journal article·2018-01

Enhanced magnetoelectric coupling in La-modified Bi5Co0.5Fe0.5Ti3O15 multiferroic ceramics

Sheng Liu, Shuoqing Yan, Heng Luo, Lingling Yao, Zhaowen Hu, Shengxiang Huang, Lianwen Deng

Journal of Materials Science· Volume 53· Issue 2
Publisher page

Abstract

Multiferroic properties of La-modified four-layered perovskite Bi5−x La x Fe0.5Co0.5Ti3O15 (0 ≤ x ≤ 1) ceramics were investigated, by analyzing the magnetodielectric effect, magneto-polarization response and magnetoelectric conversion. X-ray diffraction indicated the formation of pure Aurivillius ceramics, and Raman spectroscopy revealed the Bi ions displacement and the crystal structure variation. The enhancement of ferromagnetic and ferroelectric properties was observed in Bi5−x La x Fe0.5Co0.5Ti3O15 after La modification. The evidence for enhanced ME coupling was determined by magnetic field-induced marked variations in the dielectric constant and polarization. A maximum ME coefficient of 1.15 mV/cm·Oe was achieved in Bi4.25La0.75Fe0.5Co0.5Ti3O15 ceramic, which provides the possible promise for novel magnetoelectric device application.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Multiferroics and related materials · Ferroelectric and Piezoelectric Materials · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (40)

