journal article·2018-12

Black phosphorus: an efficient co-catalyst for charge separation and enhanced photocatalytic hydrogen evolution

Jiahao Wu, Shaolong Huang, Zhengyuan Jin, Jiaqi Chen, Liang Hu, Yaojia Long, Jianguo Lu, Shuangchen Ruan, Yu-Jia Zeng

Journal of Materials Science· Volume 53· Issue 24
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Abstract

Black phosphorus (BP), a phosphorus analog of graphene, is a two-dimensional material with the thickness-dependent bandgap and a high carrier mobility, which emerges as a promising material in nanoelectronics and optoelectronics. In this study, BP loaded with surface hydroxyl has been prepared by liquid ultrasonic exfoliation and used as the co-catalyst, which results in 341% photocatalytic hydrogen evolution enhancement to the anatase TiO2 under the simulated sunlight irradiation and a quantum efficiency as high as 18.23% at 365 nm. The improved photocatalytic activity has been ascribed to the Z-scheme mechanism. These results indicate that 2D surface hydroxyl-loaded BP can be used as a broadband photocatalyst by forming type II heterostructures with other wide-bandgap semiconductors.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: 2D Materials and Applications · Advanced Photocatalysis Techniques · MXene and MAX Phase Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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