Prussian Blue Analogue with Fast Kinetics Through Electronic Coupling for Sodium Ion Batteries

Ping Nie; Jiaren Yuan; Jie Wang; Zaiyuan Le; Guiyin Xu; Liang Hao; Gang Pang; Yuting Wu; Hui Dou; Xiaohong Yan; Xiaogang Zhang

doi:10.1021/acsami.7b05178

journal article·2017-06-21

Prussian Blue Analogue with Fast Kinetics Through Electronic Coupling for Sodium Ion Batteries

Ping Nie, Jiaren Yuan, Jie Wang, Zaiyuan Le, Guiyin Xu, Liang Hao, Gang Pang, Yuting Wu, Hui Dou, Xiaohong Yan, Xiaogang Zhang

ACS Applied Materials & Interfaces· Volume 9· Issue 24

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Source abstract

Abstract

Alternative battery systems based on the chemistry of sodium are being considered to offer sustainability and cost-effectiveness. Herein, a simple and new method is demonstrated to enable nickel hexacyanoferrate (NiHCF) Prussian blue analogues (PBA) nanocrystals to be an excellent host for sodium ion storage by functionalization with redox guest molecule. The method is achieved by using NiHCF PBA powders infiltrated with the 7,7,8,8-tetracyanoquinododimethane (TCNQ) solution. Experimental and ab initio calculations results suggest that TCNQ molecule bridging with Fe atoms in NiHCF Prussian blue analogue leads to electronic coupling between TCNQ molecules and NiHCF open-framework, which functions as an electrical highway for electron motion and conductivity enhancement. Combining the merits including high electronic conductivity, open framework structure, nanocrystal, and interconnected mesopores, the NiHCF/TCNQ shows high specific capacity, fast kinetics and good cycling stability, delivering a high specific capacity of 35 mAh g –1 after 2000 cycles, corresponding a capacity loss of 0.035% decay per cycle.

Source: openalex_inverted_index · Quality: baseline

Research context

Energy storage Nanomaterials

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Jiangsu Key Laboratory of Materials and Technology for Energy Conversion & College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, Los Angeles, California 90095, United States

School of Material Science and Engineering, Jiangsu University, Zhenjiang 212013, China

Funding

Ministry of Education of the People's Republic of China · Ministry of Science and Technology of the People's Republic of China · Nanjing University of Aeronautics and Astronautics · China Scholarship Council · National Natural Science Foundation of China · Natural Science Foundation of Anhui Province · Cooperative Innovation Fund of Jiangsu Province · Priority Academic Program Development of Jiangsu Higher Education Institutions

References (49)

Show source-provided references

1. 10.1038/451652a10.1038/451652a ↗

2. 10.1126/science.121274110.1126/science.1212741 ↗

3. 10.1021/acs.nanolett.5b0264210.1021/acs.nanolett.5b02642 ↗

4. 10.1002/anie.20141037610.1002/anie.201410376 ↗

5. 10.1039/c2ee02781j10.1039/c2ee02781j ↗

6. 10.1021/nn300920e10.1021/nn300920e ↗

7. 10.1021/acsnano.6b0833210.1021/acsnano.6b08332 ↗

8. 10.1149/1.139334810.1149/1.1393348 ↗

9. 10.1002/ijch.20140011810.1002/ijch.201400118 ↗

10. 10.1088/1674-1056/21/2/02820110.1088/1674-1056/21/2/028201 ↗

11. 10.1038/ncomms336510.1038/ncomms3365 ↗

12. 10.1021/cm202076g10.1021/cm202076g ↗

13. 10.1021/acs.accounts.5b0011410.1021/acs.accounts.5b00114 ↗

14. 10.1021/nl502860610.1021/nl5028606 ↗

15. 10.1016/0025-5408(80)90199-310.1016/0025-5408(80)90199-3 ↗

16. 10.1016/j.elecom.2009.12.03310.1016/j.elecom.2009.12.033 ↗

17. 10.1021/nl500548a10.1021/nl500548a ↗

18. 10.1039/c2cc31777j10.1039/c2cc31777j ↗

19. 10.1002/adma.20150152710.1002/adma.201501527 ↗

20. 10.1021/nl203193q10.1021/nl203193q ↗

21. 10.1038/ncomms156310.1038/ncomms1563 ↗

22. 10.1002/anie.20120685410.1002/anie.201206854 ↗

23. 10.1039/c4ta00062e10.1039/c4ta00062e ↗

24. 10.1039/C5TA03197D10.1039/C5TA03197D ↗

25. 10.1002/aenm.20140186910.1002/aenm.201401869 ↗

26. 10.1002/aenm.20140141010.1002/aenm.201401410 ↗

27. 10.1007/s12274-014-0588-710.1007/s12274-014-0588-7 ↗

28. 10.1016/j.nanoen.2015.01.01210.1016/j.nanoen.2015.01.012 ↗

29. 10.1021/cm504091z10.1021/cm504091z ↗

30. 10.1021/ja510347s10.1021/ja510347s ↗

31. 10.1021/ja512383b10.1021/ja512383b ↗

32. 10.1002/anie.20120850110.1002/anie.201208501 ↗

33. 10.1002/anie.20150026710.1002/anie.201500267 ↗

34. 10.1039/c3nr03289b10.1039/c3nr03289b ↗

35. 10.1002/adfm.20140282710.1002/adfm.201402827 ↗

36. 10.1038/ncomms494210.1038/ncomms4942 ↗

37. 10.1073/pnas.141509711110.1073/pnas.1415097111 ↗

38. 10.1039/c3ta12036h10.1039/c3ta12036h ↗

39. 10.1002/adfm.20160074710.1002/adfm.201600747 ↗

40. 10.1002/adma.20160084610.1002/adma.201600846 ↗

41. 10.1016/j.bios.2016.02.04410.1016/j.bios.2016.02.044 ↗

42. 10.1002/anie.20131067910.1002/anie.201310679 ↗

43. 10.1016/j.cplett.2014.06.02910.1016/j.cplett.2014.06.029 ↗

44. 10.1016/j.apcatb.2014.04.05010.1016/j.apcatb.2014.04.050 ↗

45. 10.1039/c3ta13223d10.1039/c3ta13223d ↗

46. 10.1126/science.124673810.1126/science.1246738 ↗

47. 10.1021/ja066260j10.1021/ja066260j ↗

48. 10.1016/j.nanoen.2017.03.00310.1016/j.nanoen.2017.03.003 ↗

49. 10.1021/acsenergylett.7b0028610.1021/acsenergylett.7b00286 ↗