journal article·2020-04-01

Fabrication of Cu 2 O/Si nanowires photocathode and its photoelectrochemical properties

Yun Hu, Yufeng Luo, Shaohuan Liu, Fayun Zhang, Senlin Rao, Fahui Wang, Yunming Li, Shuigen Li, Wei Zhong

Publisher page

Abstract

Abstract Using a simple dipping method, Cu 2 O nanoparticles were successfully deposited on the surface and the sidewall of silicon nanowires (Si NWs). As a photocathode, the Cu 2 O/Si NWs composites not only show a low reflectance of 10.75% in the 300–900 nm wavelength range, but also can enhance the separation of the photogenerated electron–hole pairs due to the junction formed by Cu 2 O and Si NWs. The Cu 2 O/Si NWs-20 min photocathode achieved a photocurrent of 3.5 mA cm −2 at −0.8 V versus AgCl/Ag and a photoconversion efficiency of 1.2%.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Copper-based nanomaterials and applications · Electronic and Structural Properties of Oxides · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (39)

Show source-provided references
1. Photocatalytic hydrogen generation using metal-decorated TiO2: sacrificial donors vs true water Splitting10.1021/acsenergylett.8b00152 ↗
2. TiO2 nanofibers coated with rGO and Ag2O for promoting visible light photocatalytic performance10.1088/1361-6641/aa5246 ↗
3. Enhanced H2 production in water splitting with CdS–ZnO core–shell nanowires10.1016/j.nanoen.2017.11.048 ↗
4. Hydrogen production from water splitting: fabrication of ZnO nanorod decorated Cu NW heterogeneous hybrid structures for photocatalytic applications10.1007/s10876-019-01504-z ↗
5. Reduced graphene oxide/silicon nanowire hetero- structures with enhanced photoactivity and superior photoelectrochemical stability10.1007/s12274-015-0790-2 ↗
6. Aligned single-crystalline Si nanowire arrays for photovoltaic applications10.1002/smll.200500137 ↗
7. Wireless solar water splitting using silicon-based semiconductors and earth-abundant catalysts10.1126/science.1209816 ↗
8. Silicon/hematite core/shell nanowire array decorated with gold nanoparticles for unbiased solar water oxidation10.1021/nl402205f ↗
9. Strong light absorption capability directed by structured profile of vertical Si nanowires10.1016/j.optmat.2017.08.049 ↗
10. A structured macroporous silicon/graphene heterojunction for efficient photoconversion10.1002/anie.200907173 ↗
11. Enhanced photoelectrochemical hydrogen production using silicon nanowires@MoS310.1016/j.nanoen.2013.06.016 ↗
12. More than 10% efficiency and one-week stability of Si photocathodes for water splitting by manipulating the loading of the Pt catalyst and TiO2 protective layer10.1039/C7TA04986B ↗
13. Hierarchical carbon–silicon nanowire heterostructures for hydrogen evolution reaction10.1039/C8NR02262C ↗
14. Tunable electrodeposition of Ni electrocatalysts onto Si microwires array for photoelectrochemical water oxidation10.1002/ppsc.201700321 ↗
15. Enhancing electrochemical hydrogen generation by platinum-modification of p-type silicon wires array under visible light10.1149/2.0361409jes ↗
16. Impact of surface morphology of Si substrate on performance of Si/ZnO heterojunction devices grown by atomic layer deposition technique10.1116/1.4900719 ↗
17. Core–shell photoanode developed by atomic layer deposition of Bi2O3 on Si nanowires for enhanced photoelectrochemical water splitting10.1088/0957-4484/25/45/455402 ↗
18. Enhanced photoelectrochemical performance of planar p-Silicon by APCVD deposition of surface mesoporous hematite coating10.1016/j.apcatb.2016.07.031 ↗
19. High efficiencyn-Si/p-Cu2O core–shell nanowires photodiode prepared by atomic layer deposition of Cu2O on well-ordered Si nanowires array10.1007/s13391-016-5356-2 ↗
20. Positive onset potential and stability of Cu2O-based photocathodes in water splitting by atomic layer deposition of a Ga2O3 buffer layer10.1039/C5EE00250H ↗
21. Enhanced photocatalytic degradation of rhodamine B by Cu2O coated silicon nanowire arrays in presence of H2O210.1016/j.jmst.2014.03.023 ↗
22. Low-temperature, facile fabrication of ultrafine Cu2O networks by anodization on TiO2 nanotube arrays10.1088/0268-1242/27/10/105010 ↗
23. Silicon nanowire array/Cu2O crystalline core–shell nanosystem for solar-driven photocatalytic water splitting10.1088/0957-4484/24/26/265402 ↗
24. A facile fabrication of high-quality Si/Cu2O nanowire arrays for photoelectrochemical water splitting10.1016/j.matlet.2017.03.124 ↗
25. Photoelectrochemical hydrogen evolution using Si microwire arrays10.1021/ja108801m ↗
26. Metal-assisted chemical etching of silicon: a review10.1002/adma.201001784 ↗
27. Preparation of large-area uniform silicon nanowires arrays through metal-assisted chemical etching10.1021/jp077053o ↗
28. Enhanced photocatalytic degradation of methylene blue by metal-modified silicon nanowires10.1016/j.materresbull.2014.11.007 ↗
29. Enhancement of the tartrazine photodegradation by modification of silicon nanowires with metal nanoparticles10.1016/j.materresbull.2015.12.046 ↗
30. Strong light absorption capability directed by structured profile of vertical Si nanowires10.1016/j.optmat.2017.08.049 ↗
31. The photoelectric performances of TiO2, nanotube arrays-sensitized with organometallic complexes10.1080/00032719.2010.512680 ↗
32. Photosensitization of TiO2 nanostructures with CdS Quantum dots: particulate versus tubular support architectures10.1002/adfm.200801173 ↗
33. Enhanced photoelectrochemical hydrogen production from silicon nanowire array photocathode10.1021/nl203564s ↗
34. p-Si/SnO2/Fe2O3 core/shell/shell nanowire photocathodes for neutral pH water splitting10.1002/adfm.201404571 ↗
35. Photoelectrochemical hydrogen production of TiO2 passivated Pt/Si-nanowire composite photocathode10.1021/acsami.5b04936 ↗
36. Visible light photoelectrochemical and water-photoelectrolysis properties of titania nanotube arrays10.1016/j.jphotochem.2005.06.013 ↗
37. Tailoring n-ZnO/p-Si branched nanowire heterostructures for selective photoelectrochemical water oxidation or reduction10.1021/nl304539x ↗
38. Solar hydrogen generation by silicon nanowires modified with platinum nanoparticle catalysts by atomic layer deposition10.1002/anie.201303813 ↗
39. Stabilizing silicon photocathodes by solution-deposited Ni–Fe layered double hydroxide for efficient hydrogen evolution in alkaline media10.1021/acsenergylett.7b00597 ↗