journal article·2020-01-27Open access

CuSCN as Hole Transport Material with 3D/2D Perovskite Solar Cells

Vinod E. Madhavan, Iwan Zimmermann, Ahmer A. B. Baloch, Afsal Manekkathodi, Abdelhak Belaidi, Nouar Tabet, Mohammad Khaja Nazeeruddin

ACS Applied Energy Materials· Volume 3· Issue 1

Abstract

We report stable perovskite solar cells having 3D/2D perovskite absorber layers and CuSCN as an inorganic hole transporting material (HTM). (Phenylethyl)ammonium (PEA) and [(4-fluorophenyl)ethyl]ammonium (FPEA) have been chosen as 2D cations, creating thin layers of (PEA)2PbI4 or (FPEA)2PbI4 on top of the 3D perovskite. The 2D perovskite as an interfacial layer, neutralizes defects at the surface of the 3D perovskite absorber, and can protect from moisture-induced degradations. We demonstrate excellent charge extraction through the modified interfaces into the inorganic CuSCN HTM, with device efficiencies above 18%, compared to 19.3% with conventional spiro-OMeTAD. Furthermore, we show significantly enhanced ambient stability.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Quantum Dots Synthesis And Properties · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Qatar Environment and Energy Research Institute, Hamad Bin Khalifa University, Qatar Foundation, P. O. Box 34110, Doha, Qatar

Group for Molecular Engineering of Functional Materials, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne, CH-1951 Sion, Switzerland

Funding

Qatar National Research Fund · Solaronix

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