journal article·2021-12-14

Wet etch, dry etch, and MacEtch of β-Ga2O3: A review of characteristics and mechanism

Hsien-Chih Huang, Zhongjie Ren, Clarence Chan, Xiuling Li

Journal of Materials Research· Volume 36· Issue 23
Publisher page

Abstract

β-Ga2O3, a promising ultra-wide bandgap material for future high-power electronics and deep-ultraviolet optoelectronics applications, has drawn tremendous attention in recent years due to its wide bandgap of ~ 4.8 eV, high breakdown electric field, and availability of substrates. However, the reported etch behavior of β-Ga2O3 and the quality of etched surfaces, as well as the associated interface characteristics, could limit the performance of β-Ga2O3 devices. In this article, the etchings of β-Ga2O3, including regular wet etching, photoelectrochemical etching (PEC), reactive ion etching (RIE) and metal-assisted chemical etching (MacEtch), are reviewed. A comparison of the etch rate, orientation dependence, aspect ratio, etching mechanism, and surface quality for each of these etching methods is presented and the step-by-step reactions in PEC and MacEtch are proposed to elucidate the etch mechanism. The challenges for these etching techniques for β-Ga2O3 are discussed.
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Research context

OpenAlex topics: Ga2O3 and related materials · Advanced Photocatalysis Techniques · ZnO doping and properties

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References (64)

Show source-provided references
1. M. Orita, H. Ohta, M. Hirano, H. Hosono, Deep-ultraviolet transparent conductive β-Ga2O3 thin films. Appl. Phys. Lett. 77(25), 4166–4168 (2000). https://doi.org/10.1063/1.133055910.1063/1.1330559 ↗
2. H. He, R. Orlando, M.A. Blanco, R. Pandey, E. Amzallag, I. Baraille, M. Rérat, First-principles study of the structural, electronic, and optical properties of Ga2O3 in its monoclinic and hexagonal phases. Phys. Rev. B 74(19), 195123 (2006). https://doi.org/10.1103/PhysRevB.74.19512310.1103/PhysRevB.74.195123 ↗
3. N. Ma, N. Tanen, A. Verma, Z. Guo, T. Luo, H. Xing, D. Jena, Intrinsic electron mobility limits in β-Ga2O3. Appl. Phys. Lett. 109(21), 1–6 (2016). https://doi.org/10.1063/1.496855010.1063/1.4968550 ↗
4. K. Arora, N. Goel, M. Kumar, M. Kumar, Ultrahigh performance of self-powered β-Ga2O3 thin film solar-blind photodetector grown on cost-effective Si substrate using high-temperature seed layer. ACS Photonics 5(6), 2391–2401 (2018). https://doi.org/10.1021/acsphotonics.8b0017410.1021/acsphotonics.8b00174 ↗
5. M. Ma, D. Zhang, Y. Li, R. Lin, W. Zheng, F. Huang, High-performance solar blind ultraviolet photodetector based on single crystal orientation mg-alloyed Ga2O3 film grown by a nonequilibrium MOCVD scheme. ACS Appl. Electron. Mater. 1(8), 1653–1659 (2019). https://doi.org/10.1021/acsaelm.9b0034310.1021/acsaelm.9b00343 ↗
6. X. Chen, K. Liu, Z. Zhang, C. Wang, B. Li, H. Zhao, D. Zhao, D. Shen, Self-powered solar-blind photodetector with fast response based on Au/β-Ga2O3 nanowires array film Schottky junction. ACS Appl. Mater. Interfaces 8(6), 4185–4191 (2016). https://doi.org/10.1021/acsami.5b1195610.1021/acsami.5b11956 ↗
