journal article·2019-03

The effect of CuS counter electrodes for the CdS/CdSe quantum dot co-sensitized solar cells based on zinc titanium mixed metal oxides

Dong Liu, Jianqiang Liu, Jie Liu, Sha Liu, Chenglei Wang, Zhongwei Ge, Xiaotao Hao, Na Du, Hongdi Xiao

Journal of Materials Science· Volume 54· Issue 6
Publisher page

Abstract

The highly catalytic copper sulfide (CuS) thin films were designed and combined with the FTO substrates by the chemical bath deposition method and were used as counter electrodes (CEs) for the CdS/CdSe quantum dot-sensitized solar cells (QDSSCs) based on zinc titanium mixed metal oxides (MMOs) deriving from the layered double hydroxide precursor for the first time. Formation of CuS films was confirmed by X-ray diffraction and X-ray photon spectroscopy. The surface morphology of CuS films was observed by scanning electron microscopy (SEM). Systemic electrochemical test was used to investigate the catalytic performance of CuS films and the photovoltaic performance of QDSSCs. When the number of deposition cycles (30 min per cycle) was two, the CuS CEs of excellent performance were obtained. The CuS CEs exhibited higher performance for QDSSCs based on ZnTi MMOs than the conventional platinum (Pt) CEs. The best power conversion efficiency of CdS/CdSe QDSSCs using optimal CuS CEs reached 3.95%, which is more than twice higher than that of Pt CEs.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · TiO2 Photocatalysis and Solar Cells · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (36)

