journal article·2016-11-30Open access

Electrochemical in Situ Tracking of Volumetric Changes in Two-Dimensional Metal Carbides (MXenes) in Ionic Liquids

Nicolas Jäckel, Benjamin Krüner, Katherine L. Van Aken, Mohamed Alhabeb, Babak Anasori, Friedrich Kaasik, Yury Gogotsi, Volker Presser

Abstract

We report the volumetric changes of MXenes in contact with different ionic liquids and the swelling/contraction during electrochemical voltage cycling by complementing electrochemical dilatometry with in situ X-ray diffraction measurements. A drastic, initial, and irreversible volume expansion of MXenes occurs during first contact to ionic liquids (wetting). Voltage cycling evidenced a highly reversible expansion and contraction of electrodes at a very large amplitude of strain (corresponding with max. 12 vol %), which may allow the use of MXene as a high-performance electrochemical actuator.
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Research context

OpenAlex topics: MXene and MAX Phase Materials · Advanced Sensor and Energy Harvesting Materials · Advanced Memory and Neural Computing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

INM-Leibniz Institute for New Materials, 66123 Saarbrücken, Germany

Department of Materials Science and Engineering, Saarland University, 66123 Saarbrücken, Germany

Department of Materials Science and Engineering & A.J. Drexel Nanomaterials Institute, Drexel University, Philadelphia, Pennsylvania 19104, United States

Funding

Basic Energy Sciences · Stiftung Prof. Joachim Lenz

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