7. M. Si, L. Yang, H. Zhou, P.D. Ye, β-Ga2O3 nanomembrane negative capacitance field-effect transistors with steep subthreshold slope for wide band gap logic applications. ACS Omega 2, 49 (2017). https://doi.org/10.1021/acsomega.7b0128910.1021/acsomega.7b01289 ↗
8. K.D. Chabak, J.P. McCandless, N.A. Moser, A.J. Green, K. Mahalingam, A. Crespo, N. Hendricks, B.M. Howe, S.E. Tetlak, K. Leedy, R.C. Fitch, D. Wakimoto, K. Sasaki, A. Kuramata, G.H. Jessen, Recessed-gate enhancement-mode β-Ga2O3 MOSFETs. IEEE Electron Device Lett. 39(1), 67–70 (2018). https://doi.org/10.1109/LED.2017.277986710.1109/LED.2017.2779867 ↗
9. J. Noh, M. Si, H. Zhou, M.J. Tadjer, P.D. Ye, The impact of substrates on the performance of top-gate p-Ga2O3 field-effect transistors: record high drain current of 980 MA/Mm on diamond. In 2018 76th Device Research Conference (DRC) (IEEE, 2018), pp. 1–2. https://doi.org/10.1109/DRC.2018.8442276.10.1109/DRC.2018.8442276 ↗
10. C. Joishi, Z. Xia, J. Mcglone, Y. Zhang, A.R. Arehart, S. Ringel, S. Lodha, S. Rajan, Effect of buffer iron doping on delta-doped β-Ga2O3 metal semiconductor field effect transistors. Appl. Phys. Lett 113, 123501 (2018). https://doi.org/10.1063/1.503950210.1063/1.5039502 ↗
11. M. Higashiwaki, K. Sasaki, T. Kamimura, M. Hoi Wong, D. Krishnamurthy, A. Kuramata, T. Masui, S. Yamakoshi, Depletion-mode Ga2 O3 metal-oxide-semiconductor field-effect transistors on β-Ga2 O3 (010) substrates and temperature dependence of their device characteristics. Appl. Phys. Lett. 103(12), 123511 (2013). https://doi.org/10.1063/1.482185810.1063/1.4821858 ↗
12. K.D. Chabak, N. Moser, A.J. Green, D.E. Walker, S.E. Tetlak, E. Heller, A. Crespo, R. Fitch, J.P. McCandless, K. Leedy, M. Baldini, G. Wagner, Z. Galazka, X. Li, G. Jessen, Enhancement-mode Ga2O3 wrap-gate fin field-effect transistors on native (100) β-Ga2O3 substrate with high breakdown voltage. Appl. Phys. Lett. 109(21), 213501 (2016). https://doi.org/10.1063/1.496793110.1063/1.4967931 ↗
13. Z. Hu, K. Nomoto, W. Li, N. Tanen, K. Sasaki, A. Kuramata, T. Nakamura, D. Jena, H.G. Xing, Enhancement-mode Ga2O3 vertical transistors with breakdown voltage >1 KV. IEEE Electron Device Lett. 39(6), 869–872 (2018). https://doi.org/10.1109/LED.2018.283018410.1109/LED.2018.2830184 ↗
14. W. Li, K. Nomoto, Z. Hu, T. Nakamura, D. Jena, H. G. Xing, Single and multi-fin normally-off Ga2O3 vertical transistors with a breakdown voltage over 2.6 KV, in Tech. Dig. - Int. Electron Devices Meet. IEDM 2019, 2019-Decem, 270–273. https://doi.org/10.1109/IEDM19573.2019.8993526.10.1109/IEDM19573.2019.8993526 ↗
15. M.H. Wong, K. Goto, H. Murakami, Y. Kumagai, M. Higashiwaki, Current aperture vertical β-Ga2O3 MOSFETs fabricated by N- and Si-ion implantation doping. IEEE Electron Device Lett. 40, 431–434 (2018). https://doi.org/10.1109/LED.2018.288454210.1109/LED.2018.2884542 ↗
16. K. Sasaki, Q.T. Thieu, D. Wakimoto, Y. Koishikawa, A. Kuramata, S. Yamakoshi, Depletion-mode vertical Ga2O3 trench MOSFETs fabricated using Ga2O3 homoepitaxial films grown by halide vapor phase epitaxy. Appl. Phys. Express 10(12), 124201 (2017). https://doi.org/10.7567/APEX.10.12420110.7567/APEX.10.124201 ↗
