journal article·2021-06

The multi-ferroelectricity in neodymium ferrite with perovskite structure

Chao Zhao, Jiahui Chen, Qingfeng Ding, Mingyu Shang

Journal of Materials Science· Volume 56· Issue 17
Publisher page

Abstract

In this paper, single-phase orthoferrite NdFeO3 crystals with the space group of Pbnm were successful prepared via mild hydrothermal method. The NdFeO3 crystal performs a weak antiferromagnetic behavior by magnetic measurement. The Dzyaloshinskii Moriya interaction in NdFeO3 crystal causes an additional canting of the antiferromagnetically ordered spins which induce the ferroelectricity. The saturation electric polarization result is 0.0163 μC/cm2 with coercive field of 6.68 kV/cm, and the Curie temperature is 430 K. So we present the direct experimental evidences that the NdFeO3 sample simultaneously exists the ferroelectricity and weak antiferromagnetic at room temperature. This work can develop a route to obtain more species of multiferroic compounds with perovskite structure.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Multiferroics and related materials · Ferroelectric and Piezoelectric Materials · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (49)

Show source-provided references
1. Spaldin NA, Cheong SW, Ramesh R (2010) Multiferroics: past, present, and future[J]. Phys Today 63(10):38–4310.1063/1.3502547 ↗
2. Ye S, Labelle J, Yoon PH et al (2007) Experimental tests of the eigenmode theory of auroral roar fine structure and its application to remote sensing[J]. J Geophys Res Space Phys 112(A12):1–13
3. Eerenstein W, Mathur ND, Scott JF (2006) Multiferroic and magnetoelectric materials J. Nature 442(7104): 759–76510.1038/nature05023 ↗
4. Hoffman J, Pan X, Reiner JW et al (2010) Ferroelectric field effect transistors for memory applications[J]. Adv Mater 22(26–27):2957–296110.1002/adma.200904327 ↗
5. Lu H, Bark CW, De Los ODE et al (2012) Mechanical writing of ferroelectric polarization[J]. Science 336(6077):59–6110.1126/science.1218693 ↗
6. Garcia V, Bibes M (2014) Ferroelectric tunnel junctions for information storage and processing[J]. Nat Commun 5(1):1–1210.1038/ncomms5289 ↗
7. Sharma P, Zhang Q, Sando D et al (2017) Nonvolatile ferroelectric domain wall memory[J]. Sci Adv 3(6):e170051210.1126/sciadv.1700512 ↗
8. Wu J, Wang N, Yan X, et al (2020) Emerging low-dimensional materials for mid-infrared detection J. Nano Res. Doi: https://doi.org/10.1007/s12274-020-3128-710.1007/s12274-020-3128-7 ↗
9. Wang X, Yu P, Lei Z et al (2019) Van der Waals negative capacitance transistors[J]. Nat Commun 10(1):1–810.1038/s41467-018-07882-8 ↗
10. Cheong SW, Mostovoy M (2007) Multiferroics: a magnetic twist for ferroelectricity[J]. Nat Mater 6(1):13–2010.1038/nmat1804 ↗
11. Ramesh R, Spaldin N A. Multiferroics: progress and prospects in thin films[J]. Nanoscience And Technology: A Collection of Reviews from Nature Journals, 2010: 20-28
12. Tokura Y (2007) Multiferroics—toward strong coupling between magnetization and polarization in a solid[J]. J Magn Magn Mater 310(2):1145–115010.1016/j.jmmm.2006.11.198 ↗
13. Catalan G, Scott JF (2009) Physics and applications of bismuth ferrite[J]. Adv Mater 21(24):2463–248510.1002/adma.200802849 ↗
14. Wang KF, Liu JM, Ren ZF (2009) Multiferroicity: the coupling between magnetic and polarization orders[J]. Adv Phys 58(4):321–44810.1080/00018730902920554 ↗
