journal article·2019-08-28Open access

Role of Inorganic Surface Layer on Solid Electrolyte Interphase Evolution at Li-Metal Anodes

Ethan P. Kamphaus, Stefany Angarita-Gomez, Xueping Qin, Minhua Shao, Mark Engelhard, Karl T. Mueller, Vijayakumar Murugesan, Perla B. Balbuena

ACS Applied Materials & Interfaces· Volume 11· Issue 34

Abstract

O is the major component on the altered surface, LiF phases formed to a greater extent. The presence of a dominant LiOH layer, however, results in enhanced sulfur decomposition processes. From AIMD studies, these observations can be explained based on the calculated quantities of electronic charge transfer found for each of the passivating films.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

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Affiliations

Department of Chemical Engineering, Texas A&M University, College Station, Texas 77843, United States

Department of Chemical and Biological Engineering, HKUST, Clear Water Bay, Kowloon, Hong Kong, China

Pacific Northwest National Laboratory, Richland, Washington 99354, United States

Joint Center for Energy Storage Research (JCESR), Lemont, Illinois 60439, United States

Funding

Basic Energy Sciences

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