journal article·2020-05-26

Prolonged Lifetime in Nanocrystal Light-Emitting Diodes Incorporating MoS2-Based Conjugated Polyelectrolyte Interfacial Layer as an Alternative to PEDOT:PSS

Paola Lagonegro, Christian Martella, Benedetta M. Squeo, Francesco Carulli, Guido Scavia, Alessio Lamperti, Francesco Galeotti, Benoit Dubertret, Mariacecilia Pasini, Sergio Brovelli, Alessandro Molle, Umberto Giovanella

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Abstract

Colloidal semiconductor nanocrystals (NCs) and, recently, nanoplatelets (NPLs), owing to their efficient and narrow-band luminescence, are considered as frontier materials for light-emitting diode (LED) technology. NC-LEDs typically incorporate interfacial layers as charge regulators to ensure charge balancing and high performance. In this Letter, we show the prolongation of the lifetime of multilayer solution-processed NC-LEDs by combining a self-doped conductive conjugated polyelectrolyte and exfoliated molybdenum disulfide (MoS2) flakes as an alternative to PEDOT:PSS. The ink features a neutral pH and a tunable hydrophobicity that mainly results in a remarkable stability of LEDs, using CdSe/CdZnS NPLs.
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Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · Perovskite Materials and Applications · 2D Materials and Applications

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Affiliations

CNR-SCITEC, via A. Corti 12, 20133 Milano, Italy

CNR-IMM, unit of Agrate Brianza, via C. Olivetti 2, 20864 Agrate Brianza (MB), Italy

Dipartimento di Scienza dei Materiali, Università degli Studi di Milano-Bicocca, via Cozzi 55, I-20125 Milano, Italy

Laboratoire de Physique et d’Etude des Matériaux, ESPCI-ParisTech, PSL Research University, Sorbonne Université UPMC, Université Paris 06, CNRS, 10 rue Vauquelin, 75005 Paris, France

Funding

Regione Lombardia · Ministero dell?Istruzione, dell?Universit? e della Ricerca

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