journal article·2017-10-11

Warm-White-Light-Emitting Diode Based on a Dye-Loaded Metal–Organic Framework for Fast White-Light Communication

Zhiye Wang, Zi Wang, Bangjiang Lin, XueFu Hu, YunFeng Wei, Cankun Zhang, Bing An, Cheng Wang, Wenbin Lin

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Abstract

A dye@metal–organic framework (MOF) hybrid was used as a fluorophore in a white-light-emitting diode (WLED) for fast visible-light communication (VLC). The white light was generated from a combination of blue emission of the 9,10-dibenzoate anthracene (DBA) linkers and yellow emission of the encapsulated Rhodamine B molecules. The MOF structure not only prevents dye molecules from aggregation-induced quenching but also efficiently transfers energy to the dye for dual emission. This light-emitting material shows emission lifetimes of 1.8 and 5.3 ns for the blue and yellow components, respectively, which are significantly shorter than the 200 ns lifetime of Y 3 Al 5 O 12:Ce 3+ in commercial WLEDs. The MOF-WLED device exhibited a modulating frequency of 3.6 MHz for VLC, six times that of commercial WLEDs.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Nanocluster Synthesis and Applications · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P.R. China

Quanzhou Institute of Equipment Manufacturing, Haixi Institutes, Chinese Academy of Sciences, Quanzhou 362200, P.R, China

Department of Chemistry, University of Chicago, 929 East 57th Street, Chicago, Illinois 60637, United States

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Xiamen University · Central People's Government of the People's Republic of China

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