journal article·2025-09Open access

Preparation and functionalization of LTCC substrate surfaces for advanced integration applications using thin film process

Kateryna Soloviova, Vladislav Kurtash, Norayr Nessimian, Younes Slimi, Jörg Pezoldt, Jens Müller

Abstract

This study introduces a multi-step surface preparation and functionalization process to optimize low-temperature co-fired ceramic (LTCC) substrates for high structural resolution, thin-film compatibility, and potential direct semiconductor material deposition in electronic and microelectronic devices. The process integrates lapping, chemical mechanical polishing (CMP), and sol-gel coating using methyltrimethoxysilane (MTMS) precursors. CMP significantly improves planarity and reduces surface roughness, lowering the average roughness (Rq) from 300 nm to 90 nm and Ra from 210 nm to 40 nm. The sol-gel coating further refines the surface, achieving a roughness of 25 nm, while reducing porosity and increasing hydrophobicity, as indicated by a water contact angle of 109°. Refractive index measurements of the transparent sol-gel coating reveal a value of 1.406, confirming enhanced dielectric properties. These surface modifications improve LTCC planarity and compatibility with high-frequency applications. Additionally, the functionalized surfaces enhance LTCC's integration with semiconductor materials, demonstrating its potential for advanced heterogeneous integration. This approach opens up possibilities for innovations in RF communications, photonics, and power electronics. By improving both the structural and functional properties of LTCC, this work contributes to the development of efficient and reliable next-generation electronic devices. • Multi-step lapping, CMP, and sol-gel coating improved LTCC surface planarity and smoothness. • Surface roughness reduced from Rq 300 nm–90 nm and Ra 210 nm–40 nm post-processing. • MTMS-based sol-gel coating reduced porosity and enhanced adhesion and mechanical properties. • Transparent sol-gel films achieved a refractive index of 1.406 for RF/optical applications. • Process improves LTCC compatibility for advanced semiconductor device integration.
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Research context

OpenAlex topics: Electrical and Thermal Properties of Materials · Advanced Surface Polishing Techniques · Copper Interconnects and Reliability

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Design of ultrathin LTCC coupled inductors for compact DC/DC converters10.1109/TPEL.2011.2109043 ↗
2. Imanaka · 2005
3. B. Liu, J. Liu, C.C. Hu, K.X. Song, Y.H. Huang, Low-temperature co-fired ceramics with high thermal expansion and reliability for millimeter-wave antennas, Cell Rep Phys Sci 5, 101959. https://doi.org/10.1016/j.xcrp.2024.101959.10.1016/j.xcrp.2024.101959 ↗
4. R. Shi, S. Zhao, R. Luo, P. Cheng, C. Liu, X. Han, S. Qi, Y. Zhang, J. Zhu, J. Xu, X.H. Bu, Controllable shape deformation of an organic single crystal actuated by anisotropic thermal expansion, Cell Rep Phys Sci 4, 101451. https://doi.org/10.1016/j.xcrp.2023.101451.10.1016/j.xcrp.2023.101451 ↗
5. Challenges and prospects for advanced packaging10.1016/j.fmre.2023.04.014 ↗
6. Chemical mechanical planarization for microelectronics applications10.1016/j.mser.2004.06.002 ↗
7. Post CMP cleaning, developments in surface contamination and cleaning, volume VIII wet and dry cleaning methods
8. Colloidal particles in thin liquid films
9. T. J. Garino, The Cracking of Sol-Gel Films During Drying, Mater Res Soc Symp Proc 180, 497. https://doi.org/10.1557/PROC-180-497.10.1557/PROC-180-497 ↗
10. K. B. Singh, M. S. Tirumkudulu, Craking in Drying Colloidal Films, Phys Rev Lett 98, 218302. https://doi.org/10.1103/PhysRevLett.98.218302.10.1103/PhysRevLett.98.218302 ↗
11. Effects of additives in colloidal silica based inorganic-hybrid binder for mineral wool insulation boards10.1080/21870764.2020.1842118 ↗
12. Sol–gel derived organic–inorganic hybrid materials: synthesis, characterizations and applications10.1007/s10971-011-2465-0 ↗
13. Fabrication of oleophobic paper with tunable hydrophilicity by treatment with non-fluorinated chemicals10.1039/C5TA03520A ↗
14. H. Zhang, Q. Yan, Q. Xu, C. Xiao, X. Liang, A sacrificial layer strategy for photolithography on highly hydrophobic surface and its application for electrowetting devices, Sci Rep 7, 3983. https://doi.org/10.1038/s41598-017-04342-z.10.1038/s41598-017-04342-z ↗
15. H. Y. Park, M. K. Na, S. Y. Yoon, S. S. Park. 2007, 544–545, 1037-1040.10.4028/www.scientific.net/MSF.544-545.1037 ↗
16. H. Bartsch, M. Lubov, V. Kharlamov, J.J. Jiménez, F.M. Morales, J. Pezoldt. Characterization of pores in polished low temperature co-fired glass-ceramic composites for optimization of their micromachining, Surf Topogr Metrol Prop 10, 045026. https://doi.org/10.1088/2051-672X/aca2c7.10.1088/2051-672X/aca2c7 ↗
17. The theory and design of plate glass polishing machines
18. Peculiarities in the stretching vibrations of the methylene groups10.1016/S0022-2860(02)00632-4 ↗
19. Preparation of transparent ultrahydrophobic silica film by sol–gel process10.1007/s11998-010-9270-5 ↗
20. Fourier transform infrared and Raman characterization of silica-based materials
21. Mechanism and kinetics of oligosilsesquioxane growth in the in situ water production sol–gel route: dependence on water availability10.1002/ejic.201501220 ↗
22. The infra-red spectra of layer silicates10.1016/0371-1951(64)80165-X ↗
23. Review of infrared spectroscopy techniques for the determination of internal structure in thin SiO2 films
24. Characterization of polymer surfaces with atomic force microscopy10.1146/annurev.matsci.27.1.175 ↗
25. Frontiers of silicon-on-insulator10.1063/1.1558223 ↗