journal article·2018-06

Dual relaxation behaviors and large electrostrictive properties of Bi0.5Na0.5TiO3–Sr0.85Bi0.1TiO3 ceramics

Jun Wang, Changrong Zhou, Qingning Li, Weidong Zeng, Jiwen Xu, Guohua Chen, Changlai Yuan, Guanghui Rao

Journal of Materials Science· Volume 53· Issue 12
Publisher page

Abstract

Lead-free ceramics (1 − x)Bi0.5Na0.5TiO3–xSr0.85Bi0.1TiO3 (BNT–xSBT, x = 0.4, 0.5, 0.6 and 0.7) were prepared by a solid-state reaction process. Coexistence of ferroelectric relaxation at low temperature and Maxwell–Wagner dielectric relaxation at high temperature was revealed for the first time in this system. Meanwhile, hysteresis-free P–E loops combined with a very high piezoelectric strain coefficient (d33) of 1658 pC/N concurrently with large electrostrictive coefficient Q = 0.287 m4C−2 were achieved. The ferroelectric relaxor behavior and large electrostrictive strain might be linked to easy reorientation and reversal of ergodic PNRs and the combined effect of Bi off-center position and lone pair electrons.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Multiferroics and related materials · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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