Lead-free X8R-type 0.92Ba0.8Sr0.2TiO3-0.08Bi(Mg0.5Zr0.5)O3 dielectric energy-storage ceramics for pulsed power capacitors
Source abstract
Abstract
Dielectric ceramic capacitors, as one kind of important electrical energy-storage device, have been widely used because of their high-power density and low cost. It is a key challenge and of great significance to develop dielectric ceramic capacitors with high energy-storage density within a wide operate temperature range. In this work, the effect of the Bi(Mg0.5Zr0.5)O3 addition on the dielectric and energy-storage properties of lead-free Ba0.8Sr0.2TiO3 ceramics was systematically studied. It can be found that with increasing Bi(Mg0.5Zr0.5)O3 content, an increase in dielectric temperature stability as a result of the addition of Bi(Mg0.5Zr0.5)O3 can accompany the formation of the long-range ordered ferroelectric domain into polar nanoregions and also conform to a decrease in remanent polarization and an increase in energy-storage properties. As a result, for the composition 0.92Ba0.8Sr0.2TiO3-0.08Bi(Mg0.5Zr0.5)O3, a stable dielectric constant in a temperature range of −100–151 °C was achieved. Furthermore, a large recoverable energy-storage density value (3.44 J/cm3) and a high-power density value (541 MW/cm3) were obtained simultaneously in the above ceramic composition. All these features suggest that the 0.92Ba0.8Sr0.2TiO3-0.08Bi(Mg0.5Zr0.5)O3 ceramics might be ideal materials for potential applications of high energy-storage capacitors.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Dielectric materials and actuators · Acoustic Wave Resonator Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (55)
Show source-provided references
1. Hui KZ, Chen LL, Cen ZY, Zhao PY, Yu Y, Guo LM, Wang XH, Li LT (2021) KNN based high dielectric constant X9R ceramics with fine grain structure and energy storage ability. J Am Ceram Soc 104:5815–5825. https://doi.org/10.1111/jace.1797010.1111/jace.17970 ↗
2. Cui CW, Pu YP, Li X, Cui YF, Liu G (2018) High energy storage density of temperature-stable X9R ceramics. Mater Res Bull 105:114–120. https://doi.org/10.1016/j.materresbull.2018.04.04310.1016/j.materresbull.2018.04.043 ↗
3. Li TY, Qiao ZL, Zuo RZ (2022) X9R-type Ag1-3xBixNbO3 based lead-free dielectric ceramic capacitors with excellent energy-storage properties. Ceram Int 48:2533–2537. https://doi.org/10.1016/j.ceramint.2021.10.03510.1016/j.ceramint.2021.10.035 ↗
4. Acosta M, Novak N, Rojas V, Patel S, Vaish R, Koruza J, Rossrtti GA, Rodel J (2017) BaTiO3-based piezoelectrics: fundamentals, current status, and perspectives. Appl Phys Rev 4:041305. https://doi.org/10.1063/1.499004610.1063/1.4990046 ↗
5. Wang T, Hao H, Liu MY, Zhou DD, Yao ZH, Cao MH, Liu HX (2015) X9R BaTiO3-based dielectric ceramics with multilayer core-shell structure produced by polymer-network gel coating method. J Am Ceram Soc 98:690–693. https://doi.org/10.1111/jace.1347910.1111/jace.13479 ↗
6. Wang S, Zhang SR, Zhou XH, Li B, Chen Z (2006) Investigation on dielectric properties of BaTiO3 co-doped with Ni and Nb. Mater Lett 60:909–911. https://doi.org/10.1016/j.matlet.2005.10.04310.1016/j.matlet.2005.10.043 ↗
7. Chen XL, Huang GS, Ma DD, Liu GF, Zhou HF (2017) High thermal stability and low dielectric loss of BaTiO3-Bi(Li1/3Zr2/3)O3 solid solution. Ceram Int 43:926–929. https://doi.org/10.1016/j.ceramint.2016.10.09910.1016/j.ceramint.2016.10.099 ↗
