Magnetic, dielectric, and magnetodielectric properties of Bi-layered perovskite Bi4.25Gd 0.75Fe0.5Co0.5Ti3O15
Source abstract
Abstract
The magnetic, dielectric, and magnetodielectric properties of bi-layered perovskite Bi4.25Gd0.75Fe0.5Co0.5Ti3O15 (BGFCT) ceramics were investigated. Weak ferromagnetism at room temperature with a remnant magnetization M r of 0.26 emu/g was found in the BGFCT specimens, and the ferromagnetic transition was determined at ~383 K. The change in valence state for magnetic ions has been confirmed by the XPS measurement, which would introduce ferromagnetism via double-exchange interaction. The Dzyaloshinsky–Moriya interaction was also proposed to explain weak ferromagnetism. The ferroelectric phase transition around 1072 K has been verified by the temperature-dependent dielectric measurement and differential scanning calorimetry. The standard positive-up–negative-down tests indicated the intrinsic ferroelectricity of BGFCT, and an obvious MD effect was observed in the temperature range from 190 to 280 K. The dielectric loss of the BGFCT exhibits one dielectric relaxation with activation energy E a ~ 0.49 eV, which is related to the hooping of oxygen vacancies.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Multiferroics and related materials · Ferroelectric and Piezoelectric Materials · Dielectric properties of ceramics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (48)
Show source-provided references
1. Schmid H (1994) Multi-ferroic magnetoelectrics. Ferroelectrics 162:31710.1080/00150199408245120 ↗
2. Eerenstein W, Mathur ND, Scott JF (2006) Multiferroic and magnetoelectric materials. Nature (London) 442:75910.1038/nature05023 ↗
3. Cheong SW, Mostovoy M (2007) Multiferroics: a magnetic twist for ferroelectricity. Nat Mater 6:1310.1038/nmat1804 ↗
4. Ramesh R, Spaldin NA (2007) Multiferroics: progress and prospects in thin films. Nat Mater 6:2110.1038/nmat1805 ↗
5. Yuan B, Yang J, Chen J, Zuo XZ, Yin LH, Tang XW, Zhu XB, Dai JM, Song WH, Sun YP (2014) Magnetic and dielectric properties of Aurivillius phase Bi6Fe2Ti3−2x Nb x Co x O18 (0 ≤ x ≤ 0.4). Appl Phys Lett 104:06241310.1063/1.4865422 ↗
6. Xu QY, Sheng Y, Khalid M, Cao YQ, Wang YT, Qiu XB, Zhang W, He MC, Wang SB, Zhou SQ, Li Q, Wu D, Zhai Y, Liu WQ, Wang P, Xu YB, Du J (2015) Magnetic interactions in BiFe0.5Mn0.5O3 films and BiFeO3/BiMnO3 superlattices. Sci Rep 5:909310.1038/srep09093 ↗
7. Scott JF, Singh MK, Katiyar RS (2008) Critical phenomena at the 140 and 200 K magnetic phase transitions in BiFeO3. J Phys Condens Matter 20:32220310.1088/0953-8984/20/32/322203 ↗
8. Nakamura S, Soeya S, Ikeda N, Tanaka M (1993) Spin-glass behavior in amorphous BiFeO3. J Appl Phys 74:565210.1063/1.354179 ↗
9. Zhang JT, Lu XM, Zhou J, Sun H, Su J (2012) Origin of magnetic anisotropy and spiral spin order in multiferroic BiFeO3. Appl Phys Lett 100:24241310.1063/1.4729555 ↗
10. Dong XW, Wang KF, Wan JG, Zhu JS, Liu JM (2008) Magnetocapacitance of polycrystalline Bi5Ti3FeO15 prepared by sol-gel method. J Appl Phys 103:09410110.1063/1.2908219 ↗
11. Bai W, Gao YQ, Zhu JY, Meng XJ, Lin T, Yang J, Zhu ZQ, Chu JH (2011) Electrical, magnetic, and optical properties in multiferroic Bi5Ti3FeO15 thin films prepared by a chemical solution deposition route. J Appl Phys 109:06490110.1063/1.3553879 ↗
12. Liu Z, Yang J, Tang XW, Yin LH, Zhu XB, Dai JM, Sun YP (2012) Multiferroic properties of Aurivillius phase Bi6Fe2−x Co x Ti3O18 thin films prepared by a chemical solution deposition route. Appl Phys Lett 101:12240210.1063/1.4752748 ↗