Show source-provided references
1. Sharma D, Jha R, Kumar S (2016) Quantum dot sensitized solar cell: recent advances and future perspectives in photoanode. Sol Energy Mater Sol Cells 155:294–322. https://doi.org/10.1016/j.solmat.2016.05.06210.1016/j.solmat.2016.05.062 ↗
2. Yu J, Wang W, Pan Z, Du J, Ren Z, Xue W, Zhong X (2017) Quantum dot sensitized solar cells with efficiency over 12% based on tetraethyl orthosilicate additive in polysulfide electrolyte. J Mater Chem A 5(27):14124–14133. https://doi.org/10.1039/c7ta04344a10.1039/C7TA04344A ↗
3. Cao J, Zhu Y, Yang X, Chen Y, Li Y, Xiao H, Hou W, Liu J (2016) The promising photo anode of graphene/zinc titanium mixed metal oxides for the CdS quantum dot-sensitized solar cell. Sol Energy Mater Sol Cells 157:814–819. https://doi.org/10.1016/j.solmat.2016.08.00310.1016/j.solmat.2016.08.003 ↗
4. Tian J, Cao G (2016) Design, fabrication and modification of metal oxide semiconductor for improving conversion efficiency of excitonic solar cells. Coord Chem Rev 320–321:193–215. https://doi.org/10.1016/j.ccr.2016.02.01610.1016/j.ccr.2016.02.016 ↗
5. Tian J, Cao G (2015) Control of nanostructures and interfaces of metal oxide semiconductors for quantum-dots-sensitized solar cells. J Phys Chem Lett 6(10):1859–1869. https://doi.org/10.1021/acs.jpclett.5b0030110.1021/acs.jpclett.5b00301 ↗
6. Liu X, Song X, Zhang N, Ma P, Mo Z, Ding N, He T (2017) The influence of ZnO nanorod length and counter electrode material on the photovoltaic properties of CdS/CdSe quantum dots cosensitized zno nanorods solar cells. IEEE J Photovolt 7(6):1653–166210.1109/JPHOTOV.2017.2754413 ↗
7. Zhou R, Zhang Q, Uchaker E, Yang L, Yin N, Chen Y, Yin M, Cao G (2014) Photoanodes with mesoporous TiO2 beads and nanoparticles for enhanced performance of CdS/CdSe quantum dot co-sensitized solar cells. Electrochim Acta 135:284–292. https://doi.org/10.1016/j.electacta.2014.05.02110.1016/j.electacta.2014.05.021 ↗
8. Lan Z, Wu W, Zhang S, Que L, Wu J (2016) Preparation of high-efficiency CdS quantum-dot-sensitized solar cells based on ordered TiO2 nanotube arrays. Ceram Int 42(7):8058–8065. https://doi.org/10.1016/j.ceramint.2016.02.00310.1016/j.ceramint.2016.02.003 ↗
9. Zhao D, Yang C-F (2016) Recent advances in the TiO2/CdS nanocomposite used for photocatalytic hydrogen production and quantum-dot-sensitized solar cells. Renew Sustain Energy Rev 54:1048–1059. https://doi.org/10.1016/j.rser.2015.10.10010.1016/j.rser.2015.10.100 ↗
10. Zhou R, Zhang Q, Uchaker E, Lan J, Yin M, Cao G (2014) Mesoporous TiO2 beads for high efficiency CdS/CdSe quantum dot co-sensitized solar cells. J Mater Chem A 2(8):2517–2525. https://doi.org/10.1039/c3ta13460a10.1039/c3ta13460a ↗
11. Pawar SA, Patil DS, Lokhande AC, Gang MG, Shin JC, Patil PS, Kim JH (2016) Chemical synthesis of CdS onto TiO2 nanorods for quantum dot sensitized solar cells. Opt Mater 58:46–50. https://doi.org/10.1016/j.optmat.2016.05.01910.1016/j.optmat.2016.05.019 ↗
12. Hou J, Zhao H, Huang F, Jing Q, Cao H, Wu Q, Peng S, Cao G (2016) High performance of Mn-doped CdSe quantum dot sensitized solar cells based on the vertical ZnO nanorod arrays. J Power Sour 325:438–445. https://doi.org/10.1016/j.jpowsour.2016.06.07010.1016/j.jpowsour.2016.06.070 ↗
13. Torresan MF, Baruzzi AM, Iglesias RA (2016) Thermal annealing of photoanodes based on CdSe Qdots sensitized TiO2. Sol Energy Mater Sol Cells 155:202–208. https://doi.org/10.1016/j.solmat.2016.06.01510.1016/j.solmat.2016.06.015 ↗
14. Lee Y-L, Lo Y-S (2009) Highly efficient quantum-dot-sensitized solar cell based on co-sensitization of CdS/CdSe. Adv Funct Mater 19(4):604–609. https://doi.org/10.1002/adfm.20080094010.1002/adfm.200800940 ↗
15. Yu X-Y, Liao J-Y, Qiu K-Q, Kuang D-B, Su C-Y (2011) Dynamic study of highly efficient CdS/CdSe quantum dot-sensitized solar cells fabricated by electrodeposition. ACS Nano 5(12):9494–950010.1021/nn203375g ↗
16. Zhou C, Geng Y, Chen Q, Xu J, Huang N, Gan Y, Zhou L (2016) A novel PbS/TiO2 composite counter electrode for CdS quantum dot-sensitized ZnO nanorods solar cells. Mater Lett 172:171–17410.1016/j.matlet.2016.02.092 ↗
17. Jiao S, Wang J, Shen Q, Li Y, Zhong X (2016) Surface engineering of PbS quantum dot sensitized solar cells with a conversion efficiency exceeding 7%. J Mater Chem A 4(19):7214–722110.1039/C6TA02465C ↗
18. Kokal RK, Deepa M, Kalluri A, Singh S, Macwan I, Patra PK, Gilarde J (2017) Solar cells with PbS quantum dot sensitized TiO 2–multiwalled carbon nanotube composites, sulfide-titania gel and tin sulfide coated C-fabric. Phys Chem Chem Phys 19(38):26330–2634510.1039/C7CP05582J ↗
