Facile syntheses of cerium-based CeMO3 (M = Co, Ni, Cu) perovskite nanomaterials for high-performance supercapacitor electrodes
Source abstract
Abstract
Cerium-based CeMO3 (M = Co, Ni, Cu) perovskites were efficiently synthesized by electrospinning process. The structures, morphologies, elemental compositions, and valence states of CeMO3 perovskites were manifested in detail using X-ray diffraction analysis, Raman spectroscopic analysis, UV–vis diffuse reflectance spectroscopy, scanning electron microscope, transmission electron microscope, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy, respectively. The tolerance factor (t) was accurately calculated to confirm the perovskite structure stability. The electrochemical properties of CeMO3 perovskites were investigated, and the specific capacitances of CeCoO3, CeNiO3, and CeCuO3 perovskites are 128, 189, and 117 F g−1 at the current density of 0.5 A g−1, respectively. This study could provide an efficient and potential applications of the cerium-based perovskites into the supercapacitor electrode materials.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Electrocatalysts for Energy Conversion · Advanced battery technologies research
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References (56)
Show source-provided references
1. Liu Yu, Dinh JD, Tade MO, Shao Z (2016) Design of perovskite oxides as anion-intercalation type electrodes for supercapacitors: cation leaching effect. ACS Appl Mater Interfaces 836:23774–2378310.1021/acsami.6b08634 ↗
2. Chodankar NR, Dubal DP, Kwon Y, Kim D-H (2017) Direct growth of FeCo2O4 nanowire arrays on flexible stainless steel mesh for high-performance asymmetric supercapacitor. NPG Asia Mater 9:e41910.1038/am.2017.145 ↗
3. Ling T, Da P, Zheng X, Ge B, Zhenpeng H, Mengying W, Xi-Wen D, Wen-Bin H, Jaroniec M, Qiao S-Z (2018) Atomic-level structure engineering of metal oxides for high-rate oxygen intercalation pseudocapacitance. Sci Adv 4:eaau626110.1126/sciadv.aau6261 ↗
4. Muhammed Shafi P, Joseph N, Thirumurugan A, Chandra Bose A (2018) Enhanced electrochemical performances of agglomeration-free LaMnO3 perovskite nanoparticles and achieving high energy and power densities with symmetric supercapacitor design. Chem Eng J 338:147–15610.1016/j.cej.2018.01.022 ↗
5. Abouali S, Garakani MA, Zhang B, Zheng-Long X, Heidari EK, Huang J-Q, Huang J, Kim J-K (2015) Electrospun carbon nanofibers with in situ encapsulated Co3O4 nanoparticles as electrodes for high performance supercapacitors. ACS Appl Mater Interfaces 7(24):13503–1351110.1021/acsami.5b02787 ↗
6. Vidhyadharan B, Zain NKM, Misnon II, Aziz RA, Ismail J, Yusoff MM, Jose R (2014) High performance supercapacitor electrodes from electrospun nickel oxide nanowires. J Alloys Compd 610:143–15010.1016/j.jallcom.2014.04.211 ↗
7. Moosavifard SE, El-Kady MF, Rahmanifar MS, Kaner RB, Mousavi MF (2015) Designing 3D highly ordered nanoporous CuO electrodes for high performance asymmetric supercapacitors. ACS Appl Mater Interfaces 7(8):4851–486010.1021/am508816t ↗
8. Tyler Mefford J, Hardin WG, Dai S, Johnston KP, Stevenson KJ (2014) Anion charge storage through oxygen intercalation in LaMnO3 perovskite pseudocapacitor electrodes. Nat Mater 13:726–73210.1038/nmat4000 ↗
9. Galal A, Hassan HK, Jacob T, Atta NF (2018) Enhancing the specific capacitance of SrRuO3 and reduced graphene oxide in NaNO3, H3PO4 and KOH electrolytes. Electrochim Acta 260:738–74710.1016/j.electacta.2017.12.026 ↗
