Catalyst with CeO₂ and Ni Nanoparticles on a LaCrO₃-Based Perovskite Substrate for Bio-Alcohol Steam Reforming and SOFC Power Generation

A Ni/CeO2–LCeCrN catalyst was developed with a unique hierarchy of exsolved Ni and CeO2 nanoparticles dispersed on a perovskite La0.8Ce0.2–xCr0.85Ni0.15–yO3−δ (LCeCrN) substrate for steam reforming methanol, ethanol, and glycerol, producing reformate gas as fuel for solid oxide fuel cell (SOFC) power generation. Methanol, ethanol, and glycerol are almost completely steam-reformed into H2, CO, and CO2 at 450, 650, and 700 °C at a steam/carbon (S/C) ratio of 1, 2.5, and 4 with a maximum hydrogen yield of 2.2, 5.2, and 6.0 mol, respectively. The catalytic performance of Ni/CeO2–LCeCrN catalyst is durable, with no carbon deposition for methanol and slight carbon deposition for ethanol and glycerol reforming for up to 100 h, due to the presence of CeO2 nanoparticles that enhance water adsorption capability and spillover oxygen to oxidize the deposited carbon. The reformate gas is fed in sequence into the anode of an SOFC single cell for power generation. The maximum power density of the cell is comparable at 650 °C and slightly lower at 700 and 750 °C than that fueled by H2, suggesting that Ni/CeO2–LCeCrN is an excellent catalyst for steam reforming methanol, ethanol, and glycerol to produce reformate gas for SOFC power generation.