journal article·2025-12

Enhanced thermal decomposition of energetic molecular perovskite DAP-4 using porous Mn@Co3O4 microspheres: a kinetic and mechanistic study

M. Yehia, Shukri Ismael, Sherif Elbasuney, Ana Sousa-Castillo, Margarita Vázquez-González, Miguel A. Correa-Duarte

Journal of Materials Science· Volume 60· Issue 48
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OpenAlex topics: Energetic Materials and Combustion · Catalytic Processes in Materials Science · Thermal and Kinetic Analysis

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References (69)

Show source-provided references
1. Liu J et al (2016) Two-dimensional CH3NH3PbI3 perovskite: synthesis and optoelectronic application. ACS Nano 10(3):3536–354210.1021/acsnano.5b07791 ↗
2. Li J et al (2021) Perovskite single crystals: synthesis, optoelectronic properties, and application. Adv Funct Mater 31(11):200868410.1002/adfm.202008684 ↗
3. Butler PB, Krier H (1986) Analysis of deflagration to detonation transition in high-energy solid propellants. Combust Flame 63(1–2):31–4810.1016/0010-2180(86)90109-4 ↗
4. Liu L et al (2022) Modifying the ignition, combustion and agglomeration characteristics of composite propellants via Al-Mg alloy additives. Combust Flame 238:11192610.1016/j.combustflame.2021.111926 ↗
5. Elbasuney S et al (2023) Novel ammonium perchlorate/RDX co-crystal: bespoke energetic materials with tailored decomposition kinetics. J Energetic Mater 43:1–18
6. Zhang W-X et al (2020) Molecular perovskites as a new platform for designing advanced multi-component energetic crystals. Energetic Mater Front 1(3–4):123–13510.1016/j.enmf.2020.12.003 ↗
7. Deng P et al (2022) The combustion behavior of boron particles by using molecular perovskite energetic materials as high-energy oxidants. Combust Flame 241:11211810.1016/j.combustflame.2022.112118 ↗
8. Deng P et al (2022) Combustion behavior and mechanism of molecular perovskite energetic material DAP-4-based composites with metal fuel Al. Def Technol 27:53–6310.1016/j.dt.2022.10.012 ↗
9. Shang Y et al (2016) A novel 3D energetic MOF of high energy content: synthesis and superior explosive performance of a Pb (II) compound with 5, 5′-bistetrazole-1, 1′-diolate. Dalton Trans 45(35):13881–1388710.1039/C6DT02558G ↗
10. He W et al (2020) Metastable energetic nanocomposites of MOF-activated aluminum featured with multi-level energy releases. Chem Eng J 381:12262310.1016/j.cej.2019.122623 ↗
11. Dunju W et al (2020) Additive manufacturing and combustion performance of CL-20 composites. J Mater Sci 55(7):2836–2845. https://doi.org/10.1007/s10853-019-04209-w10.1007/s10853-019-04209-w ↗
12. Wang S et al (2020) Synergistic catalysis of ZIF-67@ CNT OH in thermal decomposition of ammonium perchlorate. J Mater Sci 55(11):4646–4655. https://doi.org/10.1007/s10853-019-04321-x10.1007/s10853-019-04321-x ↗
13. Zhao Z et al (2024) MgCo2O4 microflower with excellent thermocatalytic properties for ammonium perchlorate decomposition. J Mater Sci 59(10):4136–4151. https://doi.org/10.1007/s10853-024-09483-x10.1007/s10853-024-09483-x ↗
14. Elbasuney S et al (2023) Facile fabrication and catalytic activity of nickel to ferric oxide nanoparticles for ammonium perchlorate decomposition. Braz J Chem Eng 40:1–1110.1007/s43153-023-00299-x ↗
15. Li R et al (2021) Defect-engineered sp2 carbon as highly active catalyst and reactive fuel for combustion of ammonium perchlorate. Chem Eng J 426:13191810.1016/j.cej.2021.131918 ↗
