journal article·2022-08

Controlled synthesis of CuS-decorated CuO pillars over Cu mesh with improved wettability, photothermal and photocatalytic properties

Chen Wang, Weiran Xu, Chao Xu, Qi Zhang, Zhicheng Zhang, Xueqi Wang, Zhao Fan, Xudong Xiong

Journal of Materials Science· Volume 57· Issue 32
Publisher page

Abstract

Studies have shown that semiconductor compound photocatalysts have a wide range of promising applications in the treatment of environmental pollution. Meanwhile, in nature, the leaves of green plants are almost always lamellar, and photosynthesis in leaves is the most common solar energy conversion system, which involves the process of light absorption and conversion. In this paper, CuS/CuO nanorod arrays with plant-like structures were prepared on Cu mesh by in situ oxidation and successive ion layer adsorption and reaction (SILAR) method. The effects of oxidation temperature, annealing time and SILAR cycle on the structure and properties of CuS/CuO/Cu Mesh were investigated, and the mechanism of photothermal effect and photocatalysis was further analyzed. The experimental results show that the layered nanostructure and porous morphology of CuS/CuO/Cu mesh can reduce photon spillage and have better photothermal, wettability and photocatalytic properties. CuS/CuO/Cu mesh degraded MB and MO up to 92.7% and 86% in 180 min, while it still has good stability after 8 cycles. Compared with powder and microbial catalyst, CuS/CuO/Cu mesh has the advantages of brief preparation time, good stability, reusable, and no secondary pollution, which can bring greater economic benefits and better sewage treatment effect.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Copper-based nanomaterials and applications · Advanced Photocatalysis Techniques · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (58)

Show source-provided references
1. Chong MN, Jin B, Chow C, Saint C (2010) Recent developments in photocatalytic water treatment technology: a review. Water Res 44:2997–3027. https://doi.org/10.1016/j.watres.2010.02.03910.1016/j.watres.2010.02.039 ↗
2. Senobari S, Nezamzadeh-Ejhieh A (2018) A comprehensive study on the photocatalytic activity of coupled copper oxide-cadmium sulfide nanoparticles. Spectrochim Acta Part A: Molecul Biomol Spectrosc 196:334–343. https://doi.org/10.1016/j.saa.2018.02.04310.1016/j.saa.2018.02.043 ↗
3. Arora C, Soni S, Sahu S et al (2019) Iron based metal organic framework for efficient removal of methylene blue dye from industrial waste. J Mol Liq 284:343–352. https://doi.org/10.1016/j.molliq.2019.04.01210.1016/j.molliq.2019.04.012 ↗
4. Valley BJ, Jing BX, Ferreira M, Zhu YX (2019) Rapid and efficient coacervate extraction of cationic industrial dyes from wastewater. ACS Appl Mater Inter 11:7472–7478. https://doi.org/10.1021/acsami.8b2167410.1021/acsami.8b21674 ↗
5. Tan L, He MY, Song L et al (2016) Aerobic decolorization, degradation and detoxification of azo dyes by anewly isolated salt-tolerant yeast Scheffersomyces spartinae TLHS-SF1. Bioresource Technol 203:287–294. https://doi.org/10.1016/j.biortech.2015.12.05810.1016/j.biortech.2015.12.058 ↗
6. Fu JW, Chen ZH, Wang MH et al (2015) Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis. Chem Eng J 259:53–61. https://doi.org/10.1016/j.cej.2014.07.10110.1016/j.cej.2014.07.101 ↗
