journal article·2015-05-27

Core–Shell Polymeric Microcapsules with Superior Thermal and Solvent Stability

Sen Kang, Marta Baginska, Scott R. White, Nancy R. Sottos

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Abstract

A protective polydopamine (PDA) coating is applied to core-shell microcapsule surfaces by the polymerization of dopamine monomers. A neutral aqueous solution and the addition of an oxidant (i.e., ammonium persulfate) are crucial for microcapsule survival and the initiation of PDA polymerization, respectively. The resulting PDA coating is a dense and uniform layer approximately 50 nm thick. The PDA protective coating significantly increases capsule stability at an elevated temperature (180 °C) and in a variety of organic solvents and acidic/basic solutions that otherwise lead to deflation and loss of the core content of uncoated microcapsules.
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Research context

OpenAlex topics: Polymer composites and self-healing · Advanced Polymer Synthesis and Characterization · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beckman Institute for Advanced Science and Technology, Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States

Beckman Institute for Advanced Science and Technology, Department of Aerospace Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States

Funding

Basic Energy Sciences

References (21)

Show source-provided references
1. Blaiszik B. J. · Annu. Rev. Mater. Res. · 2010 · 40 · 17910.1146/annurev-matsci-070909-104532 ↗
2. White S. R. · Nature · 2001 · 409 · 79410.1038/35057232 ↗
3. Esser-Kahn A. P. · Macromolecules · 2011 · 44 · 553910.1021/ma201014n ↗
4. Jones A. R. · Compos. Sci. Technol. · 2013 · 79 · 110.1016/j.compscitech.2013.02.007 ↗
5. Cho S. H. · Adv. Mater. · 2009 · 21 · 64510.1002/adma.200802008 ↗
6. Yuan Y. C. · Macromolecules · 2008 · 41 · 519710.1021/ma800028d ↗
7. Patel A. J. · Composites, Part A · 2010 · 41 · 36010.1016/j.compositesa.2009.11.002 ↗
8. Jin H. · Polymer · 2012 · 53 · 58110.1016/j.polymer.2011.12.005 ↗
9. Jin H. · Adv. Mater. (Weinheim, Ger.) · 2014 · 26 · 28210.1002/adma.201303179 ↗
10. Yuan L. · Mater. Chem. Phys. · 2008 · 110 · 41710.1016/j.matchemphys.2008.02.035 ↗
11. Li G. · Polym. Bull. · 2008 · 60 · 72510.1007/s00289-008-0894-x ↗
12. Caruso M. M. · ACS Appl. Mater. Interfaces · 2010 · 2 · 119510.1021/am100084k ↗
13. Jackson A. C. · Macromol. Rapid Commun. · 2011 · 32 · 8210.1002/marc.201000468 ↗
14. Lee H. · Science · 2007 · 318 · 42610.1126/science.1147241 ↗
15. Ryou M. H. · Adv. Mater. · 2013 · 25 · 157110.1002/adma.201203981 ↗
16. Dreyer D. R. · Chem. Sci. · 2013 · 4 · 379610.1039/c3sc51501j ↗
17. Dreyer D. R. · Langmuir · 2012 · 28 · 642810.1021/la204831b ↗
18. Blaiszik B. J. · Polymer · 2009 · 50 · 99010.1016/j.polymer.2008.12.040 ↗
19. Wei Q. · Polym. Chem. · 2010 · 1 · 143010.1039/c0py00215a ↗
20. Luo R. · Colloids Surf., B · 2013 · 106 · 6610.1016/j.colsurfb.2013.01.033 ↗
21. Müller M. · Langmuir · 2011 · 27 · 1249910.1021/la202908b ↗