16. Elbasuney S, Ismael S, Yehia M (2021) Ammonium percholorate/HMX Co-crystal: bespoke energetic materials with tailored decomposition kinetics via dual catalytic effect. J Energetic Mater 41:1–20
17. Yehia M et al (2025) Facile synthesis and decomposition kinetics of novel green energetic molecular perovskite based on nitrate group DAN-4 as an alternative for ammonium nitrate oxidizer. Sci Rep 15(1):1–1710.1038/s41598-025-99700-7 ↗
18. Deng P, Jiao Q, Ren H (2021) Laminated ammonium perchlorate-based composite prepared by ice-template freezing-induced assembly. J Mater Sci 56(3):2077–2087. https://doi.org/10.1007/s10853-020-05174-510.1007/s10853-020-05174-5 ↗
19. Deng P et al (2020) Thermal decomposition and combustion performance of high-energy ammonium perchlorate-based molecular perovskite. J Alloys Compd 827:15425710.1016/j.jallcom.2020.154257 ↗
20. An E-H et al (2023) Facile preparation of Fe/N-based biomass porous carbon composite towards enhancing the thermal decomposition of DAP-4. Def Technol 31:288–29410.1016/j.dt.2022.12.019 ↗
21. Deng P, Ren H, Jiao Q (2019) Enhanced the combustion performances of ammonium perchlorate-based energetic molecular perovskite using functionalized graphene. Vacuum 169:10888210.1016/j.vacuum.2019.108882 ↗
22. Shang Y et al (2022) Silver (I)-based molecular perovskite energetic compounds with exceptional thermal stability and energetic performance. Inorg Chem 61(9):4143–414910.1021/acs.inorgchem.1c03958 ↗
23. Yehia M et al (2024) Ammonium perchlorate catalyzed with novel n-Al modified on ZIF-67 with silane coupling agent: superior catalytic activity, advanced decomposition kinetics and mechanisms. Ceram Int 50(24):55065–5508410.1016/j.ceramint.2024.10.356 ↗
24. Fang H et al (2022) Facile fabrication of carbon nanotubes-encapsulated cobalt (nickel) salt nanocomposites and their highly efficient catalysis in the thermal degradation of ammonium perchlorate and hexogen. J Alloys Compd 928:16713410.1016/j.jallcom.2022.167134 ↗
25. Li R et al (2023) Defective-activated-carbon-encapsulated Co as a super reactive catalyst for combustion of ammonium perchlorate. Appl Surf Sci 615:15634910.1016/j.apsusc.2023.156349 ↗
26. Shang Y et al (2020) Metal-free molecular perovskite high-energetic materials. Cryst Growth Des 20(3):1891–189710.1021/acs.cgd.9b01592 ↗
27. Shang Y et al (2020) Metal-free hexagonal perovskite high-energetic materials with NH3OH+/NH2NH3+ as B-site cations. Engineering 6(9):1013–101810.1016/j.eng.2020.05.018 ↗
28. Yang B et al (2022) Reaction-dominated combustion control of ammonium perchlorate-based composites by layered V2C MXene. Energetic Mater Front 3(4):199–20810.1016/j.enmf.2022.06.001 ↗
29. Yan Q-L et al (2016) Catalytic effects of nano additives on decomposition and combustion of RDX-, HMX-, and AP-based energetic compositions. Prog Energy Combust Sci 57:75–13610.1016/j.pecs.2016.08.002 ↗
30. An E-H et al (2024) Facile preparation of Fe/N-based biomass porous carbon composite towards enhancing the thermal decomposition of DAP-4. Defence Technol 31:288–29410.1016/j.dt.2022.12.019 ↗
31. Han K et al (2020) Study of the thermal catalysis decomposition of ammonium perchlorate-based molecular perovskite with titanium carbide MXene. Vacuum 180:10957210.1016/j.vacuum.2020.109572 ↗
32. Liang J et al (2022) Preparation of Fe2O3 nanosheets and catalytic decomposition performance of DAP-4. Inorg Chem Commun 143:10975210.1016/j.inoche.2022.109752 ↗
33. Li X et al (2020) Ammonium perchlorate-based molecular perovskite energetic materials: preparation, characterization, and thermal catalysis performance with MoS2. J Energetic Mater 38(2):162–16910.1080/07370652.2019.1679281 ↗
