journal article·2019-12-24

Strain Manipulation of Magnetic Anisotropy in Room-Temperature Ferrimagnetic Quadruple Perovskite CeCu3Mn4O12

Kei Shigematsu, Keisuke Shimizu, Kazumasa Yamamoto, Takumi Nishikubo, Yuki Sakai, Sergey A. Nikolaev, Hena Das, Masaki Azuma

ACS Applied Electronic Materials· Volume 1· Issue 12
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Abstract

Epitaxial growth of quadruple perovskite oxides presents an opportunity to expand their functionality and may lead to device applications. CeCu3Mn4O12 epitaxial thin film grown on YAlO3(110) exhibits a Neel temperature exceeding 400 K and metallic transport properties at room temperature, which can be accounted for by the high valence states of the constituting Ce4+ and Mn3.5+ stabilized by the oxidative deposition process. Uniaxial magnetic anisotropy is induced in CeCu3Mn4O12, whose easy axis lies parallel to orthorhombic YAlO3[10] where CeCu3Mn4O12 is most elongated. Perpendicular magnetic anisotropy can be realized in compressively strained CeCu3Mn4O12 by inserting a small YCaAlO4 buffer layer. This trend of magnetic anisotropy in strained CeCu3Mn4O12 was in good agreement with theoretical calculations.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Ferroelectric and Piezoelectric Materials · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratory for Materials and Structures, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, Kanagawa 226-8503, Japan

Kanagawa Institute of Industrial Science and Technology (KISTEC), 705-1 Shimoimaizumi, Ebina, Kanagawa 243-0435, Japan

Tokyo Tech World Research Hub Initiative (WRHI), Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, Kanagawa 226-8503, Japan

Funding

Ministry of Education, Culture, Sports, Science and Technology · Toyota Physical and Chemical Research Institute · Japan Science Society · Japan Society for the Promotion of Science · Tokyo Institute of Technology · Institute of Innovative Research · Kanagawa Institute of Industrial Science and Technology

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