In Situ Optical Observation of Lithium Dendrite Pattern in Solid Polymer Electrolytes

Abstract Solid polymer electrolytes (SPEs) have been treated as a viable solution to build high‐performance solid‐state lithium metal batteries (SSLMBs) at the industrial level, bypassing the safety and energy density dilemmas experienced by today's lithium‐ion battery technology. To promote a wider application of SPEs‐based SSLMBs, the chemical and electrochemical characteristics of lithium metal (Li°) electrode in SPEs have to be clearly elucidated. In this work, the morphological evolution of Li° electrode in the SPEs‐based SSLMBs is comprehensively investigated, via a customized electrochemical cell allowing optical microscopic analyses. The results demonstrate that differing from inorganic solid electrolytes, the elastic feature of SPEs eliminates the “memory effect” of the dendrite formation, in which the previously formed dendrites can be dissolved and the resulting space can be simultaneously occupied by electrolyte components, instead of leaving for a second‐round growth of Li° dendrites. Furthermore, the largely increased electronic conductivities of the as‐formed interphases between Li° electrode and SPEs are found to be responsible for the notoriously soft short‐circuit behavior observed during cycling. These findings bring a fresh understanding of the formation and evolution of lithium dendrites in SPE‐based cells, which are vital for improving the long‐term stability of SSLMBs and other related high‐energy battery systems.