The morphotropic phase boundary in the (1 − x)PbZrO3–x[0.3Bi(Zn1/2Ti1/2)O3–0.7PbTiO3] perovskite solid solution
Source abstract
Abstract
Ceramics in the (1 − x)PbZrO3–x[0.3Bi(Zn1/2Ti1/2)O3–0.7PbTiO3] solid solution system with 0.48 ≤ x ≤ 0.56 were investigated. A morphotropic phase boundary separating rhombohedral and tetragonal perovskite phases was identified at x = 0.52. This composition displays the maximum remanent polarization P r of 40.7 μC/cm2 and the best piezoelectric coefficient d 33 of 311 pC/N in the pseudo-binary system. However, the Curie temperature T c for this MPB composition is 291 °C, much lower than initially expected.
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Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis · Multiferroics and related materials
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