Magnetic and charge ordering properties of Bi0.6−xEuxCa0.4MnO3 (0.0≤x≤0.6)

Abstract We have studied structure, magnetic and transport properties of polycrystalline Bi 0.6− x Eu x Ca 0.4 MnO 3 ( x =0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6) perovskite manganites. Magnetic measurements show that the charge-ordering temperature ( T CO ) decreases with increasing x up to x =0.4 and then slightly increases with further increasing x up to x =0.6. Further, the antiferromagnetic (AFM) ordering temperature ( T N ) decreases with increasing x . At T T N a transition to metamagnetic glass like state is also seen. Eu doping also leads to enhancement in the magnetic moment and a concomitant decrease in resistivity up to x =0.2 and then an increase in resistivity up to x =0.5. We propose that the local lattice distortion induced by the size mismatch between the A-site cations and 6s 2 character of Bi 3+ lone pair electron are responsible for the observed variation in physical properties.