journal article·2018-01

Ferroelectric electrocatalysts: a new class of materials for oxygen evolution reaction with synergistic effect of ferroelectric polarization

H. S. Kushwaha, Aditi Halder, Rahul Vaish

Journal of Materials Science· Volume 53· Issue 2
Publisher page

Abstract

We exploit the role of the remnant polarization to improve the electrocatalytic performance of ferroelectric perovskite. We report cost-effective, noble metal-free, ferroelectric electrocatalyst Bi0.5Na0.5TiO3 and the effect of remnant polarization on oxygen evolution reaction involved in alkaline fuel cells. The forward poling decreases the Tafel slope from 85 mv/decade to 39 mv/decade and also increases the mass activity by threefold. The effect of polarization on flat-band potential and the Schottky barrier between electrode and electrolyte contributes to enhanced electrochemical activity.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Advancements in Solid Oxide Fuel Cells

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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