8. Zeb A, Milne SJ (2014) Temperature-stable dielectric properties from −20 °C to 430 °C in the system BaTiO3-Bi(Mg0.5Zr0.5)O3. J Eur Ceram Soc 34:3159–3166. https://doi.org/10.1016/j.jeurceramsoc.2014.04.04710.1016/j.jeurceramsoc.2014.04.047 ↗
9. Cao WJ, Li TY, Liang C, Wang CC (2022) Design of high energy-storage properties in eco-friendly AgNbO3-based ceramics via two-step sintering method and tuning phase boundary. J Mater Sci 57:21000–21008. https://doi.org/10.1007/s10853-022-07964-510.1007/s10853-022-07964-5 ↗
10. Chen LL, Hui KZ, Wang HX, Zhao PY, Li LT, Wang XH (2019) Effects of Ho2O3 doping and sintering temperature on the core–shell structure of X9R Nb-modified BaTiO3-(Bi0.5Na0.5)TiO3 ceramics. J Eur Ceram Soc 39:3710–3715. https://doi.org/10.1016/j.jeurceramsoc.2019.05.04110.1016/j.jeurceramsoc.2019.05.041 ↗
11. Li XX, Chen XL, Yan X, Zhou HF, Liu XB, Li X, Sun J (2018) Excellent thermal stability and low dielectric loss of (Ba1-xBi0.5xSr0.5x)(Ti1-xBi0.5xZr0.5x)O3 solid solution ceramics in a broad temperature range applied in X8R. Appl Phys A 124:771. https://doi.org/10.1007/s00339-018-2194-010.1007/s00339-018-2194-0 ↗
12. Nurmi K, Jantunen H, Juuti J (2019) The effect of titanium excess and deficiency on the microstructure and dielectric properties of lanthanum doped Ba0.55Sr0.45TiO3 with colossal permittivity. J Eur Ceram Soc 39:1110–1115. https://doi.org/10.1016/j.jeurceramsoc.2018.12.03910.1016/j.jeurceramsoc.2018.12.039 ↗
13. Liang RH, Zhou ZY, Dong XL, Wang GS, Gao F, Hu ZG, Jiang K (2015) Enhanced dielectric tunability of Ba0.55Sr0.45TiO3–ZnAl2O4 composite ceramic. Ceram Int 41:S551–S556. https://doi.org/10.1016/j.ceramint.2015.03.20410.1016/j.ceramint.2015.03.204 ↗
14. Chen L, Yu HF, Wu J, Deng SQ, Liu H, Zhu LF, Qi H, Chen J (2023) Large energy capacitive high-entropy lead-free ferroelectrics. Nano-Micro Lett 15:65. https://doi.org/10.1007/s40820-023-01036-210.1007/s40820-023-01036-2 ↗
15. Cao WJ, Lin RJ, Chen PF, Li F, Ge BH, Song DS, Zhang J, Cheng ZX, Wang CC (2022) Phase and band structure engineering via linear additive in NBT-ST for excellent energy storage performance with superior thermal stability. ACS Appl Mater Interfaces 14:54051–54062. https://doi.org/10.1021/acsami.2c1717010.1021/acsami.2c17170 ↗
16. Li TY, Jiang XW, Li J, Xie AW, Fu J (2022) Zuo RZ (2022) Ultrahigh energy-storage performances in lead-free Na0.5Bi0.5TiO3-based relaxor antiferroelectric ceramics through a synergistic design strategy. ACS Appl Mater Interfaces 14:22263–22269. https://doi.org/10.1021/acsami.2c0128710.1021/acsami.2c01287 ↗
17. Yadav AK, Fan HQ, Yan BB, Wang C, Ma JW, Zhang MC, Wang WJ, Dong WQ, Wang SR (2020) Enhanced storage energy density and fatigue free properties for 0.94Bi0.50(Na0.78K0.22)0.50Ti1-x(Al0.50Nb0.50)xO3-0.06BaZrO3 ceramics. Ceram Int 46:17044–17052. https://doi.org/10.1016/j.ceramint.2020.03.29210.1016/j.ceramint.2020.03.292 ↗
18. Liu JK, Ding YQ, Li CY, Bai WF, Zheng P, Wu ST, Zhang JJ, Pan ZB, Zhai JW (2023) A synergistic two-step optimization design enables high capacitive energy storage in lead-free Sr0.7Bi0.2TiO3-based relaxor ferroelectric ceramics. J Mater Chem A 11:609–620. https://doi.org/10.1039/d2ta08074e10.1039/d2ta08074e ↗
19. Li TY, Chen PF, Li F, Wang CC (2021) Energy storage performance of Na0.5Bi0.5TiO3-SrTiO3 lead-free relaxors modified by AgNb0.85Ta0.15O3. Chem Eng J 406:127151. https://doi.org/10.1016/j.cej.2020.12715110.1016/j.cej.2020.127151 ↗
