journal article·2017

Superexchange interactions between Fe-3d and Ln-4f states: long range antiferromagnetism in perovskite derivatives Ba 3 LnFe 2 O 7.5

Asish K. Kundu, Vincent Caignaert, Vincent Hardy, Bernard Raveau

Journal of Materials Chemistry C· Volume 5· Issue 29
Publisher page

Abstract

Perovskite derivatives Ba 3 LnFe 2 O 7.5 can be described as an assemblage of double “FeLn” chains of isolated FeO 4 tetrahedrons and YO 6 octahedrons, interconnected through dimeric tetrahedral Fe 2 O 7 groups. Long range antiferromagnetic ordering, with T N ranging from 6.2 K for Y to 12.5 K for Dy, is observed in spite of the isolated character of iron.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Multiferroics and related materials · Advanced Condensed Matter Physics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Discipline of Physics

Indian Institute of Information Technology

Design & Manufacturing Jabalpur

Madhya Pradesh–482005

India

Laboratoire CRISMAT

CNRS ENSICAEN UMR6508

Cedex 4

France

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