journal article·2025-05-13Open access

Improving Light Stability of Nonfullerene Acceptor Inverted Organic Solar Cell by Incorporating a Mixed Nanocomposite Metal Oxide Electron Transporting Layer

Apostolos Ioakeimidis, Fedros Galatopoulos, Alina Hauser, Michael Rossier, Stelios A. Choulis

Abstract

High Resolution Image Download MS PowerPoint Slide We present significant light stability enhancement of nonfullerene acceptor inverted organic photovoltaics by incorporating a mixed nanocomposite metal oxide electron transporting layer. Using an appropriate mixture of ZnO:SnO 2 nanoparticles as an electron transporting layer in a PBDB-TF-T1 (T1):IT4F based organic solar cell device mitigates light induced photodegradation by lowering the defect formation at the active layer interface. We propose that the mixed metal oxide ETL act as hole scavengers that reduces the photocatalytic reaction of its surface. The optimized nanocomposite mixture of ZnO:SnO 2 10:90 (%V) provides higher light stability (ISOS-L2 protocol), prolonging the inverted OSCs lifetime (80% of the initial PCE, T80) by ∼16.5 times compared to the commonly used pristine ZnO electron transporting layer.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Molecular Electronics and Photonics Research Unit, Department of Mechanical Engineering and Materials Science and Engineering

Cyprus University of Technology

Avantama AG, Laubisruetistr. 50, Staefa 8712, Switzerland

Funding

H2020 LEIT Advanced Materials

References (38)

Show source-provided references
1. 10.1038/s41563-022-01244-y10.1038/s41563-022-01244-y ↗
2. 10.1039/D3EE00630A10.1039/D3EE00630A ↗
3. 10.1039/D3CS00492A10.1039/D3CS00492A ↗
4. 10.1016/j.rser.2017.12.00810.1016/j.rser.2017.12.008 ↗
5. 10.1002/adfm.20210015110.1002/adfm.202100151 ↗
6. 10.1002/advs.20190325910.1002/advs.201903259 ↗
7. 10.1038/s41586-019-1544-110.1038/s41586-019-1544-1 ↗
8. 10.1038/s41467-023-36937-810.1038/s41467-023-36937-8 ↗
9. 10.1007/s11426-021-1180-610.1007/s11426-021-1180-6 ↗
10. 10.1007/s11426-022-1256-810.1007/s11426-022-1256-8 ↗
11. 10.1002/smll.20180179310.1002/smll.201801793 ↗
12. 10.1016/j.mtener.2017.09.00810.1016/j.mtener.2017.09.008 ↗
13. 10.1039/C7CS00892A10.1039/C7CS00892A ↗
14. 10.1016/j.joule.2021.03.01410.1016/j.joule.2021.03.014 ↗
15. 10.1039/D0EE02503H10.1039/D0EE02503H ↗
16. 10.1063/5.009167110.1063/5.0091671 ↗
17. 10.1039/C6TA00909C10.1039/C6TA00909C ↗
18. 10.1016/j.orgel.2021.10613910.1016/j.orgel.2021.106139 ↗
19. 10.1002/eom2.1215610.1002/eom2.12156 ↗
20. 10.1002/anie.20220739710.1002/anie.202207397 ↗
21. 10.1002/adfm.20230795810.1002/adfm.202307958 ↗
22. 10.1021/acs.jpclett.1c0027610.1021/acs.jpclett.1c00276 ↗
23. 10.1016/j.scib.2019.10.01910.1016/j.scib.2019.10.019 ↗
24. 10.1002/eem2.1271210.1002/eem2.12712 ↗
25. 10.1039/C9MH00379G10.1039/C9MH00379G ↗
26. 10.1021/acsami.3c1580110.1021/acsami.3c15801 ↗
27. 10.1016/j.solmat.2011.01.03610.1016/j.solmat.2011.01.036 ↗
28. 10.1016/j.saa.2014.09.09210.1016/j.saa.2014.09.092 ↗
29. 10.1016/j.cap.2019.12.00410.1016/j.cap.2019.12.004 ↗
30. 10.1002/adfm.20180275710.1002/adfm.201802757 ↗
31. 10.1016/j.nanoen.2023.10903210.1016/j.nanoen.2023.109032 ↗
32. 10.1002/aenm.20160132010.1002/aenm.201601320 ↗
33. 10.1039/D0TA03016C10.1039/D0TA03016C ↗
34. 10.1016/j.orgel.2018.09.02510.1016/j.orgel.2018.09.025 ↗
35. 10.31635/ccschem.021.20210085210.31635/ccschem.021.202100852 ↗
36. 10.1039/D1SC07269B10.1039/D1SC07269B ↗
37. 10.1039/D0RA03233F10.1039/D0RA03233F ↗
38. 10.1039/C9TA07417A10.1039/C9TA07417A ↗