20. Jain A, Wang YG, Guo H (2020) Microstructural properties and ultrahigh energy storage density in Ba0.9Ca0.1TiO3-NaNb0.85Ta0.15O3 relaxor ceramics. Ceram Int 46:24333–24346. https://doi.org/10.1016/j.ceramint.2020.06.21510.1016/j.ceramint.2020.06.215 ↗
21. Wang Q, Gong PM, Wang CM (2020) High recoverable energy storage density and large energy efficiency simultaneously achieved in BaTiO3-Bi(Zn1/2Zr1/2)O3 relaxor ferroelectrics. Ceram Int 46:22452–22459. https://doi.org/10.1016/j.ceramint.2020.06.00310.1016/j.ceramint.2020.06.003 ↗
22. Si F, Tang B, Fang ZX, Li H, Zhang SR (2019) Enhanced energy storage and fast charge–discharge properties of (1–x) BaTiO3-xBi(Ni1/2Sn1/2)O3 relaxor ferroelectric ceramics. Ceram Int 45:17580–17590. https://doi.org/10.1016/j.ceramint.2019.05.32310.1016/j.ceramint.2019.05.323 ↗
23. Li WB, Zhou D, Liu WF, Su JZ, Hussain F, Wang DW, Wang G, Lu ZL, Wang QP (2021) High-temperature BaTiO3-based ternary dielectric multilayers for energy storage applications with high efficiency. Chem Eng J 414:128760. https://doi.org/10.1016/j.cej.2021.12876010.1016/j.cej.2021.128760 ↗
24. Uchino K, Nomura S (1982) Critical exponents of the dielectric constants in diffused-phase-transition crystals. Ferroelectr Lett 44:55–61. https://doi.org/10.1080/0015019820826064410.1080/00150198208260644 ↗
25. Zhao NS, Fan HQ, Ren XH, Ma JW, Bao J, Guo YJ, Zhou YY (2018) Dielectric, conductivity and piezoelectric properties in (0.67-x)BiFeO3-0.33BaTiO3-xSrZrO3 ceramics. Ceram Int 44:18821–18827. https://doi.org/10.1016/j.ceramint.2018.07.11610.1016/j.ceramint.2018.07.116 ↗
26. Zhao JH, Bao SH, Tang LM, Shen YH, Su Z, Yang F, Liu JJ, Pan ZB (2022) Improved energy storage performances of lead-free BiFeO3-based ceramics via doping Sr0.7La0.2TiO3. J Alloy Compd 898:162795. https://doi.org/10.1016/j.jallcom.2021.16279510.1016/j.jallcom.2021.162795 ↗
27. Zeng MS, Liu JS, Li HQ, Zhang SR, Zhang WL (2022) High energy storage efficiency and fast discharge property of temperature stabilized Ba0.4Sr0.6TiO3-Bi(Mg0.5Ti0.5)O3 ceramics. Ceram Int 48:23518–23526. https://doi.org/10.1016/j.ceramint.2022.04.34810.1016/j.ceramint.2022.04.348 ↗
28. Wang J, Li TY, Jiang XW, Zhou C, Xu YJ, Shi RJ, Liu LQ, Chu BJ, Zhao Z, Zuo RZ (2022) An alternative way to design excellent energy-storage properties in Na0.5Bi0.5TiO3-based lead-free system by constructing relaxor dielectric composites. J Eur Ceram Soc 42:6512–6517. https://doi.org/10.1016/j.jeurceramsoc.2022.07.02510.1016/j.jeurceramsoc.2022.07.025 ↗
29. Ding YQ, Li P, He JT, Que WJ, Bai WF, Zheng P, Zhang JJ, Zhai JW (2022) Simultaneously achieving high energy-storage efficiency and density in Bi-modified SrTiO3-based relaxor ferroelectrics by ion selective engineering. Compos Part B Eng 230:109493. https://doi.org/10.1016/j.compositesb.2021.10949310.1016/j.compositesb.2021.109493 ↗
30. Weibull W (1951) A statistical distribution function of wide applicability. J Appl Mech 18:293–297. https://doi.org/10.1115/1.401033710.1115/1.4010337 ↗
31. Dai ZH, Zhang FB, Wang SB, Lei Y, Liu Y, Chen H, Pan Y, Ding XD (2022) High energy storage properties for BiMg0.5Ti0.5O3-modified KNN ceramics under low electric fields. J Mater Sci 57:15919–15928. https://doi.org/10.1007/s10853-022-07636-410.1007/s10853-022-07636-4 ↗
32. Cao WJ, Li TY, Chen PF, Wang CC (2021) Outstanding energy storage performance of Na0.5Bi0.5TiO3-BaTiO3-(Sr0.85Bi0.1)(Mg1/3Nb2/3)O3 lead-free ceramics. ACS Appl Energy Mater 4:9362–9367. https://doi.org/10.1021/acsaem.1c0156610.1021/acsaem.1c01566 ↗
