journal article·2013-08-14

Efficient Plasma Route to Nanostructure Materials: Case Study on the Use of m-WO3 for Solar Water Splitting

Moreno de Respinis, Gregory De Temmerman, Irem Tanyeli, Mauritius C.M. van de Sanden, Russ P. Doerner, Matthew J. Baldwin, Roel van de Krol

Publisher page

Abstract

One of the main challenges in developing highly efficient nanostructured photoelectrodes is to achieve good control over the desired morphology and good electrical conductivity. We present an efficient plasma-processing technique to form porous structures in tungsten substrates. After an optimized two-step annealling procedure, the mesoporous tungsten transforms into photoactive monoclinic WO3. The excellent control over the feature size and good contact between the crystallites obtained with the plasma technique offers an exciting new synthesis route for nanostructured materials for use in processes such as solar water splitting.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Transition Metal Oxide Nanomaterials · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Applied Sciences, Department of Chemical Engineering, Materials for Energy Conversion and Storage, Delft University of Technology, P.O. Box 5045, 2600 GA Delft, The Netherlands

FOM-Institute DIFFER, Dutch Institute For Fundamental Energy Research, P. O. Box 1207, 3430 BE Nieuwegein, The Netherlands

Center for Energy Research, University of California at San Diego, 9500 Gilman Drive, La Jolla, California, United States

Institute for Solar Fuels, Helmholtz-Zentrum Berlin für Materialien und Energie Gmbh, Hahn-Meitner-Platz 1, 14109 Berlin, Germany

References (43)

Show source-provided references
1. Lewis N. S. · Proc. Natl. Acad. Sci. U.S.A. · 2006 · 103 · 1572910.1073/pnas.0603395103 ↗
2. Van de Krol R. · 201210.1007/978-1-4614-1380-6 ↗
3. Chen X. · Chem. Rev. · 2010 · 110 · 650310.1021/cr1001645 ↗
4. Zou Z. · Nature · 2001 · 414 · 62510.1038/414625a ↗
5. Alexander B. D. · J. Mater. Chem. · 2008 · 18 · 229810.1039/b718644d ↗
6. Van de Krol R. · J. Mater. Chem. · 2008 · 18 · 231110.1039/b718969a ↗
7. Thomann I. · Nano Lett. · 2011 · 11 · 344010.1021/nl201908s ↗
8. Abe R. · J. Am. Chem. Soc. · 2010 · 132 · 1182810.1021/ja1016552 ↗
9. Baldwin M. J. · Nucl. Fusion · 2008 · 48 · 035001-110.1088/0029-5515/48/3/035001 ↗
10. De Temmerman G. · J. Vac. Sci. Technol., A · 2012 · 30 · 041306-110.1116/1.4731196 ↗
11. Kajita S. · Appl. Phys. Express · 2010 · 3 · 085204-110.1143/APEX.3.085204 ↗
12. Butler M. A. · J. Appl. Phys. · 1977 · 48 · 191410.1063/1.323948 ↗
13. Chen X. · ACS Nano · 2011 · 5 · 431010.1021/nn200100v ↗
14. Santato C. · J. Phys. Chem. B · 2001 · 105 · 93610.1021/jp002232q ↗
15. Santato C. · Adv. Mater. · 2001 · 13 · 51110.1002/1521-4095(200104)13:7<511::AID-ADMA511>3.0.CO;2-W ↗
16. Santato C. · J. Am. Chem. Soc. · 2001 · 123 · 1063910.1021/ja011315x ↗
17. Berger S. · Appl. Phys. Lett. · 2006 · 88 · 20311910.1063/1.2206696 ↗
18. Hsiao P.-T. · J. Mater. Chem. · 2011 · 21 · 1940210.1039/c1jm14785d ↗
19. Qin D.-D. · Chem. Commun. · 2012 · 48 · 72910.1039/C1CC15691H ↗
20. Hong S. J. · Int. J. Hydrogen Energy · 2009 · 34 · 323410.1016/j.ijhydene.2009.02.006 ↗
21. Baeck S. H. · Nano Lett. · 2002 · 2 · 83110.1021/nl025587p ↗
22. Vemuri R. S. · ACS Appl. Mater. Interfaces · 2012 · 4 · 137110.1021/am2016409 ↗
23. Gissler W. · J. Electrochem. Soc. · 1977 · 124 · 171010.1149/1.2133141 ↗
24. Gu G. · Nano Lett. · 2002 · 2 · 84910.1021/nl025618g ↗
25. Spichiger-Ulmann M. · J. Appl. Phys. · 1983 · 54 · 606110.1063/1.331756 ↗
26. Cifuentes S. C. · Corros. Sci. · 2012 · 57 · 11410.1016/j.corsci.2011.12.027 ↗
27. Van Rooij G. J. · Appl. Phys. Lett. · 2007 · 90 · 121501-110.1063/1.2716208 ↗
28. Krashenninikov S. I. · Phys. Scr. · 2011 · 145 · 014040-1
29. Al Mohammad A. · Thin Solid Films · 2002 · 408 · 30210.1016/S0040-6090(02)00090-1 ↗
30. Granqvist C. G. · Sol. Energy Mater. Sol. Cells · 2000 · 60 · 20110.1016/S0927-0248(99)00088-4 ↗
31. Sato R. · Appl. Surf. Sci. · 2008 · 254 · 767610.1016/j.apsusc.2008.01.161 ↗
32. Wriedt H. A. · Bull. Alloy Phase Diagrams · 1989 · 10 · 36810.1007/BF02877593 ↗
33. Migas D. B. · J. Appl. Phys. · 2010 · 108 · 093713-1
34. Sikka V. K. · Corros. Sci. · 1980 · 20 · 120110.1016/0010-938X(80)90092-X ↗
35. Murphy A. B. · Sol. Energy Mater. Sol. Cells · 2007 · 91 · 132610.1016/j.solmat.2007.05.005 ↗
36. Lopez R. · J. Sol-Gel Sci. Technol. · 2012 · 61 · 110.1007/s10971-011-2582-9 ↗
37. González-Borrero P. P. · Appl. Phys. Lett. · 2010 · 96 · 061909-110.1063/1.3313945 ↗
38. Liu X. · Phys. Chem. Chem. Phys. · 2012 · 14 · 789410.1039/c2cp40976c ↗
39. Ahn K.-S. · J. Appl. Phys. · 2007 · 101 · 093524-1
40. Mi Q. · Energy Environ. Sci. · 2012 · 5 · 569410.1039/c2ee02929d ↗
41. Kajita S. · J. Nucl. Mater. · 2012 · 421 · 2210.1016/j.jnucmat.2011.11.044 ↗
42. Yajimaa M. · J. Nucl. Mater. · 2013 · 438 · S114210.1016/j.jnucmat.2013.01.252 ↗
43. Bange K. · Sol. Energy Mater. Sol. Cells · 1999 · 58 · 110.1016/S0927-0248(98)00196-2 ↗