Show source-provided references
1. Nan CW, Bichurin MI, Dong S, Viehland D (2008) Multiferroic magnetoelectric composites: historical perspective, status, and future directions. J Appl Phys 103:03110110.1063/1.2836410 ↗
2. Eerenstein W, Mathur ND, Scott JF (2006) Multiferroic and magnetoelectric materials. Nature (London) 442:759–76510.1038/nature05023 ↗
3. Dong S, Liu JM, Cheong SW, Ren Z (2015) Multiferroic materials and magnetoelectric physics: symmetry, entanglement, excitation, and topology. Adv Phys 64:519–62610.1080/00018732.2015.1114338 ↗
4. Hu JM, Chen LQ, Nan CW (2016) Multiferroic heterostructures integrating ferroelectric and magnetic materials. Adv Mater 28(1):15–3910.1002/adma.201502824 ↗
5. Sun NX, Srinivasan G (2012) Voltage control of magnetism in multiferroic heterostructures and devices. Spin 2:124000410.1142/S2010324712400048 ↗
6. Catalan G, Scott JF (2009) Physics and applications of bismuth ferrite. Adv Mater 21:2463–248510.1002/adma.200802849 ↗
7. Schlom DG, Waghmare UV, Spaldin NA, Rabe KM, Wuttig M, Ramesh R (2003) Epitaxial BiFeO3 multiferroic thin film heterostructures. Science 299(5613):1719–172210.1126/science.1080615 ↗
8. Singh K, Caignaert V, Chapon LC, Pralong V, Raveau B, Maignan A (2012) Gigantic magnetic-field-induced polarization and magnetoelectric coupling in a ferrimagnetic oxide CaBaCo4O7. Phys Rev B 86:02441010.1103/PhysRevB.86.024410 ↗
9. Dey K, Indra A, De D, Majumdar S, Giri S (2016) Magnetoelectric coupling, ferroelectricity, and magnetic memory effect in double perovskite La3Ni2NbO9. ACS Appl Mater Interfaces 8:12901–1290710.1021/acsami.6b02990 ↗
10. Kubel F, Schmid H (1992) X-ray room temperature structure from single crystal data, powder diffraction measurements and optical studies of the aurivillius phase Bi5(Ti3Fe)O15. Ferroelectrics 129:101–11210.1080/00150199208016980 ↗
11. Mao X, Wang W, Chen X, Lu Y (2009) Multiferroic properties of layer-structured Bi5Fe0.5Co0.5Ti3O15 ceramics. Appl Phys Lett 95:08290110.1063/1.3213344 ↗
12. Dong XW, Wang KF, Wan JG, Zhu JS, Liu JM (2008) Magnetocapacitance of polycrystalline Bi5Ti3FeO15 prepared by sol–gel method. J Appl Phys 103:09410110.1063/1.2908219 ↗
13. Zhao H, Kimura H, Cheng Z, Osada M, Wang J, Wang X, Dou S, Liu Y, Yu J, Matsumoto T, Tohei T, Shibata N, Ikuhara Y (2014) Large magnetoelectric coupling in magnetically short-range ordered Bi5Ti3FeO15 film. Sci Res 4:5255
14. Chen XQ, Xiao J, Xue Y, Zeng XB, Yang FJ, Su P (2014) Room temperature multiferroic properties of Ni-doped Aurivillus phase Bi5Ti3FeO15. Ceram Int 40:2635–263910.1016/j.ceramint.2013.10.063 ↗
15. Mao X, Sun H, Wang W, Chen X, Lu Y (2013) Ferromagnetic, ferroelectric properties, and magneto-dielectric effect of Bi4.25La0.75Fe0.5Co0.5Ti3O15 ceramics. Appl Phys Lett 102:07290410.1063/1.4793305 ↗
16. Wu Y, Yao T, Lu Y, Zou B, Mao X, Huang FZ, Sun H, Chen XB (2017) Magnetic, dielectric, and magnetodielectric properties of Bi-layered perovskite Bi4.25Gd0.75Fe0.5Co0.5Ti3O15. J Mater Sci 52:7360–7368. doi: 10.1007/s10853-017-0971-310.1007/s10853-017-0971-3 ↗
17. Zuo XZ, Yang J, Song DP, Yuan B, Tang XW, Zhang KJ, Zhu XB, Song WH, Dai JM, Sun YP (2014) Magnetic, dielectric, and magneto-dielectric properties of rare-earth-substituted Aurivillius phase Bi6Fe1.4Co0.6Ti3O18. J Appl Phys 116:15410210.1063/1.4898318 ↗
18. Yang FJ, Su P, Wei C, Chen XQ, Yang CP, Cao WQ (2011) Large magnetic response in (Bi4Nd)Ti3(Fe0.5Co0.5)O15 ceramic at room-temperature. J Appl Phys 110:12610210.1063/1.3671418 ↗
19. Chen XQ, Xue Y, Lu ZW, Xiao J, Yao J, Kang ZW, Su P, Yang FJ, Zeng XB, Sun HZ (2015) Magnetodielectric properties of Bi4NdTi3Fe0.7Co0.3O15 multiferroic system. J Alloys Compd 622:288–29110.1016/j.jallcom.2014.10.080 ↗