7. Landaburu AJ, Pongracz E, Peramaki P, Keiski R (2010) Micellar-enhanced ultrafiltration for the removal of cadmium and zinc: use of response surface methodology to improve understanding of process performance and optimisation. J Hazard Mater 180:524–534. https://doi.org/10.1016/j.jhazmat.2010.04.06610.1016/j.jhazmat.2010.04.066 ↗
8. Singh J, Soni RK (2021) Efficient charge separation in Ag nanoparticles functionalized ZnO nanoflakes/CuO nanoflowers hybrids for improved photocatalytic and SERS activity. Colloid Surface A 626:127005. https://doi.org/10.1016/j.colsurfa.2021.12700510.1016/j.colsurfa.2021.127005 ↗
9. Singh J, Juneja S, Soin RK, Bhattacharya J (2021) Sunlight mediated enhanced photocatalytic activity of TiO2 nanoparticles functionalized CuO–Cu2O nanorods for removal of methylene blue and oxytetracycline hydrochloride. J Colloid Interf Sci 590:60–71. https://doi.org/10.1016/j.jcis.2021.01.02210.1016/j.jcis.2021.01.022 ↗
10. Singh J, Manna AK, Soni RK (2020) Sunlight driven photocatalysis and non-enzymatic glucose sensing performance of cubic structured CuO thin films. Appl Surf Sci 530:147258. https://doi.org/10.1016/j.apsusc.2020.14725810.1016/j.apsusc.2020.147258 ↗
11. Su Z, Lin J, Zhang D, Ye P et al (2019) Novel flexible fenton-like catalyst: unique CuO nanowires arrays on copper mesh with high efficiency across a wide pH range. Sci Total Environ 647:587–596. https://doi.org/10.1016/j.scitotenv.2018.08.02210.1016/j.scitotenv.2018.08.022 ↗
12. Wang CC, Li JR, Lv XL et al (2014) Photocatalytic organic pollutants degradation in metal–organic frameworks. Energy Environ Sci 7:2831–2867. https://doi.org/10.1039/C4EE01299B10.1039/C4EE01299B ↗
13. Zhu H, Cai H, Liao GF et al (2021) Recent advances in photocatalysis based on bioinspired superwettabilities. Acs Catal 11:14751–14771. https://doi.org/10.1021/acscatal.1c0404910.1021/acscatal.1c04049 ↗
14. Rao MP, Wu JJ, Asiri AM et al (2018) Photocatalytic properties of hierarchical CuO nanosheets synthesized by a solution phase method. J Environ Sci 69:115–124. https://doi.org/10.1016/j.jes.2017.05.00510.1016/j.jes.2017.05.005 ↗
15. Liu XM, Yang G, Fu SY (2007) Mass synthesis of nanocrystalline spinel ferrites by a polymer-pyrolysis route. Mat Sci Eng C-Mater 27:750–755. https://doi.org/10.1016/j.msec.2006.07.02610.1016/j.msec.2006.07.026 ↗
16. Yang LF, Chu DQ, Wang L (2016) CuO core–shell nanostructures: precursor-mediated fabrication and visible-light induced photocatalytic degradation of organic pollutants. Powder Technol 287:346–354. https://doi.org/10.1016/j.powtec.2015.10.01110.1016/j.powtec.2015.10.011 ↗
17. Vaseem M, Umar A, Hahn YB et al (2008) Flower-shaped CuO nanostructures: structural, photocatalytic and xanes studies. Catal Commun 10:11–16. https://doi.org/10.1016/j.catcom.2008.07.02210.1016/j.catcom.2008.07.022 ↗
18. Chaudhary GR, Bansal P, Kaur N, Mehta SK (2014) Recyclable CuO nanoparticles as heterogeneous catalysts for the synthesis of xanthenes under solvent free conditions. Rsc Adv 4:49462. https://doi.org/10.1002/chin.20151519410.1002/chin.201515194 ↗