19. Yang S, Zhao P, Zhao X, Qu L, Lai X (2015) InP and Sn: InP based quantum dot sensitized solar cells. J Mater Chem A 3(43):21922–21929. https://doi.org/10.1039/c5ta04925c10.1039/C5TA04925C ↗
20. Chang JY, Chang SC, Tzing SH, Li CH (2014) Development of nonstoichiometric CuInS(2) as a light-harvesting photoanode and catalytic photocathode in a sensitized solar cell. ACS Appl Mater Interfaces 6(24):22272–22281. https://doi.org/10.1021/am506199210.1021/am5061992 ↗
21. Cai C, Zhai L, Wu Q, Ma Y, Zhang L, Yang Y, Zou C, Huang S (2017) Tailoring defects of CuInS2 quantum dots for sensitized solar cells. J Alloy Compd 719:227–23510.1016/j.jallcom.2017.05.007 ↗
22. Wang G, Wei H, Shi J, Xu Y, Wu H, Luo Y, Li D, Meng Q (2017) Significantly enhanced energy conversion efficiency of CuInS2 quantum dot sensitized solar cells by controlling surface defects. Nano Energy 35:17–2510.1016/j.nanoen.2017.03.008 ↗
23. Zhang H, Wang C, Peng W, Yang C, Zhong X (2016) Quantum dot sensitized solar cells with efficiency up to 8.7% based on heavily copper-deficient copper selenide counter electrode. Nano Energy 23:60–69. https://doi.org/10.1016/j.nanoen.2016.03.00910.1016/j.nanoen.2016.03.009 ↗
24. Gopi CV, Venkata-Haritha M, Ravi S, Thulasi-Varma CV, Kim S-K, Kim H-J (2015) Solution processed low-cost and highly electrocatalytic composite NiS/PbS nanostructures as a novel counter-electrode material for high-performance quantum dot-sensitized solar cells with improved stability. J Mater Chem C 3(48):12514–1252810.1039/C5TC03138A ↗
25. Thulasi-Varma CV, Rao SS, Ikkurthi KD, Kim S-K, Kang T-S, Kim H-J (2015) Enhanced photovoltaic performance and morphological control of the PbS counter electrode grown on functionalized self-assembled nanocrystals for quantum-dot sensitized solar cells via cost-effective chemical bath deposition. J Mater Chem C 3(39):10195–1020610.1039/C5TC01988E ↗
26. Cao J, Zhao Y, Zhu Y, Yang X, Shi P, Xiao H, Du N, Hou W, Qi G, Liu J (2017) Preparation and photovoltaic properties of CdS quantum dot-sensitized solar cell based on zinc tin mixed metal oxides. J Colloid Interface Sci 498:223–228. https://doi.org/10.1016/j.jcis.2017.03.06110.1016/j.jcis.2017.03.061 ↗
27. Zhu Y, Wang D, Yang X, Liu S, Liu D, Liu J, Xiao H, Hao X, Liu J (2017) Investigation of the dye-sensitized solar cell designed by a series of mixed metal oxides based on ZnAl-layered double hydroxide. Appl Phys A 123(10):641–648. https://doi.org/10.1007/s00339-017-1256-z10.1007/s00339-017-1256-z ↗
28. Kim H-J, Ko B, Gopi CVVM, Venkata-Haritha M, Lee Y-S (2017) Facile synthesis of morphology dependent CuS nanoparticle thin film as a highly efficient counter electrode for quantum dot-sensitized solar cells. J Electroanal Chem 791:95–102. https://doi.org/10.1016/j.jelechem.2017.03.01910.1016/j.jelechem.2017.03.019 ↗
29. Yuan B, Duan L, Gao Q, Zhang X, Li X, Yang Y, Chen L, Lü W (2018) Investigation of metal sulfide composites as counter electrodes for improved performance of quantum dot sensitized solar cells. Mater Res Bull 100:198–205. https://doi.org/10.1016/j.materresbull.2017.12.02110.1016/j.materresbull.2017.12.021 ↗
30. Hodes G, Manassen J, Cahen D (1980) Electrocatalytic electrodes for the polysulfide redox system. J Electrochem Soc 127(3):544–54910.1149/1.2129709 ↗
31. Savariraj AD, Viswanathan KK, Prabakar K (2014) Influence of Cu vacancy on knit coir mat structured CuS as counter electrode for quantum dot sensitized solar cells. ACS Appl Mater Interfaces 6(22):19702–1970910.1021/am504615x ↗
32. Sunesh CD, Gopi CV, Muthalif MPA, Kim H-J, Choe Y (2017) Improving the efficiency of quantum-dot-sensitized solar cells by optimizing the growth time of the CuS counter electrode. Appl Surf Sci 416:446–45310.1016/j.apsusc.2017.04.200 ↗
33. Fang X, Ma T, Guan G, Akiyama M, Kida T, Abe E (2004) Effect of the thickness of the Pt film coated on a counter electrode on the performance of a dye-sensitized solar cell. J Electroanal Chem 570(2):257–26310.1016/j.jelechem.2004.04.004 ↗
34. Muthalif MPA, Sunesh CD, Choe Y (2018) H3PO4 treated surface modified CuS counter electrodes with high electrocatalytic activity for enhancing photovoltaic performance of quantum dot-sensitized solar cells. Appl Surf Sci 440:1022–102610.1016/j.apsusc.2018.01.233 ↗
35. Huang F, Hou J, Zhang Q, Wang Y, Massé RC, Peng S, Wang H, Liu J, Cao G (2016) Doubling the power conversion efficiency in CdS/CdSe quantum dot sensitized solar cells with a ZnSe passivation layer. Nano Energy 26:114–12210.1016/j.nanoen.2016.05.012 ↗
36. Zhang X, Huang X, Yang Y, Wang S, Gong Y, Luo Y, Li D, Meng Q (2013) Investigation on new CuInS2/carbon composite counter electrodes for CdS/CdSe cosensitized solar cells. ACS Appl Mater Interfaces 5(13):5954–596010.1021/am400268j ↗