17. Q.N. Abdullah, A.R. Ahmed, A.M. Ali, F.K. Yam, Z. Hassan, M. Bououdina, Novel SnO2-coated β-Ga2O3 nanostructures for room temperature hydrogen gas sensor. Int. J. Hydrogen Energy 46(9), 7000–7010 (2021). https://doi.org/10.1016/j.ijhydene.2020.11.10910.1016/j.ijhydene.2020.11.109 ↗
18. S. Nakagomi, T. Sai, Y. Kokubun, Hydrogen gas sensor with self temperature compensation based on β-Ga2O3 thin film. Sens. Actuators B 187, 413–419 (2013). https://doi.org/10.1016/j.snb.2013.01.02010.1016/j.snb.2013.01.020 ↗
19. X. Li, P.W. Bohn, Metal-assisted chemical etching in HF/H2O2 produces porous silicon. Appl. Phys. Lett. 77(16), 2572–2574 (2000). https://doi.org/10.1063/1.131919110.1063/1.1319191 ↗
20. M. Kim, S. Yi, J.D. Kim, W. Zhou, X. Yin, J. Li, J. Bong, D. Liu, S.-C. Liu, A. Kvit, W. Zhou, Z. Yu, Z. Ma, X. Li, Enhanced performance of Ge photodiodes via monolithic antireflection texturing and α-Ge self-passivation by inverse metal-assisted chemical etching. ACS Nano 12(7), 6748–6755 (2018). https://doi.org/10.1021/acsnano.8b0184810.1021/acsnano.8b01848 ↗
21. S.H. Kim, P.K. Mohseni, Y. Song, T. Ishihara, X. Li, Inverse metal-assisted chemical etching produces smooth high aspect ratio InP nanostructures. Nano Lett. 15(1), 641–648 (2015). https://doi.org/10.1021/nl504136c10.1021/nl504136c ↗
22. K. Balasundaram, K. Hsu, P. Ferreira, B. Azeredo, J.C. Shin, J.S. Sadhu, D. Chanda, S. Sinha, X. Li, M. Malik, J.A. Rogers, Porosity control in metal-assisted chemical etching of degenerately doped silicon nanowires. Nanotechnology 23(30), 305304 (2012). https://doi.org/10.1088/0957-4484/23/30/30530410.1088/0957-4484/23/30/305304 ↗
23. C.Y. Chan, S. Namiki, J.K. Hite, M.A. Mastro, S.B. Qadri, X. Li, Homoepitaxial GaN micropillar array by plasma-free photo-enhanced metal-assisted chemical etching. J. Vac. Sci. Technol. A (2021). https://doi.org/10.1116/6.000123110.1116/6.0001231 ↗
24. J.D. Kim, M. Kim, C. Chan, N. Draeger, J.J. Coleman, X. Li, CMOS-compatible catalyst for MacEtch: titanium nitride-assisted chemical etching in vapor phase for high aspect ratio silicon nanostructures. ACS Appl. Mater. Interfaces 11(30), 27371–27377 (2019). https://doi.org/10.1021/acsami.9b0087110.1021/acsami.9b00871 ↗
25. J.A. Michaels, L. Janavicius, X. Wu, C. Chan, H.C. Huang, S. Namiki, M. Kim, D. Sievers, X. Li, Producing silicon carbide micro and nanostructures by plasma-free metal-assisted chemical etching. Adv. Funct. Mater. 31(32), 89 (2021). https://doi.org/10.1002/adfm.20210329810.1002/adfm.202103298 ↗
26. H. Han, Z. Huang, W. Lee, Metal-assisted chemical etching of silicon and nanotechnology applications. Nano Today 9(3), 271–304 (2014). https://doi.org/10.1016/j.nantod.2014.04.01310.1016/j.nantod.2014.04.013 ↗
27. Y. Song, P.K. Mohseni, S.H. Kim, J.C. Shin, T. Ishihara, I. Adesida, X. Li, Ultra-high aspect ratio InP junctionless FinFETs by a novel wet etching method. IEEE Electron Device Lett. 37(8), 970–973 (2016). https://doi.org/10.1109/LED.2016.257704610.1109/LED.2016.2577046 ↗
28. M. Kim, H.-C. Huang, J.D. Kim, K.D. Chabak, A. Raj, K. Kalapala, W. Zhou, X. Li, Nanoscale groove textured β-Ga2O3 by room temperature inverse metal-assisted chemical etching and photodiodes with enhanced responsivity. Appl. Phys. Lett 113, 222104 (2018). https://doi.org/10.1063/1.505321910.1063/1.5053219 ↗