19. Singh J, Soni RK (2020) Controlled synthesis of CuO decorated defect enriched ZnO nanoflakes for improved sunlight-induced photocatalytic degradation of organic pollutants. Appl Surf Sci 521:146420. https://doi.org/10.1016/j.apsusc.2020.14642010.1016/j.apsusc.2020.146420 ↗
20. Bu IY, Huang R (2017) Fabrication of CuO-decorated reduced graphene oxide nanosheets for supercapacitor applications. Ceram Int 43:45–50. https://doi.org/10.1016/j.ceramint.2016.08.13610.1016/j.ceramint.2016.08.136 ↗
21. Zuo C, Ding L (2015) Solution-processed Cu2O and CuO as hole transport materials for efficient perovskite solar cells. Small 11:5528–5532. https://doi.org/10.1002/smll.20150133010.1002/smll.201501330 ↗
22. Ejhieh AN, Hushmandrad S (2010) Solar photodecolorization of methylene blue by CuO/X zeolite as a heterogeneous catalyst. Appl Catal A-Gen 388:149–159. https://doi.org/10.1016/j.apcata.2010.08.04210.1016/j.apcata.2010.08.042 ↗
23. Ejhieh AN, Salimi Z (2010) Heterogeneous photodegradation catalysis of o-phenylenediamine using CuO/X zeolite. Appl Catal A-Gen 390:110–118. https://doi.org/10.1016/j.apcata.2010.09.03810.1016/j.apcata.2010.09.038 ↗
24. Calace N, Nardi E, Petronio BM, Pietroletti M et al (2002) Adsorption of phenols by papermill sludges. Environ Pollut 118:315–319. https://doi.org/10.1016/S0269-7491(01)00303-710.1016/S0269-7491(01)00303-7 ↗
25. Cai Y, Yang F, Lili Wu et al (2021) Hydrothermal-ultrasonic synthesis of CuO nanorods and CuWO4 nanoparticles for catalytic reduction, photocatalysis activity, and antibacterial properties. Mater Chem Phys 258:123919. https://doi.org/10.1016/j.matchemphys.2020.12391910.1016/j.matchemphys.2020.123919 ↗
26. Yang Y, Xu D, Wu QY, Diao P (2016) Cu2O/CuO bilayered composite as a high-efficiency photocathode for photoelectrochemical hydrogen evolution reaction. Sci Rep-Uk 6:35158. https://doi.org/10.1038/srep3515810.1038/srep35158 ↗
27. Li W, Li YX, Zhang DY et al (2020) CuO-Co3O4 @ CeO2 as a heterogeneous catalyst for efficient degradation of 2,4-dichlorophenoxyacetic acid by peroxymonosulfate. J Hazard Mater 381:121209. https://doi.org/10.1016/j.jhazmat.2019.12120910.1016/j.jhazmat.2019.121209 ↗
28. Zou LL, Shen XQ, Wang QJ et al (2015) Preparation, magnetic and electrochemical properties of xCuFe2O4/CuO composite microfibers. J Sol-Gel Sci Techn 75:54–62. https://doi.org/10.1007/s10971-015-3675-710.1007/s10971-015-3675-7 ↗
29. Yuan S, Huang XL, Ma DL et al (2014) Engraving copper foil to give large-scale binder-free porous CuO arrays for a high-performance sodium-ion battery anode. Adv Mater 26:2273–2279. https://doi.org/10.1002/adma.20130446910.1002/adma.201304469 ↗
30. Liu Y, Cao XY, Jiang DG et al (2018) Hierarchical CuO nanorod arrays in situ generated on three-dimensional copper foam via cyclic voltammetry oxidation for high-performance supercapacitors. J Mater Chem A 6:10474. https://doi.org/10.1039/C8TA00945G10.1039/C8TA00945G ↗
31. Li QQ, Sun QY, Li YH et al (2020) Solar-heating crassula perforata-structured superoleophilic CuO@CuS/PDMS nanowire arrays on copper foam for fast remediation of viscous crude oil spill. ACS Appl Mater Inter 12:19476–19482. https://doi.org/10.1021/acsami.0c0120710.1021/acsami.0c01207 ↗
32. Moosavifard SF, El-Kady MF, Rahmanifar MS et al (2015) Designing 3D highly ordered nanoporous CuO electrodes for high-performance asymmetric supercapacitors. ACS Appl Mater Inter 7:4851–4860. https://doi.org/10.1021/am508816t10.1021/am508816t ↗
