Kinetic Study of Parasitic Reactions in Lithium-Ion Batteries: A Case Study on LiNi_{0.6}Mn_{0.2}Co_{0.2}O₂

Xiaoqiao Zeng; Gui-Liang Xu; Yan Li; Xiangyi Luo; Filippo Maglia; Christoph Bauer; Simon Franz Lux; Odysseas Paschos; Sung-Jin Kim; Peter Lamp; Jun Lu; Khalil Amine; Zonghai Chen

doi:10.1021/acsami.5b11800

journal article·2016-02-10

Kinetic Study of Parasitic Reactions in Lithium-Ion Batteries: A Case Study on LiNi_0.6Mn_0.2Co_0.2O₂

Xiaoqiao Zeng, Gui-Liang Xu, Yan Li, Xiangyi Luo, Filippo Maglia, Christoph Bauer, Simon Franz Lux, Odysseas Paschos, Sung-Jin Kim, Peter Lamp, Jun Lu, Khalil Amine, Zonghai Chen

ACS Applied Materials & Interfaces· Volume 8· Issue 5

Publisher page

Source abstract

Abstract

The side reactions between the electrode materials and the nonaqueous electrolytes have been the major contributor to the degradation of electrochemical performance of lithium-ion batteries. A home-built high-precision leakage current measuring system was deployed to investigate the reaction kinetics between the delithiated LiNi(0.6)Mn(0.2)Co(0.2)O2 and a conventional nonaqueous electrolyte. It was found that the rate of parasitic reaction had strong dependence on the upper cutoff potential of the cathode material. The kinetic data also indicated a change of reaction mode at about 4.5 V vs Li(+)/Li.

Source: openalex_inverted_index · Quality: baseline

Research context

Energy storage

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Technologies Research · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States

Materials Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States

BMW Group, Petuelring 130, 80788 Munich, Germany

BMW Group Technology Office, 2606 Bayshore Parkway, Mountain View, California 94043, United States

Funding

Basic Energy Sciences · Office of Science · Bayerische Motoren Werke AG

References (45)

Show source-provided references

1. 10.1038/nmat241810.1038/nmat2418 ↗

2. 10.1038/3510464410.1038/35104644 ↗

3. 10.1016/j.nanoen.2012.04.00110.1016/j.nanoen.2012.04.001 ↗

4. 10.1002/anie.20110500610.1002/anie.201105006 ↗

5. 10.1126/science.121274110.1126/science.1212741 ↗

6. 10.1039/c1ee01388b10.1039/c1ee01388b ↗

7. 10.1038/451652a10.1038/451652a ↗

8. 10.1039/C5TA00361J10.1039/C5TA00361J ↗

9. 10.1016/j.mattod.2014.10.04010.1016/j.mattod.2014.10.040 ↗

10. 10.1016/S0378-7753(01)00887-410.1016/S0378-7753(01)00887-4 ↗

11. 10.1038/3503504510.1038/35035045 ↗

12. 10.1016/j.nanoen.2013.05.01310.1016/j.nanoen.2013.05.013 ↗

13. 10.1021/cr020731c10.1021/cr020731c ↗

14. 10.1002/anie.20070250510.1002/anie.200702505 ↗

15. 10.1016/j.nantod.2010.11.00210.1016/j.nantod.2010.11.002 ↗

16. 10.1039/c2ee21892e10.1039/c2ee21892e ↗

17. 10.1016/S0378-7753(00)00431-610.1016/S0378-7753(00)00431-6 ↗

18. 10.1016/j.elecom.2007.07.03310.1016/j.elecom.2007.07.033 ↗

19. 10.1126/science.112215210.1126/science.1122152 ↗

20. 10.1002/adfm.20080109510.1002/adfm.200801095 ↗

21. 10.1016/j.nanoen.2013.12.00110.1016/j.nanoen.2013.12.001 ↗

22. 10.1016/j.nanoen.2013.06.00610.1016/j.nanoen.2013.06.006 ↗

23. 10.1016/S0378-7753(96)02547-510.1016/S0378-7753(96)02547-5 ↗

24. 10.1002/adma.20070062110.1002/adma.200700621 ↗

25. 10.1063/1.292937310.1063/1.2929373 ↗

26. Zhang W. J. · J. Power Sources · 2011 · 6 · 2963

27. 10.1016/j.nanoen.2014.03.01310.1016/j.nanoen.2014.03.013 ↗

28. 10.1016/j.jpowsour.2013.09.06410.1016/j.jpowsour.2013.09.064 ↗

29. 10.1016/j.nanoen.2015.01.00310.1016/j.nanoen.2015.01.003 ↗

30. 10.1021/acs.jpclett.5b0172710.1021/acs.jpclett.5b01727 ↗

31. 10.1016/j.elecom.2005.12.00710.1016/j.elecom.2005.12.007 ↗

32. 10.1149/1.278377010.1149/1.2783770 ↗

33. 10.1038/nnano.2010.11610.1038/nnano.2010.116 ↗

34. 10.1016/j.jpowsour.2003.09.00810.1016/j.jpowsour.2003.09.008 ↗

35. 10.1016/S0378-7753(01)00646-210.1016/S0378-7753(01)00646-2 ↗

36. Monconduit, L.; Croguennec, L.; Dedryvère, R.Electrodes for Li-ion Batteries: Materials, Mechanisms and Performance;John Wiley & Sons:Chichester, U. K., 2015; pp47.10.1002/9781119007364 ↗

37. 10.1016/j.jpowsour.2010.11.06410.1016/j.jpowsour.2010.11.064 ↗

38. 10.1016/j.electacta.2005.06.03310.1016/j.electacta.2005.06.033 ↗

39. 10.1021/cr020730k10.1021/cr020730k ↗

40. 10.1149/1.183885710.1149/1.1838857 ↗

41. 10.1039/c1ee01131f10.1039/c1ee01131f ↗

42. 10.1021/ja206268a10.1021/ja206268a ↗

43. 10.1149/1.342851510.1149/1.3428515 ↗

44. 10.1016/j.jpowsour.2005.12.00210.1016/j.jpowsour.2005.12.002 ↗

45. 10.1016/j.nanoen.2015.11.03110.1016/j.nanoen.2015.11.031 ↗