journal article·2025

Possible gapless spin-liquid state in the Fe-based halide perovskite Cs 4 BiFeBr 10 derived from the antiferromagnet CsFeBr 4

Jie Pan, Yaru Zhang, Yixin Liu, Xin Mi, Fuyang Liu, Yuqiang Fang, Binbin Zhou, Peizhi Yang, Gang Mu, Peng Qin, Fuqiang Huang

Journal of Materials Chemistry C· Volume 13· Issue 17
Publisher page

Abstract

CsFeBr 4 possesses antiferromagnetic Fe–Fe zigzag chains with a T N of 12 K. Insertion of Bi atoms into the lattice induced long-range magnetic frustration appeared in Cs 4 BiFeBr 10 with the possible gapless spin-liquid ground state at low temperature.
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Research context

OpenAlex topics: Perovskite Materials and Applications · Solid-state spectroscopy and crystallography · Advanced Condensed Matter Physics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Flexible Electronics (Future Technologies), Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, 211816 Nanjing, China

State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 200050 Shanghai, China

Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

National Key Laboratory of Materials for Integrated Circuits, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

Center for High Pressure Science and Technology Advanced Research (HPSTAR), Beijing, 100193, China

Shenzhen Institute of Advanced Electronic Materials, Shenzhen Institute of Advanced Technology Chinese Academy of Sciences, Shenzhen 518055, China

Key Laboratory of Renewable Energy Advanced Materials and Manufacturing Technology, Ministry of Education, Yunnan Normal University, Kunming, 650500, Yunnan, China

State Key Lab of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Dongchuan Road 800, 200240 Shanghai, China

Funding

National Natural Science Foundation of China · Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions · Chinese Academy of Sciences

References (35)

Show source-provided references
1. Manser · Chem. Rev. · 2016 · 116 · 1295610.1021/acs.chemrev.6b00136 ↗
2. Chouhan · Chem. Soc. Rev. · 2020 · 49 · 286910.1039/C9CS00848A ↗
3. He · Light: Sci. Appl. · 2023 · 12 · 1510.1038/s41377-022-01010-4 ↗
4. Liu · Adv. Funct. Mater. · 2022 · 32 · 210989110.1002/adfm.202109891 ↗
5. Puttisong · J. Phys. Chem. Lett. · 2020 · 11 · 487310.1021/acs.jpclett.0c01543 ↗
6. Ning · Sci. Adv. · 2020 · 6 · eabb538110.1126/sciadv.abb5381 ↗
7. Nafradi · Nat. Commun. · 2016 · 7 · 1340610.1038/ncomms13406 ↗
8. He · CCS Chem. · 2023 · 5 · 196110.31635/ccschem.023.202303019 ↗
9. Essaoud · Chem. Phys. Lett. · 2024 · 850 · 14145510.1016/j.cplett.2024.141455 ↗
10. Kurita · Phys. Rev. B · 2016 · 94 · 10440910.1103/PhysRevB.94.104409 ↗
11. Tanaka · J. Phys. Soc. Jpn. · 2001 · 70 · 306810.1143/JPSJ.70.3068 ↗
12. Kurita · J. Phys. Conf. Ser. · 2017 · 828 · 01200210.1088/1742-6596/828/1/012002 ↗
13. Wei · J. Mater. Chem. C · 2018 · 6 · 357310.1039/C7TC04798C ↗
14. Xue · Chem. Mater. · 2022 · 34 · 281310.1021/acs.chemmater.2c00163 ↗
15. Baek · Phys. Rev. Lett. · 2017 · 119 · 03720110.1103/PhysRevLett.119.037201 ↗
16. Tokiwa · Phys. Rev. B: Condens. Matter Mater. Phys. · 2006 · 73 · 13441410.1103/PhysRevB.73.134414 ↗
17. Ramirez · Annu. Rev. Mater. Sci. · 1994 · 24 · 45310.1146/annurev.ms.24.080194.002321 ↗
18. Aczel · Phys. Rev. B: Condens. Matter Mater. Phys. · 2014 · 90 · 13440310.1103/PhysRevB.90.134403 ↗
19. Jiang · Phys. Rev. Lett. · 2021 · 127 · 09700210.1103/PhysRevLett.127.097002 ↗
20. Banerjee · npj Quantum Mater. · 2018 · 3 · 810.1038/s41535-018-0079-2 ↗
21. Balents · Nature · 2010 · 464 · 19910.1038/nature08917 ↗
22. Greedan · J. Alloys Compd. · 2006 · 408 · 44410.1016/j.jallcom.2004.12.084 ↗
23. Xing · Acs Mater. Lett. · 2020 · 2 · 7110.1021/acsmaterialslett.9b00464 ↗
24. Usman · Cryst. Growth Des. · 2021 · 21 · 57910.1021/acs.cgd.0c01397 ↗
25. Thiele · Z. Anorg. Allg. Chem. · 1992 · 616 · 19510.1002/zaac.19926161032 ↗
26. Zhang · Inorg. Chem. · 2020 · 59 · 537710.1021/acs.inorgchem.9b03592 ↗
27. Mugiraneza · Commun. Phys. · 2022 · 5 · 9510.1038/s42005-022-00853-y ↗
28. Wang · Phys. Rev. Lett. · 2018 · 120 · 20720510.1103/PhysRevLett.120.207205 ↗
29. Yamashita · Nat. Commun. · 2011 · 2 · 27510.1038/ncomms1274 ↗
30. Yamashita · Nat. Phys. · 2008 · 4 · 45910.1038/nphys942 ↗
31. Okamoto · Phys. Rev. Lett. · 2007 · 99 · 13720710.1103/PhysRevLett.99.137207 ↗
32. Li · Sci. Rep. · 2015 · 5 · 1641910.1038/srep16419 ↗
33. Nakatsuji · Science · 2005 · 309 · 169710.1126/science.1114727 ↗
34. Ramirez · Phys. Rev. Lett. · 2000 · 84 · 295710.1103/PhysRevLett.84.2957 ↗
35. Turnbull · Coord. Chem. Rev. · 2005 · 249 · 256710.1016/j.ccr.2005.01.015 ↗