15. Tokura Y, Seki S (2010) Multiferroics with spiral spin orders[J]. Adv Mater 22(14):1554–156510.1002/adma.200901961 ↗
16. Fiebig M (2005) Revival of the magnetoelectric effect[J]. J Phys D Appl Phys 38(8):R12310.1088/0022-3727/38/8/R01 ↗
17. Tokura Y, Kida N (1951) Dynamical magnetoelectric effects in multiferroic oxides[J]. Philos Trans R Soc A: Math, Phys Eng Sci 2011(369):3679–3694
18. Vinnik DA, Zhivulin VE, Uchaev DA et al (2021) Effect of titanium substitution and temperature variation on structure and magnetic state of barium hexaferrites[J]. J Alloy Compd 859:15836510.1016/j.jallcom.2020.158365 ↗
19. Kozlovskiy AL, Kenzhina IE, Zdorovets MV (2020) FeCo–Fe2CoO4/Co3O4 nanocomposites: phase transformations as a result of thermal annealing and practical application in catalysis[J]. Ceram Int 46(8):10262–1026910.1016/j.ceramint.2020.01.019 ↗
20. Yin L, Mi W (2020) Progress in BiFeO3-based heterostructures: materials, properties and applications[J]. Nanoscale 12(2):477–52310.1039/C9NR08800H ↗
21. Yin L, Wang X, Mi W (2017) Electric-field tunable perpendicular magnetic anisotropy in tetragonal Fe4N/BiFeO3 heterostructures[J]. Appl Phys Lett 111(3):03240410.1063/1.4993907 ↗
22. Zatsiupa AA, Bashkirov LA, Troyanchuk IO et al (2014) Magnetization, magnetic susceptibility, effective magnetic moment of Fe3+ ions in Bi25FeO39 ferrite[J]. J Solid State Chem 212:147–15010.1016/j.jssc.2014.01.019 ↗
23. Karpinsky DV, Silibin MV, Trukhanov SV et al (2020) Peculiarities of the crystal structure evolution of BiFeO3-BaTiO3 ceramics across structural phase transitions[J]. Nanomaterials 10(4):80110.3390/nano10040801 ↗
24. Shvartsman VV, Kleemann W, Haumont R et al (2007) Large bulk polarization and regular domain structure in ceramic BiFeO3[J]. Appl Phys Lett 90(17):17211510.1063/1.2731312 ↗
25. Wang J, Neaton J B, Zheng H, et al (2003) Epitaxial BiFeO3 multiferroic thin film heterostructures[J]. Science 299(5613): 1719–1722.10.1126/science.1080615 ↗
26. Trukhanov A V, Trukhanov S V, Panina L V, et al (2017) Evolution of structure and magnetic properties for BaFe11.9Al0.1019 hexaferrite in a wide temperature range[J]. J Magn Magn Mater 426: 487–49610.1016/j.jmmm.2016.10.140 ↗
27. Turchenko V, Kostishyn VG, Trukhanov S et al (2020) Crystal and magnetic structures, magnetic and ferroelectric properties of strontium ferrite partially substituted with in ions[J]. J Alloy Compd 821:15341210.1016/j.jallcom.2019.153412 ↗
28. Bersuker IB (2012) Pseudo jahn-teller origin of perovskite multiferroics, magnetic-ferroelectric crossover, and magnetoelectric effects: The d0–d10 problem[J]. Phys Rev Lett 108(13):13720210.1103/PhysRevLett.108.137202 ↗
29. Tokunaga Y, Taguchi Y, Arima T et al (2012) Electric-field-induced generation and reversal of ferromagnetic moment in ferrites[J]. Nat Phys 8(11):838–84410.1038/nphys2405 ↗
30. Zhao ZY, Wang XM, Fan C et al (2011) Magnetic phase transitions and magnetoelectric coupling of GdFeO3 single crystals probed by low-temperature heat transport[J]. Phys Rev B 83(1):01441410.1103/PhysRevB.83.014414 ↗
31. Acharya S, Mondal J, Ghosh S et al (2010) Multiferroic behavior of lanthanum orthoferrite (LaFeO3)[J]. Mater Lett 64(3):415–41810.1016/j.matlet.2009.11.037 ↗
32. Tokunaga Y, Furukawa N, Sakai H et al (2009) Composite domain walls in a multiferroic perovskite ferrite[J]. Nat Mater 8(7):558–56210.1038/nmat2469 ↗