33. Liu P, Huang Y, Yan J et al (2016) Construction of CuS nanoflakes vertically aligned on magnetically decorated graphene and their enhanced microwave absorption properties. ACS Appl Mater Inter 8:5536–5546. https://doi.org/10.1021/acsami.5b1051110.1021/acsami.5b10511 ↗
34. Zhang L, Yang Z, Zhu W et al (2017) Dual-stimuli-responsive, polymer-microsphere-encapsulated CuS nanoparticles for magnetic resonance imaging guided synergistic chemo-photothermal therapy. ACS Biomater Sci Eng 3:1690–1701. https://doi.org/10.1021/acsbiomaterials.7b0020410.1021/acsbiomaterials.7b00204 ↗
35. Jia SF, Li XY, Zhang BP et al (2019) TiO2/CuS heterostructure nanowire array photoanodes toward water oxidation: the role of CuS. Appl Surf Sci 463:829–837. https://doi.org/10.1016/j.apsusc.2018.09.00310.1016/j.apsusc.2018.09.003 ↗
36. Guo L, Sun Q, Marcus K et al (2018) Photocatalytic glycerol oxidation on AuxCu–CuS@TiO2 plasmonic heterostructures. J Mater Chem A 6:22005. https://doi.org/10.1039/C8TA02170H10.1039/C8TA02170H ↗
37. Tian JT, Zhang W, Gu JJ et al (2015) Bioinspired Au–CuS coupled photothermal materials: enhanced infrared absorption and photothermal conversion from butterfly wings. Nano Energy 17:52–62. https://doi.org/10.1016/j.nanoen.2015.07.02710.1016/j.nanoen.2015.07.027 ↗
38. Sun Y, Gao JP, Liu Y et al (2019) Copper sulfide-macroporous polyacrylamide hydrogel for solar steam generation. Chem Eng Sci 207:516–526. https://doi.org/10.1016/j.ces.2019.06.04410.1016/j.ces.2019.06.044 ↗
39. Wang ZJ, Yu WJ, Yu N et al (2020) Construction of CuS@Fe-MOF nanoplatforms for mri-guided synergistic photothermal-chemo therapy of tumors. Chem Eng J 400:125877. https://doi.org/10.1016/j.cej.2020.12587710.1016/j.cej.2020.125877 ↗
40. Liang S, Deng XR, Chang Y et al (2019) Intelligent hollow Pt-CuS janus architecture for synergistic catalysis-enhanced sonodynamic and photothermal cancer therapy. Nano Lett 19:4134–4145. https://doi.org/10.1021/acs.nanolett.9b0159510.1021/acs.nanolett.9b01595 ↗
41. Cao F, Pan ZH, Ji XH (2019) Enhanced photocatalytic activity of a pine-branch-like ternary CuO/CuS/ZnO heterostructure under visible light irradiation. New J Chem 43:11342. https://doi.org/10.1039/C9NJ01785B10.1039/C9NJ01785B ↗
42. Kao YT, Yang SM, Lu KC (2019) Synthesis and photocatalytic properties of CuO-CuS core-shell nanowires. Materials 12:1106. https://doi.org/10.3390/ma1207110610.3390/ma12071106 ↗
43. Zhang L, Liu YN, Zhou MJ, Yan JH (2013) Improving photocatalytic hydrogen evolution over CuO/Al2O3 by platinum-depositing and CuS-loading. Appl Surf Sci 282:531–537. https://doi.org/10.1016/j.apsusc.2013.06.00610.1016/j.apsusc.2013.06.006 ↗
44. Liu Y, Liu J, Zhang QH et al (2021) CuO/Ag2S/CuS nanohybrids-integrated photoelectric and photothermal effects for ultrasensitive detection of inorganic pyrophosphatase. Adv Funct Mater 32(5):2106854. https://doi.org/10.1002/adfm.20210685410.1002/adfm.202106854 ↗
45. Wu CC, Sun YG, Cui Z et al (2020) Fabrication of CuS/CuO nanowire heterostructures on copper mesh with improved visible light photocatalytic properties. J Phys Chem Solids 140:109355. https://doi.org/10.1016/j.jpcs.2020.10935510.1016/j.jpcs.2020.109355 ↗