34. Zhu P et al (2023) Effects of magnesium hydride on the thermal decomposition and combustion properties of DAP-4. Vacuum 214:11217010.1016/j.vacuum.2023.112170 ↗
35. Kumar R et al (2014) Graphene-wrapped and cobalt oxide-intercalated hybrid for extremely durable super-capacitor with ultrahigh energy and power densities. Carbon 79:192–20210.1016/j.carbon.2014.07.059 ↗
36. Zdorovets M et al (2021) Phase transformations in FeCo–Fe2CoO4/Co3O4-spinel nanostructures as a result of thermal annealing and their practical application. J Mater Sci Mater Electron 32(12):16694–1670510.1007/s10854-021-06226-5 ↗
37. Chauhan A et al (2024) Recent advances on Co3O4-based nanostructure photocatalysis: structure, synthesis, modification strategies, and applications. Surf Interfaces 54:10515210.1016/j.surfin.2024.105152 ↗
38. Aadil M et al (2021) Fabrication of nickel foam supported Cu-doped Co3O4 nanostructures for electrochemical energy storage applications. Ceram Int 47(7):9225–923310.1016/j.ceramint.2020.12.048 ↗
39. Huo J et al (2021) Surface modification of Co3O4 nanoplates as efficient peroxidase nanozymes for biosensing application. ACS Appl Bio Mater 4(4):3443–345210.1021/acsabm.1c00017 ↗
40. Xiong T et al (2020) Defect engineering in manganese-based oxides for aqueous rechargeable zinc-ion batteries: a review. Adv Energy Mater 10(34):200176910.1002/aenm.202001769 ↗
41. Du X et al (2023) Recent advances on the manganese cobalt oxides as electrode materials for supercapacitor applications: a comprehensive review. J Energy Storage 68:10767210.1016/j.est.2023.107672 ↗
42. Fu Y et al (2025) Polypyrrol/iron-manganese oxide/graphene oxide composites as electrode materials for supercapacitors based on core–shell layered structure. J Mater Sci 60:1–18. https://doi.org/10.1007/s10853-025-10626-x10.1007/s10853-025-10626-x ↗
43. Shi W, Lee WSV, Xue J (2021) Recent development of Mn-based oxides as zinc-ion battery cathode. Chemsuschem 14(7):1634–165810.1002/cssc.202002493 ↗
44. Wiechen M et al (2014) Water oxidation catalysis by manganese oxides: learning from evolution. Energy Environ Sci 7(7):2203–221210.1039/c4ee00681j ↗
45. Bolar S et al (2019) Optimization of active surface area of flower like MoS2 using V-doping towards enhanced hydrogen evolution reaction in acidic and basic medium. Appl Catal B 254:432–44210.1016/j.apcatb.2019.04.028 ↗
46. Chen S-L et al (2018) Molecular perovskite high-energetic materials. Sci China Mater 61(8):1123–112810.1007/s40843-017-9219-9 ↗
47. Choppali U et al (2010) Polymeric precursor derived nanocrystalline ZnO thin films using EDTA as chelating agent. Sol Energy Mater Sol Cells 94(12):2351–235710.1016/j.solmat.2010.08.012 ↗
48. Motta M et al (2008) Chelating agent effects in the synthesis of mesoscopic-size superconducting particles. J Sol-Gel Sci Technol 46:201–20710.1007/s10971-007-1673-0 ↗
49. Khawam A, Flanagan DR (2006) Basics and applications of solid-state kinetics: a pharmaceutical perspective. J Pharm Sci 95(3):472–49810.1002/jps.20559 ↗
50. Trache D, Abdelaziz A, Siouani B (2017) A simple and linear isoconversional method to determine the pre-exponential factors and the mathematical reaction mechanism functions. J Therm Anal Calorim 128(1):335–34810.1007/s10973-016-5962-0 ↗
51. Vyazovkin S et al (2011) ICTAC kinetics committee recommendations for performing kinetic computations on thermal analysis data. Thermochim Acta 520(1–2):1–1910.1016/j.tca.2011.03.034 ↗