33. Iida S, Ohbayashi K, Kagoshima S. Magnetism of rare earth orthoferrites as revealed from critical phenomena observation[J]. Le Journal de Physique Colloques, 1971, 32(C1): C1–654-C1–656.
34. Lee JH, Jeong YK, Park JH et al (2011) Spin-canting-induced improper ferroelectricity and spontaneous magnetization reversal in SmFeO3[J]. Phys Rev Lett 107(11):11720110.1103/PhysRevLett.107.117201 ↗
35. Tokunaga Y, Iguchi S, Arima T et al (2008) Magnetic-field-induced ferroelectric state in DyFeO3[J]. Phys Rev Lett 101(9):09720510.1103/PhysRevLett.101.097205 ↗
36. Shang M, Zhang C, Zhang T et al (2013) The multiferroic perovskite YFeO3[J]. Appl Phys Lett 102(6):06290310.1063/1.4791697 ↗
37. Wang PJ, Zhou D, Guo HH et al (2020) Ultrahigh enhancement rate of the energy density of flexible polymer nanocomposites using core-shell BaTiO3@MgO structures as the filler[J]. J Mater Chem A 8(22):11124–1113210.1039/D0TA03304A ↗
38. Shlimas DI, Zdorovets MV, Kozlovskiy AL (2020) Synthesis and resistance to helium swelling of Li2TiO3 ceramics[J]. J Mater Sci: Mater Electron 31(15):12903–12912
39. Trukhanov S V, Khomchenko V A, Lobanovski L S, et al (2006) Crystal structure and magnetic properties of Ba-ordered manganites Ln0.70Ba0.30MnO3-δ (Ln=Pr, Nd)[J]. J Exp Theor Phys 103(3): 398–41010.1134/S1063776106090093 ↗
40. Kozlovskiy AL, Zdorovets MV (2020) The study of the structural characteristics and catalytic activity of Co/CoCo2O4 nanowires[J]. Compos B Eng 191:10796810.1016/j.compositesb.2020.107968 ↗
41. Troyanchuk I O, Trukhanov S V, Khalyavin D D, et al (2000) Magnetic properties of anion deficit manganites Ln0. 55Ba0. 45MnO3-γ (Ln= La, Nd, Sm, Gd, γ⩽0.37)[J]. J Magn Magn Mater 208(3): 217–22010.1016/S0304-8853(99)00529-6 ↗
42. Zdorovets MV, Kozlovskiy AL (2020) The effect of lithium doping on the ferroelectric properties of LST ceramics[J]. Ceram Int 46(10):14548–1455710.1016/j.ceramint.2020.02.254 ↗
43. Yamashita T, Hayes P (2006) Effect of curve fitting parameters on quantitative analysis of Fe0.94O and Fe2O3 using XPS[J]. J Electron Spectrosc Relat Phenom, 152(1–2): 6–1110.1016/j.elspec.2006.02.002 ↗
44. Parida SC, Rakshit SK, Singh Z (2008) Heat capacities, order–disorder transitions, and thermodynamic properties of rare-earth orthoferrites and rare-earth iron garnets[J]. J Solid State Chem 181(1):101–12110.1016/j.jssc.2007.11.003 ↗
45. Troyanchuk IO, Khalyavin DD, Trukhanov SV et al (1999) Magnetic phase diagrams of the manganites Ln1-xBaxMnO3 (Ln=Nd, Sm)[J]. J Phys: Condens Matter 11(44):8707
46. Trukhanov S V, Trukhanov A V, Vasil’ev A N, et al (2007) Critical behavior of La0.825Sr0.175MnO2.912 anion-deficient manganite in the magnetic phase transition region[J]. JETP Lett 85(10): 507–51210.1134/S0021364007100086 ↗
47. Sławiński W, Przeniosło R, Sosnowska I et al (2005) Spin reorientation and structural changes in NdFeO3[J]. J Phys: Condens Matter 17(29):4605
48. Vinnik DA, Podgornov FV, Zabeivorota NS et al (2020) Effect of treatment conditions on structure and magnetodielectric properties of barium hexaferrites[J]. J Magn Magn Mater 498:16619010.1016/j.jmmm.2019.166190 ↗
49. Trukhanov AV, Astapovich KA, Almessiere MA et al (2020) Pecularities of the magnetic structure and microwave properties in Ba(Fe-xScx) O (x<) hexaferrites [J]. J Alloys Comp 822: 15357510.1016/j.jallcom.2019.153575 ↗