29. I.S. Chun, E.K. Chow, X. Li, Nanoscale three dimensional pattern formation in light emitting porous silicon. Appl. Phys. Lett. 92(19), 191113 (2008). https://aip.scitation.org/doi/abs/10.1063/1.292431110.1063/1.2924311 ↗
30. X. Li, Metal assisted chemical etching for high aspect ratio nanostructures: a review of characteristics and applications in photovoltaics. Curr. Opin. Solid State Mater. Sci. 16(2), 71–81 (2012). https://doi.org/10.1016/j.cossms.2011.11.00210.1016/j.cossms.2011.11.002 ↗
31. A. Mallavarapu, P. Ajay, C. Barrera, S.V. Sreenivasan, Ruthenium-assisted chemical etching of silicon: enabling CMOS-compatible 3D semiconductor device nanofabrication. ACS Appl. Mater. Interfaces 13(1), 1169–1177 (2021). https://doi.org/10.1021/acsami.0c1701110.1021/acsami.0c17011 ↗
32. H.-C. Huang, M. Kim, X. Zhan, K. Chabak, J.D. Kim, A. Kvit, D. Liu, Z. Ma, J.-M. Zuo, X. Li, High aspect ratio β-Ga2O3 fin arrays with low-interface charge density by inverse metal-assisted chemical etching. ACS Nano 13, 8784 (2019). https://doi.org/10.1021/acsnano.9b0170910.1021/acsnano.9b01709 ↗
33. Y. Zhang, A. Mauze, J. Speck, Anisotropic etching of β-Ga2O3 using hot phosphoric acid. Appl. Phys. Lett. 115(1), 013501 (2019). https://doi.org/10.1063/1.509318810.1063/1.5093188 ↗
34. S.J. Pearton, J. Yang, P.H. Cary, F. Ren, J. Kim, M.J. Tadjer, M.A. Mastro, A review of Ga2O3 materials, processing, and devices. Appl. Phys. Rev. 5, 11301 (2018). https://doi.org/10.1063/1.500694110.1063/1.5006941 ↗
35. P.K. Mohseni, S. Hyun Kim, X. Zhao, K. Balasundaram, J. Dong Kim, L. Pan, J.A. Rogers, J.J. Coleman, X. Li, GaAs pillar array-based light emitting diodes fabricated by metal-assisted chemical etching. J. Appl. Phys. 114(6), 064909 (2013). https://doi.org/10.1063/1.481742410.1063/1.4817424 ↗
36. S. Jang, S. Jung, K. Beers, J. Yang, F. Ren, A. Kuramata, S.J. Pearton, K.H. Baik, A comparative study of wet etching and contacts on (-201) and (010) oriented β-Ga2O3. J. Alloys Compd. 731, 118–125 (2018). https://doi.org/10.1016/J.JALLCOM.2017.09.33610.1016/J.JALLCOM.2017.09.336 ↗
37. X. Geng, B.K. Duan, D.A. Grismer, L. Zhao, P.W. Bohn, Monodisperse GaN nanowires prepared by metal-assisted chemical etching with in situ catalyst deposition. Electrochem. Commun. 19(1), 39–42 (2012). https://doi.org/10.1016/j.elecom.2012.03.01110.1016/j.elecom.2012.03.011 ↗
38. K.C. Wang, G.D. Yuan, R.W. Wu, H.X. Lu, Z.Q. Liu, T.B. Wei, J.X. Wang, J.M. Li, W.J. Zhang, GaN nanowire arrays by a patterned metal-assisted chemical etching. J. Cryst. Growth 440, 96–101 (2016). https://doi.org/10.1016/j.jcrysgro.2016.01.01710.1016/j.jcrysgro.2016.01.017 ↗
39. D.M. Dryden, R.J. Nikolic, M.S. Islam, Photogalvanic etching of N-GaN for three-dimensional electronics. J. Electron. Mater. 48(5), 3345–3350 (2019). https://doi.org/10.1007/s11664-019-06982-510.1007/s11664-019-06982-5 ↗
40. C.Y. Chan, S. Namiki, J.K. Hite, X. Li, Photoinduced open-circuit metal-assisted chemical etching of homoepitaxial GaN. In 2021 Compound Semicondutor Week (2021).