52. Trache D et al (2016) Physicochemical properties of microcrystalline nitrocellulose from Alfa grass fibres and its thermal stability. J Therm Anal Calorim 124(3):1485–149610.1007/s10973-016-5293-1 ↗
53. Elbasuney S et al (2023) Facile synthesis and catalytic activity assessment of cobalt oxide nanoparticles: towards advanced energetic nitramines. J Clust Sci 34:1–1210.1007/s10876-023-02407-w ↗
54. Rahimi-Nasrabadi M et al (2017) Cobalt carbonate and cobalt oxide nanoparticles synthesis, characterization and supercapacitive evaluation. J Mater Sci Mater Electron 28:1877–188810.1007/s10854-016-5739-z ↗
55. Kalubarme RS et al (2018) Porous Mn-doped cobalt oxide@ C nanocomposite: a stable anode material for Li-ion rechargeable batteries. Nanotechnology 29(28):28570510.1088/1361-6528/aac034 ↗
56. Babakhani B, Ivey DG (2011) Investigation of electrochemical behavior of Mn–Co doped oxide electrodes for electrochemical capacitors. Electrochim Acta 56(13):4753–476210.1016/j.electacta.2011.03.008 ↗
57. Chen C et al (2025) Cobalt-based nano-MOF additive to aluminum for enhancing energy release of energetic components. Chem Eng J 522:16730010.1016/j.cej.2025.167300 ↗
58. Zheng Z et al (2024) Hierarchical MOFs with Good Catalytic Properties and Structural Stability in Oxygen-Rich and High-Temperature Environments. Small 20(27):230930210.1002/smll.202309302 ↗
59. Aghazadeh M (2012) Electrochemical preparation and properties of nanostructured Co3O4 as supercapacitor material. J Appl Electrochem 42(2):89–9410.1007/s10800-011-0375-z ↗
60. Liu S et al (2021) Unlocking the optimum supercapacitance of Co3O4 by reducing the Co valence state via Mn doping. Mater Today Commun 28:10266510.1016/j.mtcomm.2021.102665 ↗
61. Zhou L et al (2020) Facet effect of Co3O4 nanocatalysts on the catalytic decomposition of ammonium perchlorate. J Hazard Mater 392:12235810.1016/j.jhazmat.2020.122358 ↗
62. Deng P et al (2022) One-pot hydrothermal synthesis of flower-like MnO2 nanostructure with rich oxygen vacancy for catalysis thermal-induced pyrolysis of energetic molecular perovskite. Vacuum 203:11123410.1016/j.vacuum.2022.111234 ↗
63. Fang H et al (2023) Thermal decomposition and combustion characteristics of molecular perovskite energetic material DAP-4 catalyzed by Co3O4 nanoclusters. J Therm Anal Calorim 148(19):10441–1044810.1007/s10973-023-12357-0 ↗
64. Fang H et al (2021) The thermal catalytic effects of CoFe-Layered double hydroxide derivative on the molecular perovskite energetic material (DAP-4). Vacuum 193:11050310.1016/j.vacuum.2021.110503 ↗
65. Ismael S et al (2023) Ammonium perchlorate catalyzed with novel porous Mn-doped Co3O4 microspheres: superior catalytic activity, advanced decomposition kinetics and mechanisms. J Therm Anal Calorim 148(21):11811–1182410.1007/s10973-023-12456-y ↗
66. Yu C et al (2018) Shape-controlled syntheses of Co3O4 nanowires arrays with excellent catalytic performances upon ammonium perchlorate decomposition. Mater Res Bull 97:483–48910.1016/j.materresbull.2017.09.049 ↗
67. Chen Y et al (2018) Catalytic activities of two different morphological nano-MnO2 on the thermal decomposition of ammonium perchlorate. Mater Res Bull 101:56–6010.1016/j.materresbull.2018.01.013 ↗
68. Hu Y et al (2020) Thermal decomposition of ammonium perchlorate over perovskite catalysts: catalytic decomposition behavior, mechanism and application. Appl Surf Sci 513:14584910.1016/j.apsusc.2020.145849 ↗
69. Dave PN, Likhariya T, Chaturvedi S (2025) LaCoxMn1− xO3 perovskite oxide: its synthesis and catalytic application in thermal study of AP. Chem Eng Technol 48(7):e7007110.1002/ceat.70071 ↗