Biodegradable Gel Electrolyte Suppressing Water-Induced Issues for Long-Life Zinc Metal Anodes

Owing to the inherent properties of aqueous electrolytes, aqueous zinc-ion batteries are considered to be a promising energy storage system. Unfortunately, the water-induced issues, such as hydrogen evolution and corrosion reaction, inevitably occur on the Zn anode surface during cycling, which leads to poor electrochemical performance. The gel polymer electrolyte would reduce the parasitic reactions associated with water. However, the nondegradable polymer is harmful to the environment. Herein, with the aim to alleviate the serious issues derived from water and environmental problems, a biodegradable gum arabic has been proposed to serve as a hydrogel electrolyte for aqueous zinc-ion batteries. The electrochemical activity of water could be reduced by the hydrogen-bond network between the gum arabic and water. Thus, the corrosion and hydrogen evolution reaction (HER) can be restrained by employing the prepared gel electrolyte. Evidenced by the online mass spectrometry, it is found that the less produced H2 is detected in the biodegradable gel electrolyte-based Zn||Zn symmetric cell during the processes of Zn plating/stripping, showing the inhibited HER. Moreover, the by-product on the Zn anode is barely observed during cycling when using the obtained gel electrolyte. Uniform zinc-ion distribution can be achieved to mitigate Zn dendrite growth in the gel electrolyte. Therefore, the Zn||Zn symmetric cell based on the gel electrolyte exhibits a long lifespan of more than 1300 h, which is longer than that in the aqueous electrolyte. Moreover, the Zn||LiFePO4 hybrid ion battery based on the gel electrolyte shows improved capacity retention by suppressing the reactions related to water.