journal article·2024-05-28

Passivation Effect of CsPbBr3 Films Based on SnBr4 Post-Treatment

Xingming Yang, Junjie Jiang, Shuai Fu, Cuiping Xu, Peiqi Ji, Ziyi Xu, Kang Wang, Ligang Ma, Hongling Cai, Fengming Zhang, Xiaoshan Wu

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Abstract

The defect state and energy level matching in CsPbBr 3 perovskite solar cells (PSCs) are the main factors affecting the photoelectric conversion efficiency (PCE). In this work, we report a synergic post-treatment strategy based on SnBr 4 to simultaneously modulate the defect state and energy level arrangement, which can effectively suppress the charge recombination loss and reduce the barrier of interfacial charge extraction. Consequently, the carrier transport properties of the CsPbBr 3 PSCs are significantly improved. The all-inorganic CsPbBr 3 carbon-based PSCs without a hole transport layer optimized with SnBr 4 have achieved a champion efficiency of 8.29%, which increases larger by 33% in average.
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Research context

OpenAlex topics: Perovskite Materials and Applications · TiO2 Photocatalysis and Solar Cells · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing 210093, China

Institute of Materials Engineering, Nantong 226019, China

School of Electronic Engineering, Nanjing Xiaozhuang University, Nanjing 211171, China

Funding

Natural Science Foundation of Jiangsu Province · Science and Technology Project of Nantong City · National Natural Science Foundation of China · Applied Fundamental Research Foundation of Nantong City

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