journal article·2016-08-24

Highly Safe Ionic Liquid Electrolytes for Sodium-Ion Battery: Wide Electrochemical Window and Good Thermal Stability

Feng Wu, Na Zhu, Ying Bai, Libin Liu, Hang Zhou, Chuan Wu

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Abstract

Novel ionic liquid (IL) electrolytes are prepared by mixing 1-ethyl-3-methylimidazolium-bis-tetrafluoroborate (EMIBF4) with different concentrations of sodium salt (NaBF4). The as-prepared IL electrolytes display wide electrochemical windows of ∼4 V (1-5 V), which are consistent with the quantum chemical theoretical calculation. The IL electrolyte with 0.1 M NaBF4 shows excellent ionic conductivity, namely, 9.833 × 10(-3) S cm(-1) at 20 °C. In addition, nonflammability and good thermal stability are exhibited by combustion test and thermogravimetric analysis (TGA), which indicate the high safety of the IL electrolyte.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

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Affiliations

Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, People’s Republic of China

Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081, People’s Republic of China

Funding

Program for New Century Excellent Talents in University · Ministry of Science and Technology of the People's Republic of China · Beijing Co-construction Project

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