10. Elsiddig ZA, Hui X, Wang D, Zhang W, Guo X, Zhang Y, Sun Z, Chen J (2017) Modulating Mn4+ ions and oxygen vacancies in nonstoichiometric LaMnO3 perovskite by a facile sol-gel method as high-performance supercapacitor electrodes. Electrochimica Acta 253:422–42910.1016/j.electacta.2017.09.076 ↗
11. Shao T, You H, Zhai Z, Liu T, Li M, Zhang L (2017) Hollow spherical LaNiO3 supercapacitor electrode synthesized by a facile template-free method. Mater Lett 201:122–12410.1016/j.matlet.2017.04.143 ↗
12. Guo Y, Shao T, You H, Li S, Li C, Zhang L (2017) Polyvinylpyrrolidone-assisted solvothermal synthesis of porous LaCoO3 nanospheres as supercapacitor electrode. Int J Electrochem Sci 12:7121–712710.20964/2017.08.47 ↗
13. Arjun N, Pan GT, Yang TCK (2017) The exploration of Lanthanum based perovskites and their complementary electrolytes for the supercapacitor applications. Results Phys 7:920–92610.1016/j.rinp.2017.02.013 ↗
14. Dou C, Kakushima K, Ahmet P, Tsutsui K, Nishiyama A, Sugii N, Natori K, Hattori T, Iwai H (2012) Resistive switching behavior of a CeO2 based ReRAM cell incorporated with Si buffer layer. Microelectron Reliab 52:688–69110.1016/j.microrel.2011.10.019 ↗
15. Wang Y, Guo CX, Liu J, Chen T, Yang H, Li CM (2011) CeO2 nanoparticles/graphene nanocomposite-based high performance supercapacitor. Dalton Trans 40:6388–939110.1039/c1dt10397k ↗
16. Maheswari N, Muralidharan G (2015) Supercapacitor behavior of cerium oxide nanoparticles in neutral aqueous electrolytes. Energy Fuels 29:8246–825310.1021/acs.energyfuels.5b02144 ↗
17. Ghiasi M, Malekzadeh A (2014) Structural features of (Ce, La or Sr) (Mn or Co)O3 nano-perovskites as a catalyst for carbon monoxide oxidation. Acta Metallurgica Sinica (English Lett) 27(4):635–64110.1007/s40195-014-0060-4 ↗
18. Chen J, He Z, Li G, An T, Shi H, Li Y (2017) Visible-light-enhanced photothermocatalytic activity of ABO3-type perovskites for the decontamination of gaseous styrene. Appl Catal B 209:146–15410.1016/j.apcatb.2017.02.066 ↗
19. Wang Q, Li Z, Bañares MA, Weng L-T, Qinfen G, Price J, Han W, Yeung KL (2019) A novel approach to high-performance aliovalent-substituted catalysts—2D bimetallic MOF-derived CeCuOx microsheets. Small 15:1903525
20. Fabbri E, Pergolesi D, Traversa E (2010) Materials challenges toward proton-conducting oxide fuel cells: a critical review. Chem Soc Rev 39:4355–436910.1039/b902343g ↗
21. Kieslich G, Sun S, Cheetham AK (2015) An extended Tolerance Factor approach for organic–inorganic perovskites. Chem Sci 6:3430–343310.1039/C5SC00961H ↗
22. Qiao HW, Yang S, Wang Y, Chen X, Wen Tian Yu, Tang LJ, Qilin Cheng Yu, Hou HZ, Yang HG (2018) A gradient heterostructure based on tolerance factor in high-performance perovskite solar cells with 0.84 fill factor. Adv Mater 31(5):1804217
23. Li Z, Yang M, Park J-S, Wei S-H, Berry JJ, Zhu K (2016) Stabilizing perovskite structures by tuning tolerance factor: formation of formamidinium and cesium lead iodide solid-state alloys. Chem Mater 28:284–29210.1021/acs.chemmater.5b04107 ↗
24. Shannon RD (1976) Revised effective ionic radii and systematic study of inter atomic distances in halides and chalcogenides. Acta Crystallogr A A32:751–76710.1107/S0567739476001551 ↗
25. Van Horn JD (2001) Electronic table of Shannon ionic Radii, 2001, downloaded from http://v.web.umkc.edu/vanhornj/shannonradii.htm. Accessed 13 Aug 2010