13. Joshi PC, Desu SB (1996) Structural and electrical characteristics of rapid thermally processed ferroelectric Bi4Ti3O12 thin films prepared by metalorganic solution deposition technique. J Appl Phys 80:234910.1063/1.363069 ↗
14. Singh RS, Bhimasankaram T, Kumar GS, Suryanarayana SV (1994) Dielectric and magnetoelectric properties of Bi5FeTi3O15. Solid State Commun 91:56710.1016/0038-1098(94)90376-X ↗
15. Bai W, Zhu JY, Wang JL, Lin T, Yang J, Meng XJ, Tang XD, Zhu ZQ, Chu JH (2012) Effects of annealing temperature on the structures, ferroelectric and magnetic properties of Aurivillius Bi5Ti3FeO15 polycrystalline films. Magn J Magn Mater 324:226510.1016/j.jmmm.2012.02.113 ↗
16. Yuan B, Yang J, Zuo XZ, Song DP, Tang XW, Zhu XB, Dai JM, Song WH, Sun YP (2015) Ferrimagnetic and spin-glass transition in the Aurivillius compound SrBi5Ti4Cr0.5Co0.5O18. J Appl Phys 117:23390610.1063/1.4922869 ↗
17. Kim HJ, Kim JW, Choi JY, Kim EJ, Raghavan CM, Kim SS (2013) Structural and electrical investigations of aurivillius-phase La- and V-doped Bi5FeTi3O15 thin films. J Korean Phys Soc 63:233010.3938/jkps.63.2330 ↗
18. Chen G, Bai W, Sun L, Wu J, Ren Q, Xu WF, Yang J, Meng XJ, Tang XD, Duan CG, Chu JH (2013) Processing optimization and sintering time dependent magnetic and optical behaviors of Aurivillius Bi5Ti3FeO15 ceramics. J Appl Phys 113:03490110.1063/1.4775800 ↗
19. Tang K, Bai W, Liu J, Yang J, Zhang Y, Duan C-G, Tang X, Chu J (2015) The effect of Mn doping contents on the structural, dielectric and magnetic properties of multiferroic Bi5Ti3FeO15 Aurivillius ceramics. Ceram Int 41:S18510.1016/j.ceramint.2015.03.233 ↗
20. Mao XY, Wang W, Chen XB, Lu YL (2009) Multiferroic properties of layer-structured Bi5Fe0.5Co0.5Ti3O15 ceramics. Appl Phys Lett 95:08290110.1063/1.3213344 ↗
21. Sun H, Lu X, Xu T, Su J, Jin Y, Ju C (2012) Study of multiferroic properties in Bi5Fe0.5Co0.5Ti3O15 thin films. J Appl Phys 111:12411610.1063/1.4730892 ↗
22. Sun H, Xu T, Su J, Ju C (2012) The effect of process on ferroelectric and magnetic properties in Bi5Fe0.5Co0.5Ti3O15 thin films. Integr Ferroelectr 140:6410.1080/10584587.2012.741449 ↗
23. Mao XY, Sun H, Wang W, Chen XB, Lu YL (2013) Ferromagnetic, ferroelectric properties, and magneto-dielectric effect of Bi4.25La0.75Fe0.5Co0.5Ti3O15 ceramics. Appl Phys Lett 102:07290410.1063/1.4793305 ↗
24. Wang JL, Li L, Peng R, Fu Z, Liu M, Lu YL (2015) Structural evolution and multiferroics in Sr-doped Bi7Fe1.5Co1.5Ti3O21 ceramics. J Am Ceram Soc 98:152810.1111/jace.13495 ↗
25. Zuo XZ, Yang J, Song DP, Yuan B, Tang XW, Zhang KJ, Zhu XB, Song WH, Dai JM, Sun YP (2014) Magnetic, dielectric, and magneto-dielectric properties of rare-earth-substituted Aurivillius phase Bi6Fe1.4Co0.6Ti3O18. J Appl Phys 116:15410210.1063/1.4898318 ↗
26. Zhu Z, Li XN, Gu W, Wang JL, Huang HL, Peng RR, Zhai XF, Fu ZP, Lu YL (2016) Improving photocatalysis and magnetic recyclability in Bi5Fe0.95Co0.05Ti3O15 via europium doping. J Alloys Compd 686:30610.1016/j.jallcom.2016.06.012 ↗
27. Wu MS, Tian ZM, Yuan SL, Huang ZB (2012) Magnetic and optical properties of the Aurivillius phase Bi5Ti3FeO15. Mater Lett 68:19010.1016/j.matlet.2011.09.113 ↗
28. Chen C, Song K, Bai W, Yang J, Zhang YY, Xiang PH, Qin MY, Tang XD, Chu JH (2016) Effect of Nb and more Fe ions co-doping on the microstructures, magnetic, and piezoelectric properties of Aurivillius Bi5Ti3FeO15 phases. J Appl Phys 120:21410410.1063/1.4971256 ↗
29. Yang J, Yin LH, Shao DF, Zhu XB, Dai JM, Sun YP (2015) Magnetic and dielectric properties of Aurivillius phase Bi4.2Nd0.8Ti3Fe0.5Co0.5O15. Euro. Phys Lett 96:67006