41. X. Li, Y. Kim, P. Bohn, I. Adesida, In-plane bandgap control in porous GaN through electroless wet chemical etching. Appl. Phys. Lett. 80(6), 980–982 (2002). https://doi.org/10.1063/1.144886010.1063/1.1448860 ↗
42. H.-C. Huang, Z. Ren, A. Green, K. Chabak, X. Li, Metal-assisted chemical etching of (001) β-Ga2O3, in 2021 Compound Semicondutor Week (2021)
43. S. Ohira, N. Arai, Wet chemical etching behavior of β-Ga2O3 single crystal. Phys. Status Solidi 5(9), 3116–3118 (2008). https://doi.org/10.1002/pssc.20077922310.1002/pssc.200779223 ↗
44. M.L. Schnoes, G.J. Zydzik, A Ga2O3 films for electronic and optoelectronic applications. J. Appl. Phys. 686(1), 686–693 (2018)
45. T. Oshima, T. Okuno, N. Arai, Y. Kobayashi, S. Fujita, Wet etching of β-Ga2O3 substrates. Jpn. J. Appl. Phys. 48(4), 1–4 (2009). https://doi.org/10.1143/JJAP.48.04020810.1143/JJAP.48.040208 ↗
46. F. Ren, M. Hong, J.P. Mannaerts, J.R. Lothian, A.Y. Cho, Wet chemical and plasma etching of Ga2O3(Gd2O3). J. Electrochem. Soc. 144(9), 239–241 (1997)10.1149/1.1837929 ↗
47. M.G.S.O. Mesfets, G.T. Dang, T. Kawaharamura, M. Furuta, M.W. Allen, Mist-CVD grown Sn-doped. IEEE Trans. Electrons Dev. 62(11), 3640–3644 (2015)10.1109/TED.2015.2477438 ↗
48. Y. Yao, Y. Ishikawa, Y. Sugawara, Revelation of dislocations in β-Ga2O3 substrates grown by edge-defined film-fed growth. Phys. Status Solidi Appl. Mater. Sci. 217(3), 2–7 (2020). https://doi.org/10.1002/pssa.20190063010.1002/pssa.201900630 ↗
49. B. Alhalaili, R. Vidu, H. Mao, O. Kamoun, M. Saif Islam, Photoelectrochemical (PEC) etching of Ga2O3. Ceram. Int. 47(1), 479–486 (2021). https://doi.org/10.1016/j.ceramint.2020.08.15510.1016/j.ceramint.2020.08.155 ↗
50. S.L. Ou, D.S. Wuu, Y.C. Fu, S.P. Liu, R.H. Horng, L. Liu, Z.C. Feng, Growth and etching characteristics of gallium oxide thin films by pulsed laser deposition. Mater. Chem. Phys. 133(2–3), 700–705 (2012). https://doi.org/10.1016/j.matchemphys.2012.01.06010.1016/j.matchemphys.2012.01.060 ↗
51. Y.H. Choi, K.H. Baik, S. Kim, J. Kim, Photoelectrochemical etching of ultra-wide bandgap β-Ga2O3 semiconductor in phosphoric acid and its optoelectronic device application. Appl. Surf. Sci. 539, 148130 (2021). https://doi.org/10.1016/j.apsusc.2020.14813010.1016/j.apsusc.2020.148130 ↗
52. J.E. Hogan, S.W. Kaun, E. Ahmadi, Y. Oshima, J.S. Speck, Chlorine-based dry etching of β-Ga2O3 To. Semicond. Sci. Technol. (2016). https://doi.org/10.1016/S0169-4332(01)00593-110.1016/S0169-4332(01)00593-1 ↗
53. J. Yang, S. Ahn, F. Ren, S. Pearton, R. Khanna, K. Bevlin, D. Geerpuram, A. Kuramata, Inductively coupled plasma etching of bulk, single-crystal Ga2O3. J. Vac. Sci. Technol. B 35(3), 031205 (2017). https://doi.org/10.1116/1.498271410.1116/1.4982714 ↗