20. Paul J, Bhardwaj S, Sharma KK, Kotnala RK, Kumar R (2014) Room temperature multiferroic properties and magnetoelectric coupling in Sm and Ni substituted Bi4−x Sm x Ti3−x Ni x O12±δ (x = 0, 0.02, 0.05, 0.07) ceramics. J Appl Phys 115:20490910.1063/1.4880159 ↗
21. Osada M, Tada M, Kakihana M, Watanabe T, Funakubo H (2001) Cation distribution and structural instability in Bi4−x La x Ti3O12. Jpn J Appl Phys 40:5572–557510.1143/JJAP.40.5572 ↗
22. Kojima S, Shimada S (1996) Soft mode spectroscopy of bismuth titanate single crystals. Phys B Condens Matter 219:617–61910.1016/0921-4526(95)00830-6 ↗
23. Wang W, Gu SP, Mao XY, Chen XB (2007) Effect of Nd modification on electrical properties of mixed-layer Aurivillius phase Bi4Ti3O12–SrBi4Ti4O15. J Appl Phys 102:02410210.1063/1.2753582 ↗
24. Liang K, Qia YJ, Lu CJ (2009) Temperature-dependent Raman scattering in ferroelectric Bi4−x Nd x Ti3O12(x = 0, 0.5, 0.85) single crystals. Raman Spectrosc 40:2088–209110.1002/jrs.2376 ↗
25. Graves PR, Hua G, Myhra S, Thompson JG (1995) The Raman modes of the aurivillius phases: temperature and polarization dependence. J Solid State Chem 114:112–12210.1006/jssc.1995.1017 ↗
26. Kumar S, Varma KBR (2009) Influence of lanthanum doping on the dielectric, ferroelectric and relaxor behaviour of barium bismuth titanate ceramics. J Phys D Appl Phys 42:07540510.1088/0022-3727/42/7/075405 ↗
27. Sun S, Wang G, Huang Y, Wang J, Peng R, Lu Y (2014) Structural transformation and multiferroic properties in Gd-doped Bi7Fe3Ti3O21 ceramics. RSC Adv 4:30440–3044610.1039/C4RA04945D ↗
28. Kim SK, Miyayama M, Yanagida H (1996) Electrical anisotropy and a plausible explanation for dielectric anomaly of Bi4Ti3O12 single crystal. Mater Res Bull 31:121–13110.1016/0025-5408(95)00161-1 ↗
29. Padhan P, LeClair P, Gupta A, Srinivasan G (2008) Magnetodielectric response in epitaxial thin films of multiferroic Bi2NiMnO6. J Phys Condens Matter 20:35500310.1088/0953-8984/20/35/355003 ↗
30. Catalan G (2006) Magnetocapacitance without magnetoelectric coupling. Appl Phys Lett 88:10290210.1063/1.2177543 ↗
31. Yamasaki Y, Kohara Y, Tokura Y (2009) Quantum magnetoelectric effect in iron garnet. Phys Rev B 80:14041210.1103/PhysRevB.80.140412 ↗
32. Park BH, Kang BS, Bu SB, Noh TW, Lee J, Jo W (1999) Lanthanum-substituted bismuth titanate for use in non-volatile memories. Nature 401:682–68410.1038/44352 ↗
33. Sun H, Lu XM, Su J, Xu TT, Ju CC, Huang FZ, Zhu JS (2012) Multiferroic behaviour and the magneto-dielectric effect in Bi5FeTi3O15 thin films. J Phys D Appl Phys 45:38500110.1088/0022-3727/45/38/385001 ↗
34. Liu S, Luo H, Yan SQ, Yao LL, He J, Li YH, He LH, Huang SX, Deng LW (2017) Effect of Nd-doping on structure and microwave electromagnetic properties of BiFeO3. J Magn Magn Mater 426:267–27210.1016/j.jmmm.2016.11.080 ↗
35. Scott JF, Araujo CAP (1989) Ferroelectric memories. Science 246:140010.1126/science.246.4936.1400 ↗
36. Kimura T, Goto T, Shintani H, Ishizaka K, Arima T, Tokura Y (2003) Magnetic control of ferroelectric polarization. Nature 426:55–5810.1038/nature02018 ↗
37. Palkar VR, Kundaliya DC, Malik SK, Bhattacharya S (2004) Magnetoelectricity at room temperature in the Bi0.9−x Tb x La0.1FeO3 system. Phys Rev B 69:21210210.1103/PhysRevB.69.212102 ↗
38. Kojima T, Sakai T, Watanabe T, Funakubo H, Saito K, Osada M (2002) Large remanent polarization of (Bi, Nd)4Ti3O12 epitaxial thin films grown by metalorganic chemical vapor deposition. Appl Phys Lett 80:2746–274810.1063/1.1468914 ↗
39. Singh RS, Bhimasankaram T, Kumar GS, Suryanarayana SV (1994) Dielectric and magnetoelectric properties of Bi5FeTi3O15. Solid State Commun 91:567–56910.1016/0038-1098(94)90376-X ↗
40. Paul J, Bhardwaj S, Sharma KK, Kotnala RK, Kumar R (2014) Room-temperature multiferroic properties and magnetoelectric coupling in Bi4−x Sm x Ti3−x Co x O12−δ ceramics. J Mater Sci 49:6056–6066. doi: 10.1007/s10853-014-8328-710.1007/s10853-014-8328-7 ↗