30. Harikrishnan S, Naveen Kumar CM, Bhat HL, Elizabeth S, Rößler UK, Dörr K, Rößler S, Wirth S (2008) Investigations on the spin-glass state in Dy0.5Sr0.5MnO3 single crystals through structural, magnetic and thermal properties. J Phys Condens Matter 20:27523410.1088/0953-8984/20/27/275234 ↗
31. Kimura T, Ishihara S, Shintani H, Arima T, Takahashi KT, Ishizaka K, Tokura Y (2003) Distorted perovskite with e g 1 configuration as a frustrated spin system. Phys Rev B 68:06040310.1103/PhysRevB.68.060403 ↗
32. Zhang JT, Lu XM, Yang XQ, Wang JL, Zhu JS (2016) Origins of ↑↑↓↓ magnetic structure and ferroelectricity in multiferroic Lu2CoMnO6. Phys Rev B 93:07514010.1103/PhysRevB.93.075140 ↗
33. Vanga PR, Mangalaraja RV, Ashok M (2016) Effect of co-doping on the optical, magnetic and photocatalytic properties of the Gd modified BiFeO3. J Mater Sci Mater Electron 27:569910.1007/s10854-016-4481-x ↗
34. Yang J, Yin LH, Liu Z, Zhu XB, Song WH, Dai JM, Yang ZR, Sun YP (2012) Magnetic and dielectric properties of Aurivillius phase Bi6Fe2Ti3O18 and the doped compounds. Appl Phys Lett 101:01240210.1063/1.4732526 ↗
35. Li Z, Ma J, Gao ZP, Viola G et al (2016) Room temperature magnetoelectric coupling in intrinsic multiferroic Aurivillius phase textured ceramics. Dalton Trans 145:14094
36. Li Z, Huang Y, Liu M, Ge W et al (2014) Ferroelectric and ferromagnetic properties of Bi7−x La x Fe1.5Co1.5Ti3O21 ceramics prepared by the hot-press method. J Alloys Compd 600:16810.1016/j.jallcom.2014.02.122 ↗
37. Yang FJ, Su P, Wei C, Chen XQ, Yang CP, Cao WQ (2011) Large magnetic response in (Bi4Nd) Ti3(Fe0.5Co0.5) O15 ceramic at room-temperature. J Appl Phys 110:12610210.1063/1.3671418 ↗
38. Goodenough JB (1958) An interpretation of the magnetic properties of the perovskite-type mixed crystals La1−x Sr x CoO3. J Phys Chem Solid 6:28710.1016/0022-3697(58)90107-0 ↗
39. Brion D (1980) Etude par spectroscopie de photoelectrons de la degradation superficielle de FeS2, CuFeS2, ZnS et PbS a l’air et dans l’eau. Appl Surf Sci 5:13310.1016/0378-5963(80)90148-8 ↗
40. Kim KS (1975) X-ray-photoelectron spectroscopic studies of the electronic structure of CoO. Phys Rev B 11:217710.1103/PhysRevB.11.2177 ↗
41. Tan BJ, Klabunde KJ, Sherwood PMA (1991) XPS studies of solvated metal atom dispersed (SMAD) catalysts. Evidence for layered cobalt-manganese particles on alumina and silica. J Am Chem Soc 113:85510.1021/ja00003a019 ↗
42. Mao XY, Wang W, Chen XB (2008) Electrical and magnetic properties of Bi5FeTi3O15 compound prepared by inserting BiFeO3 into Bi4Ti3O12. Solid State Commun 147:18610.1016/j.ssc.2008.05.025 ↗
43. Li JB, Huang YP, Rao GH, Liu GY, Luo J, Chen JR, Liang JK (2010) Inhomogeneous structure and magnetic properties of aurivillius ceramics Bi4Bi n−3Ti3Fe n−3O3n+3. Appl Phys Lett 96:22290310.1063/1.3447372 ↗
44. Scott JF, Dawber M (2000) Oxygen-vacancy ordering as a fatigue mechanism in perovskite ferroelectrics. Appl Phys Lett 76:380110.1063/1.126786 ↗
45. Bhardwaj S, Paul J, Chand S, Raina KK, Kumar R (2014) Oxygen vacancy induced dielectric relaxation studies in Bi4−x La x Ti3O12 (x = 0.0, 0.3, 0.7, 1.0) ceramics. J Mater Sci Mater Electron 25:456810.1007/s10854-014-2205-7 ↗
46. Li W, Chen K, Yao YY, Zhu JS, Wang YN (2004) Correlation among oxygen vacancies in bismuth titanate ferroelectric ceramics. Appl Phys Lett 85:471710.1063/1.1823583 ↗
47. Padhan P, LeClair P, Gupta A, Srinivasan G (2008) Magnetodielectric response in epitaxial thin films of multiferroic Bi2NiMnO6. J Phys Condens Matter 20:35500310.1088/0953-8984/20/35/355003 ↗
48. Catalan G (2006) Magnetocapacitance without magnetoelectric coupling. Appl Phys Lett 88:10290210.1063/1.2177543 ↗