54. L. Zhang, A. Verma, H.G. Xing, D. Jena, Inductively-coupled-plasma reactive ion etching of single-crystal β-Ga2O3. Jpn. J. Appl. Phys. 56, 030304 (2017)10.7567/JJAP.56.030304 ↗
55. J. Yang, S. Ahn, F. Ren, R. Khanna, K. Bevlin, D. Geerpuram, S.J. Pearton, A. Kuramata, Inductively coupled plasma etch damage in (-201) Ga2O3 Schottky diodes. Appl. Phys. Lett. 110(14), 1–5 (2017). https://doi.org/10.1063/1.497959210.1063/1.4979592 ↗
56. J. Yang, F. Ren, R. Khanna, K. Bevlin, D. Geerpuram, L.-C. Tung, J. Lin, H. Jiang, J. Lee, E. Flitsiyan, L. Chernyak, S.J. Pearton, A. Kuramata, Annealing of dry etch damage in metallized and bare (-201) Ga2O3. J. Vac. Sci. Technol. B 35(5), 051201 (2017). https://doi.org/10.1116/1.498630010.1116/1.4986300 ↗
57. H.K. Lee, H.J. Yun, K.H. Shim, H.G. Park, T.H. Jang, S.N. Lee, C.J. Choi, Improvement of dry etch-induced surface roughness of single crystalline β-Ga2O3 using post-wet chemical treatments. Appl. Surf. Sci. 2020(506), 144673 (2019). https://doi.org/10.1016/j.apsusc.2019.14467310.1016/j.apsusc.2019.144673 ↗
58. H. Okumura, T. Tanaka, Dry and wet etching for β-Ga2O3 Schottky barrier diodes with mesa termination. Jpn. J. Appl. Phys. 58(12), 89 (2019). https://doi.org/10.7567/1347-4065/ab4f9010.7567/1347-4065/ab4f90 ↗
59. H. Liang, Y. Chen, X. Xia, C. Zhang, R. Shen, Y. Liu, Y. Luo, G. Du, A preliminary study of SF6 based inductively coupled plasma etching techniques for beta gallium trioxide thin film. Mater. Sci. Semicond. Process. 39, 582–586 (2015). https://doi.org/10.1016/j.mssp.2015.05.06510.1016/j.mssp.2015.05.065 ↗
60. Y. Kwon, G. Lee, S. Oh, J. Kim, S.J. Pearton, F. Ren, Tuning the thickness of exfoliated quasi-two-dimensional β-Ga2O3 flakes by plasma etching. Appl. Phys. Lett. 110(13), 89 (2017). https://doi.org/10.1063/1.497902810.1063/1.4979028 ↗
61. A.P. Shah, A. Bhattacharya, Inductively coupled plasma reactive-ion etching of β-Ga2O3: comprehensive investigation of plasma chemistry and temperature. J. Vac. Sci. Technol. 35(4), 041301 (2017). https://doi.org/10.1116/1.498307810.1116/1.4983078 ↗
62. R.J. Shul, S.J. Pearton, Handbook of Advanced Plasma Processing Techniques (Springer, Berlin, 2000)10.1007/978-3-642-56989-0 ↗
63. A.Y. Polyakov, I.H. Lee, N.B. Smirnov, E.B. Yakimov, I.V. Shchemerov, A.V. Chernykh, A.I. Kochkova, A.A. Vasilev, P.H. Carey, F. Ren, D.J. Smith, S.J. Pearton, Defects at the surface of β-Ga2O3 produced by Ar plasma exposure. APL Mater. (2019). https://doi.org/10.1063/1.510902510.1063/1.5109025 ↗
64. Z. Hu, K. Nomoto, W. Li, Z. Zhang, N. Tanen, Q.T. Thieu, K. Sasaki, A. Kuramata, T. Nakamura, D. Jena, H.G. Xing, Breakdown mechanism in 1 KA/Cm2 and 960 V E-mode β-Ga2O3 vertical transistors. Appl. Phys. Lett. 113(12), 122103 (2018). https://doi.org/10.1063/1.503810510.1063/1.5038105 ↗