33. Luo NN, Han K, Cabral MJ, Liao XZ, Zhang SJ, Liao CZ, Zhang GZ, Chen XY, Feng Q, Li JF, Wei YZ (2020) Constructing phase boundary in AgNbO3 antiferroelectrics: pathway simultaneously achieving high energy density and efficiency. Nat Commun 11:4824. https://doi.org/10.1038/s41467-020-18665-510.1038/s41467-020-18665-5 ↗
34. Li TY, Cao WJ, Chen PF, Wang JS, Wang CC (2021) Effects of sintering method on the structural, dielectric and energy storage properties of AgNbO3 lead-free antiferroelectric ceramics. J Mater Sci 56:13499–13508. https://doi.org/10.1007/s10853-021-06148-x10.1007/s10853-021-06148-x ↗
35. Wu YC, Fan YZ, Liu NT, Peng P, Zhou MX, Yan SG, Cao F, Dong XL, Wang GS (2019) Enhanced energy storage properties in sodium bismuth titanate-based ceramics for dielectric capacitor applications. J Mater Chem C 7:6222–6230. https://doi.org/10.1039/c9tc01239g10.1039/c9tc01239g ↗
36. Yao Y, Li Y, Sun NN, Du JH, Li XW, Zhang LW, Zhang QW, Hao XH (2018) Enhanced dielectric and energy-storage properties in ZnO-doped 0.9(0.94Na0.5Bi0.5TiO3-0.06BaTiO3)-0.1NaNbO3 ceramics. Ceram Int 44:5961–5966. https://doi.org/10.1016/j.ceramint.2017.12.17410.1016/j.ceramint.2017.12.174 ↗
37. Pan ZB, Hu D, Zhang Y, Liu JJ, Shen B, Zhai JW (2019) Achieving high discharge energy density and efficiency with NBT-based ceramics for application in capacitors. J Mater Chem C 7:4072–4078. https://doi.org/10.1039/c9tc00087a10.1039/c9tc00087a ↗
38. Zhang L, Pu YP, Chen M, Zhuo FP, Dietz C, Frömling T (2021) Decreasing polar-structure size: achieving superior energy storage properties and temperature stability in Na0.5Bi0.5TiO3-based ceramics for low electric field and high-temperature applications. J Eur Ceram Soc 41:5890–5899. https://doi.org/10.1016/j.jeurceramsoc.2021.05.03610.1016/j.jeurceramsoc.2021.05.036 ↗
39. Zhao P, Tang B, Fang ZX, Si F, Yang CT, Zhang SR (2021) Improved dielectric breakdown strength and energy storage properties in Er2O3 modified Sr0.35Bi0.35K0.25TiO3. Chem Eng J 403:126290. https://doi.org/10.1016/j.cej.2020.12629010.1016/j.cej.2020.126290 ↗
40. Xu R, Xu Z, Feng YJ, Jian JJ, Huang D (2016) Energy storage and release properties of Sr-doped (Pb, La)(Zr, Sn, Ti)O3 antiferroelectric ceramics. Ceram Int 42:12875–12879. https://doi.org/10.1016/j.ceramint.2016.05.05310.1016/j.ceramint.2016.05.053 ↗
41. Cao L, Yuan Y, Li EZ, Zhang SR (2021) Relaxor regulation and improvement of energy storage properties of Sr2NaNb5O15-based tungsten bronze ceramics through B-site substitution. Chem Eng J 421:127846. https://doi.org/10.1016/j.cej.2020.12784610.1016/j.cej.2020.127846 ↗
42. Wu LL, Zhang JJ, Du HW, Chen JF, Yu HA, Liu YP, Wang JY, Zhou Y, Yao YX, Zhai JW (2022) Chemical nature of the enhanced energy storage in A-site defect engineered Bi0.5Na0.5TiO3-based relaxor ferroelectrics. J Alloy Compd 905:164183. https://doi.org/10.1016/j.jallcom.2022.16418310.1016/j.jallcom.2022.164183 ↗
43. Shi P, Wang XJ, Lou XJ, Zhou C, Liu QD, He LQ, Yang S, Zhang XX (2021) Significantly enhanced energy storage properties of Nd3+ doped AgNbO3 lead-free antiferroelectric ceramics. J Alloy Compd 877:160162. https://doi.org/10.1016/j.jallcom.2021.16016210.1016/j.jallcom.2021.160162 ↗
44. Zhou MX, Liang RH, Zhou ZY, Dong XL (2018) Superior energy storage properties and excellent stability of novel NaNbO3-based lead-free ceramics with A-site vacancy obtained via a Bi2O3 substitution strategy. J Mater Chem A 6:17896–17904. https://doi.org/10.1039/c8ta07303a10.1039/c8ta07303a ↗