26. Yuan C, Wang H-G, Liu J, Wu Q, Duan Q, Li Y (2017) Facile synthesis of Co3O4–CeO2 composite oxide nanotubes and their multifunctional applications for lithium ion batteries and CO oxidation. J Colloid Interface Sci 494:274–28110.1016/j.jcis.2017.01.074 ↗
27. Cui Q, Dong X, Wang J, Li M (2008) Direct fabrication of cerium oxide hollow nanofibers by electrospinning. J Rare Earths 26(5):664–66910.1016/S1002-0721(08)60158-1 ↗
28. Hammouda SB, Zhao F, Safaei Z, Srivastava V, LakshmiRamasamy D, Iftekhar S, Kalliola S, Sillanpää M (2017) Degradation and mineralization of phenol in aqueous medium by heterogeneous monopersulfate activation on nanostructured cobalt based-perovskite catalysts ACoO3 (A = La, Ba, Sr and Ce): characterization, kinetics and mechanism study. Appl Catalysis B: Environ 215:60–7310.1016/j.apcatb.2017.05.051 ↗
29. Persson K (2016) Materials data on CeCuO3 (SG:221) by Materials Project, 2016. https://doi.org/10.17188/131564810.17188/1315648 ↗
30. Wang W-R, Da-Peng X, Wen-Hui S, Ding Z-H, Xue Y-F, Song G-X (2005) Raman active phonons in RCoO3 (R = La, Ce, Pr, Nd, Sm, Eu, Gd, and Dy) perovskites. Chin Phys Lett 22(9):2400–240210.1088/0256-307X/22/9/072 ↗
31. Barad H-N, Keller DA, Rietwyk KJ, Ginsburg A, Tirosh S, Meir S, Anderson AY, Zaban A (2018) How transparent oxides gain some color: discovery of a CeNiO3 reduced bandgap phase as an absorber for photovoltaics. ACS Comb Sci 20:366–37610.1021/acscombsci.8b00031 ↗
32. Persson K (2014) Materials data on CeNiO3 (SG:62) by Materials Project, 2014. https://doi.org/10.17188/130461110.17188/1304611 ↗
33. Schilling C, Hofmann A, Hess C, Ganduglia-Pirovano MV (2017) Raman spectra of polycrystalline CeO2: a density functional theory study. J Phys Chem C 121:20834–2084910.1021/acs.jpcc.7b06643 ↗
34. Liu G, Yue R, Jia Y, Nia Y, Yang J, Liu H, Wang Z, Xiaofeng W, Chen Y (2013) Catalytic oxidation of benzene over Ce–Mn oxides synthesized by flame spraypyrolysis. Particuology 11(4):454–45910.1016/j.partic.2012.09.013 ↗
35. Yang J, Liu H, Martens WN, Frost RL (2010) Synthesis and characterization of cobalt hydroxide, cobalt oxyhydroxide, and cobalt Oxide nanodiscs. J Phys Chem C 114:111–11910.1021/jp908548f ↗
36. Na CW, Woo H-S, Kim H-J, Jeong U, Chung J-H, Lee J-H (2012) Controlled transformation of ZnO nanobelts into CoO/Co3O4 nanowires. CrystEngComm 14:3737–374110.1039/c2ce06681e ↗
37. Rashad M, Rüsing M, Berth G, Lischka K, Pawlis A (2013) CuO and Co3O4 nanoparticles: synthesis, characterizations, and Raman spectroscopy. J Nanomater 2013:1–610.1155/2013/714853 ↗
38. Parwaiz S, Bhunia K, Das AK, Khan MM, Pradhan D (2017) Cobalt-doped ceria/reduced graphene oxide nanocomposite as an efficient oxygen reduction reaction catalyst and supercapacitor material. J Phys Chem C 121:20165–2017610.1021/acs.jpcc.7b06846 ↗
39. Mironova-Ulmane N, Kuzmin A, Sildos I, Pärs M (2011) Polarisation dependent Raman study of single-crystal nickel oxide. Cent Eur J Phys 9:1096–1099
40. Luo M-F, Fang P, He M, Xie Y-L (2005) In situ XRD, Raman, and TPR studies of CuO/Al2O3 catalysts for CO oxidation. J Mol Catal A: Chem 239:243–24810.1016/j.molcata.2005.06.029 ↗
41. Wang W, Liu Z, Liu Y, Xu C, Zheng C, Wang G (2003) A simple wet-chemical synthesis and characterization of CuO nanorods. Appl Phys A 76:417–42010.1007/s00339-002-1514-5 ↗
42. Li H, Chen Y, Ma Q, Wang J, Che Q, Wang G, Tan Y, Yang P (2018) The effect of ZIF-8 on the phase structure and morphology of bead-like CuMn2O4/ZnO photocatalystic electrospun nanofibers. Mater Lett 216:199–20210.1016/j.matlet.2018.01.036 ↗
