journal article·2018-10-24Open access

All Carbon Dual Ion Batteries

Zhe Hu, Qiannan Liu, Kai Zhang, Limin Zhou, Lin Li, Mingzhe Chen, Zhanliang Tao, Yong-Mook Kang, Liqiang Mai, Shu-Lei Chou, Jun Chen, Shi-Xue Dou

ACS Applied Materials & Interfaces· Volume 10· Issue 42

Abstract

Dual ion batteries based on Na+ and PF6– received considerable attention due to their high operating voltage and the abundant Na resources. Here, cheap and easily obtained graphite that served as a cathode material for dual ion battery delivered a very high average discharge platform (4.52 V vs Na+/Na) by using sodium hexafluorophosphate in propylene carbonate as electrolyte. Moreover, the all-carbon dual ion batteries with graphite as cathode and hard carbon as anode exhibited an ultrahigh discharge voltage of 4.3 V, and a reversible capacity of 62 mAh·g–1 at 40 mA·g–1. Phase changes have been investigated in detail through in situ X-ray diffraction and in situ Raman characterizations. The stable structure provides long life cycling performance, and the pseudocapacitance behavior also demonstrates its benefits to the rate capability. Thus, dual ion batteries based on sodium chemistry are very promising to find their applications in future.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering, College of Chemistry, Nankai University, Tianjin 300071, China

Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong, New South Wales 2522, Australia

Department of Energy and Materials Engineering, Dongguk University-Seoul, Seoul 100-715, Republic of Korea

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

Funding

Ministry of Science and Technology of the People's Republic of China · National Research Foundation of Korea · Australian Research Council · National Natural Science Foundation of China · Commonwealth of Australia

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