45. Xu SD, Hao R, Yan Z, Hou ST, Peng ZH, Wu D, Liang PF, Chao XL, Wei LL, Yang ZP (2022) Enhanced energy storage properties and superior thermal stability in SNN-based tungsten bronze ceramics through substitution strategy. J Eur Ceram Soc 42:2781–2788. https://doi.org/10.1016/j.jeurceramsoc.2022.02.00510.1016/j.jeurceramsoc.2022.02.005 ↗
46. Jiang Y, Zhu CQ, Zhao PY, Bi K, Liu JM, Guo LM, Wang XH, Li LT (2021) Excellent energy storage performance of NaNbO3-based antiferroelectric ceramics with ultrafast charge/discharge rate. J Eur Ceram Soc 41:6465–6473. https://doi.org/10.1016/j.jeurceramsoc.2021.06.03310.1016/j.jeurceramsoc.2021.06.033 ↗
47. Wang W, Zhang LY, Li C, Alikin DO, Shur VY, Wei XY, Gao F, Du HL, Jin L (2022) Effective strategy to improve energy storage properties in lead-free (Ba0.8Sr0.2)TiO3-Bi(Mg0.5Zr0.5)O3 relaxor ferroelectric ceramics. Chem Eng J 446:137389. https://doi.org/10.1016/j.cej.2022.13738910.1016/j.cej.2022.137389 ↗
48. Ma ZY, Su Q, Zhu JY, Meng XJ, Zhao Y, Xin GX, Li Y, Hao XH (2022) Optimization of energy-storage properties for lead-free relaxor-ferroelectric (1–x)Na0.5Bi0.5TiO3-xSr0.7Nd0.2TiO3 ceramics. J Mater Sci 57:217–228. https://doi.org/10.1007/s10853-021-06684-610.1007/s10853-021-06684-6 ↗
49. Qiao XS, Sheng AH, Wu D, Zhang FD, Chen B, Liang PF, Wang JJ, Chao XL, Yang ZP (2021) A novel multifunctional ceramic with photoluminescence and outstanding energy storage properties. Chem Eng J 408:127368. https://doi.org/10.1016/j.cej.2020.12736810.1016/j.cej.2020.127368 ↗
50. Ge PZ, Tang XG, Meng K, Huang XX, Li SF, Liu QX, Jiang YP (2022) Energy storage density and charge-discharge properties of PbHf1-xSnxO3 antiferroelectric ceramics. Chem Eng J 429:132540. https://doi.org/10.1016/j.cej.2021.13254010.1016/j.cej.2021.132540 ↗
51. Chao WN, Tian LY, Yang TQ, Li YX, Liu ZF (2022) Excellent energy storage performance achieved in novel PbHfO3-based antiferroelectric ceramics via grain size engineering. Chem Eng J 433:133814. https://doi.org/10.1016/j.cej.2021.13381410.1016/j.cej.2021.133814 ↗
52. Yan GW, Xu LQ, Fang BJ, Zhang S, Lu XL, Zhao XY, Ding JN (2022) Achieving high pulse charge-discharge energy storage properties and temperature stability of (Ba0.98-xLi0.02Lax)(Mg0.04Ti0.96)O3 lead-free ceramics via bandgap and defect engineering. Chem Eng J 450:137814. https://doi.org/10.1016/j.cej.2022.13781410.1016/j.cej.2022.137814 ↗
53. Qin YY, Luo F, Geng XL, Xing JH, Shang F, Chen GH (2022) Influences of crystallization temperature on the structure, dielectric, and energy storage characteristics of KBaSrNb5O15-based glass-ceramics. J Am Ceram Soc 105:6311–6319. https://doi.org/10.1111/jace.1861510.1111/jace.18615 ↗
54. Jiang J, Meng XJ, Li L, Guo S, Huang M, Zhang J, Wang J, Hao XH, Zhu HG, Zhang ST (2021) Ultrahigh energy storage density in lead-free relaxor antiferroelectric ceramics via domain engineering. Energy Storage Mater 43:383–390. https://doi.org/10.1016/j.ensm.2021.09.01810.1016/j.ensm.2021.09.018 ↗
55. Ge GL, Bai HR, Shi YJ, Shi C, He X, He J, Shen B, Zhai JW, Chou XJ (2021) Optimizing the energy storage properties of antiferroelectric ceramics by modulating the phase structure via constructing a novel binary composite. J Mater Chem A 9:11291–11299. https://doi.org/10.1039/d1ta01663f10.1039/d1ta01663f ↗