43. Pettong T, Iamprasertkun P, Krittayavathananon A, Suktha P, Sirisinudomkit P, Seubsai A, Chareonpanich M, Kongkachuichay P, Limtrakul J, Sawangphruk M (2016) High-performance asymmetric supercapacitors of MnCo2O4 nanofibers and N-doped reduced graphene oxide aerogel. ACS Appl Mater Interfaces 8(49):34045–3405310.1021/acsami.6b09440 ↗
44. Shah LR, Ali B, Zhu H, Wang WG, Song YQ, Zhang HW, Shah SI, Xiao JQ (2009) Detailed study on the role of oxygen vacancies in structural, magnetic and transport behavior of magnetic insulator: Co–CeO2. J Phys: Condens Matter 21:486004
45. Kumar M, Yun J-H, Bhatt V, Singh B, Kim J, Kim J-S, Kim BS, Lee CY (2018) Role of Ce3+ valence state and surface oxygen vacancies on enhanced electrochemical performance of single step solvothermally synthesized CeO2 nanoparticles. Electrochimica Acta 284:709–72010.1016/j.electacta.2018.07.184 ↗
46. Peck MA, Langell MA (2012) Comparison of nanoscaled and bulk NiO structural and environmental characteristics by XRD, XAFS, and XPS. Chem Mater 24:4483–449010.1021/cm300739y ↗
47. Gawali SR, Dubal DP, Deonikar VG, Patil SS, Patil SD, Gomez-Romero P, Patil DR, Pant J (2016) Asymmetric supercapacitor based on nanostructured Ce-doped NiO (Ce:NiO) as positive and reduced graphene oxide (rGO) as negative electrode. ChemistrySelect 1:3471–347810.1002/slct.201600566 ↗
48. Xia H, Li J, Ma L, Liu Q, Wang J (2018) Electrospun porous CuFe2O4 nanotubes on nickel foam for nonenzymatic voltammetric determination of glucose and hydrogen peroxide. J Alloy Compd 739:764–77010.1016/j.jallcom.2017.12.187 ↗
49. Jang J, Chung S, Kang H, Subramanian V (2016) p-type CuO and Cu2O transistors derived from a sol-gel copper (II) acetate monohydrate precursor. Thin Solid Films 600:157–16110.1016/j.tsf.2016.01.036 ↗
50. Zhu Y, Murali S, Stoller MD, Ganesh KJ, Cai W, Ferreira PJ, Pirkle A, Wallace RM, Cychosz KA, Thommes M, Su D, Stach EA, Ruoff RS (2011) Carbon-based supercapacitors produced by activation of graphene. Science 332:1537–154110.1126/science.1200770 ↗
51. Li J, Le D-B, Ferguson PP, Dahn JR (2010) Lithium polyacrylate as a binder for tin-cobalt-carbon negative electrodes in lithium-ion batteries. Electrochimica Acta 55:2991–299510.1016/j.electacta.2010.01.011 ↗
52. Dezfuli AS, Ganjali MR, Naderi HR, Norouzi P (2015) A high performance supercapacitor based on a ceria/graphene nanocomposite synthesized by a facile sonochemical method. RSC Adv 5:46050–4605810.1039/C5RA02957K ↗
53. Zhang K, Mao L, Zhang LL, Chan HSO, Zhao XS, Wu JS (2011) Surfactant-intercalated, chemically reduced graphene oxide for high performance supercapacitor electrodes. J Mater Chem 21:7302–730710.1039/c1jm00007a ↗
54. Saravanan T, Shanmugam M, Anandan P, Azhagurajan M, Pazhanivel K, Arivanandhan M, Hayakawad Y, Jayavel R (2015) Facile synthesis of graphene-CeO2 nanocomposites with enhanced electrochemical properties for Supercapacitors. Dalton Trans 44:9901–990810.1039/C5DT01235J ↗
55. Zhang H, Jiangna G, Tong J, Yongfeng H, Guan B, Bin H, Zhao J, Wang C (2016) Hierarchical porous MnO2/CeO2 with high performance for supercapacitor electrodes. Chem Eng J 286:139–14910.1016/j.cej.2015.10.057 ↗
56. Maiti S, Pramanik A, Mahanty S (2014) Extraordinarily high pseudocapacitance of metal organic framework derived nanostructured cerium oxide. Chem Commun 50:11717–1172010.1039/C4CC05363J ↗