10.1039/c0ee00699h ↗
5. 10.1021/acsnano.6b0651710.1021/acsnano.6b06517 ↗
6. 10.1016/j.nanoen.2016.07.00610.1016/j.nanoen.2016.07.006 ↗
7. 10.1002/adma.20170052310.1002/adma.201700523 ↗
8. 10.1021/ja312604r10.1021/ja312604r ↗
9. 10.1002/adma.20070136410.1002/adma.200701364 ↗
10. 10.1016/j.jpowsour.2006.09.08410.1016/j.jpowsour.2006.09.084 ↗
11. 10.1002/adma.20070074810.1002/adma.200700748 ↗
12. 10.1021/nl072715710.1021/nl0727157 ↗
13. 10.1016/S0378-7753(00)00576-010.1016/S0378-7753(00)00576-0 ↗
14. 10.1007/s10008-010-1256-910.1007/s10008-010-1256-9 ↗
15. 10.1016/j.carbon.2011.12.04010.1016/j.carbon.2011.12.040 ↗
16. 10.1021/cm048137210.1021/cm0481372 ↗
17. 10.1021/ja906261c10.1021/ja906261c ↗
18. 10.1021/nl403631h10.1021/nl403631h ↗
19. 10.1021/nn406105n10.1021/nn406105n ↗
20. 10.1002/aenm.20110038010.1002/aenm.201100380 ↗
21. 10.1021/nl303823k10.1021/nl303823k ↗
22. 10.1039/c1ee01592c10.1039/c1ee01592c ↗
23. 10.1039/C6TA02284G10.1039/C6TA02284G ↗
24. 10.1016/j.nanoen.2014.06.03010.1016/j.nanoen.2014.06.030 ↗
25. 10.1016/j.jpowsour.2014.10.00810.1016/j.jpowsour.2014.10.008 ↗
26. 10.1002/adma.20120019710.1002/adma.201200197 ↗
27. 10.1016/j.jpowsour.2012.02.01310.1016/j.jpowsour.2012.02.013 ↗
28. 10.1002/adfm.20060073910.1002/adfm.200600739 ↗
29. 10.1039/b200393g10.1039/b200393g ↗
30. 10.1126/science.119216010.1126/science.1192160 ↗
31. 10.1016/j.micromeso.2004.03.03410.1016/j.micromeso.2004.03.034 ↗
32. 10.1038/nchem.127210.1038/nchem.1272 ↗
33. 10.1021/ja307475c10.1021/ja307475c ↗
34. 10.1002/adma.20140232210.1002/adma.201402322 ↗
35. 10.1002/ange.20130162210.1002/ange.201301622 ↗
36. 10.1039/c3cc38009b10.1039/c3cc38009b ↗
37. 10.1021/ja710614610.1021/ja7106146 ↗
38. 10.1016/j.carbon.2009.09.06110.1016/j.carbon.2009.09.061 ↗
39. 10.1021/ja401869h10.1021/ja401869h ↗
40. 10.1021/nl302618s10.1021/nl302618s ↗
41. 10.1021/ja311550t10.1021/ja311550t ↗
42. 10.1002/smll.20130291010.1002/smll.201302910 ↗
43. 10.1021/ja511539a10.1021/ja511539a ↗
44. 10.1021/cm070997610.1021/cm0709976 ↗
45. 10.1016/j.elecom.2004.03.00910.1016/j.elecom.2004.03.009 ↗
46. 10.1016/j.electacta.2007.04.10010.1016/j.electacta.2007.04.100 ↗
47. 10.1002/adma.20150231510.1002/adma.201502315 ↗
48. 10.1021/ja508412810.1021/ja5084128 ↗
49. 10.1039/c3nr05523j10.1039/c3nr05523j ↗
50. 10.1002/aenm.20120034610.1002/aenm.201200346 ↗
51. 10.1002/smll.20130352010.1002/smll.201303520 ↗