46. Dubale AD, Tamirat AG, Chen HM et al (2016) A highly stable CuS and CuS–Pt modified Cu2O/CuO heterostructure as an efficient photocathode for the hydrogen evolution reaction. J Mater Chem A 4:2205. https://doi.org/10.1039/C5TA09464J10.1039/C5TA09464J ↗
47. Zhang QB, Zhang K, Xu DG et al (2014) CuO nanostructures: Synthesis, characterization, growth mechanisms, fundamental properties, and applications. Prog Mater Sci 60:208–337. https://doi.org/10.1016/j.pmatsci.2013.09.00310.1016/j.pmatsci.2013.09.003 ↗
48. Kameyama N, Senna M (2014) Effects of aging temperature on the size and morphology of Cu(OH)2 and CuO nanoparticles. J Nanopart Res 16:2584. https://doi.org/10.1007/s11051-014-2584-y10.1007/s11051-014-2584-y ↗
49. Yang C, Cao XD, Wang SJ et al (2015) Complex-directed hybridization of CuO/ZnO nanostructures and their gas sensing and photocatalytic properties. Ceram Int 41:1749–1756. https://doi.org/10.1016/j.ceramint.2014.09.12010.1016/j.ceramint.2014.09.120 ↗
50. Wang YP, Ge ZH, Li X et al (2020) Cu2S nanorod arrays with coarse surfaces to enhance the electrochemically active surface area for water oxidation. J Colloid Interf Sci 567:308–315. https://doi.org/10.1016/j.jcis.2020.02.03010.1016/j.jcis.2020.02.030 ↗
51. Fan MH, Gao RQ, Zou YC et al (2016) An efficient nanostructured copper(I) sulfide-based hydrogen evolution electrocatalyst at neutral Ph. Electrochim Acta 215:366–373. https://doi.org/10.1016/j.electacta.2016.08.12910.1016/j.electacta.2016.08.129 ↗
52. Li GX, Sun JH, Hou WP et al (2016) Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium–sulfur batteries. Nat Commun 7:10601. https://doi.org/10.1038/ncomms1060110.1038/ncomms10601 ↗
53. Jia SF, Li XY, Zhang BP et al (2019) TiO2 /CuS heterostructure nanowire array photoanodes toward water oxidation: the role of CuS. Appl Surf Sci 463:829–837. https://doi.org/10.1016/j.apsusc.2018.09.00310.1016/j.apsusc.2018.09.003 ↗
54. Si YF, Dong ZC, Jiang L (2018) Bioinspired designs of superhydrophobic and superhydrophilic materials. ACS Central Sci 4:1102–1112. https://doi.org/10.1021/acscentsci.8b0050410.1021/acscentsci.8b00504 ↗
55. Li XY, Pi YH, Wu LQ et al (2017) Facilitation of the visible light-induced Fenton-like excitation of H2O2 via heterojunction of g-C3N4/NH2-Iron terephthalate metal-organic framework for MB degradation. Appl Catal B-Environ 202:653–663. https://doi.org/10.1016/j.apcatb.2016.09.07310.1016/j.apcatb.2016.09.073 ↗
56. Nikzad-Langerodi R, Zellinger W, Saminger-Platz S et al (2020) Domain adaptation for regression under Beer–Lambert’s law. Knowl-Based Syst 210:106447. https://doi.org/10.1016/j.knosys.2020.10644710.1016/j.knosys.2020.106447 ↗
57. Lai C, Zhang MM, Li BS et al (2019) Fabrication of CuS/BiVO4 (040) binary heterojunction photocatalysts with enhanced photocatalytic activity for Ciprofloxacin degradation and mechanism insight. Chem Eng J 358:891–902. https://doi.org/10.1016/j.cej.2018.10.07210.1016/j.cej.2018.10.072 ↗
58. Dubale AA, Su WN, Tamirat AG et al (2014) The synergetic effect of graphene on Cu2O nanowire arrays as a highly efficient hydrogen evolution photocathode in water splitting. J Mater Chem A 2:18383. https://doi.org/10.1039/C4TA03464C10.1039/C4TA03464C ↗