journal article·2022-10

A nano-liter droplet-based microfluidic reactor serves as continuous large-scale production of inorganic perovskite nanocrystals

Yuhao Geng, Jiazhuang Guo, Si Da Ling, Xingjiang Wu, Hengyuan Liu, Zhuo Chen, Su Chen, Jianhong Xu

Science China Materials· Volume 65· Issue 10
Publisher page

Abstract

铅卤钙钛矿纳米晶具有高光致发光量子产率、窄半峰宽和广发光色域的优势, 是众多领域中的理想光电材料. 但釜式制备方法无法实现规模化制备, 限制了钙钛矿纳米晶的市场化应用. 本文设计了一种液滴流微反应器, 为大规模合成高量子产率的钙钛矿纳米晶提供了新方法. 该装置可精确控制纳米晶在130 nL液滴内的生长过程. 与其他合成方法相比, 可以将前驱体浓度提高到文献水平的3–116倍, 将配体与反应物比例降低到热注入法的2%–50%. 通过改变反应温度和停留时间, 探究了纳米晶形貌和光致发光性质之间的构效关系. 此外, 通过在线调整PbX2比例, 可实现单次反应内制备全可见光谱(406–677 nm)发光的纳米晶.
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Research context

OpenAlex topics: Perovskite Materials and Applications · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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