journal article·2023-01Open access

Controllable volatile-to-nonvolatile memristive switching in single-crystal lead-free double perovskite with ultralow switching electric field

Qi You, Fu Huang, Feier Fang, Jiaqi Zhu, Yue Zheng, Shaofan Fang, Bo Zhou, Henan Li, Cheng Han, Yumeng Shi

Science China Materials· Volume 66· Issue 1

Abstract

全无机无铅双钙钛矿由于其优异的电子传输能力、高光敏性、 低毒性和环境稳定性, 为电子/光电存储器件提供了潜在的材料. 然而, 钙钛矿薄膜的多晶性质严重限制了器件性能. 在此, 我们展示了一种基 于单晶双钙钛矿Cs2AgBiBr6的高性能忆阻器, 其具有6.67 × 104 V m−1的 超低开关电场和107的高电流开/关比. 值得注意的是, Cs2AgBiBr6的电 阻开关行为与单晶钙钛矿的厚度相关, 当单晶厚度从100到800 nm变化 时, 忆阻器从易失性的阈值开关行为演变为非易失性的忆阻开关行为. 元素分析表明, Cs2AgBiBr6中导电通道的形成与具有低活化能Br空位 的迁移有关. 此外, 形成的导电通道可以被具有不同波长和强度的光照 湮灭, 从而实现具有单独的电写入和光擦除的光电存储器. 我们的研究 结果为单晶钙钛矿中的离子迁移提供了深刻的见解, 并为其在未来的 电子和光电存储器中的应用提供了理论基础.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Perovskite Materials and Applications · Advanced Memory and Neural Computing · Transition Metal Oxide Nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (50)

Show source-provided references
1. Burr GW, Shelby RM, Sebastian A, et al. Neuromorphic computing using non-volatile memory. Adv Phys-X, 2017, 2: 89–124
2. Kwon DH, Kim KM, Jang JH, et al. Atomic structure of conducting nanofilaments in TiO2 resistive switching memory. Nat Nanotech, 2010, 5: 148–15310.1038/nnano.2009.456 ↗
3. Yu S, Guan X, Wong HSP. Conduction mechanism of TiN/HfOx/Pt resistive switching memory: A trap-assisted-tunneling model. Appl Phys Lett, 2011, 99: 06350710.1063/1.3624472 ↗
4. Lee MJ, Lee CB, Lee D, et al. A fast, high-endurance and scalable nonvolatile memory device made from asymmetric Ta2O5−x/TaO2−x bilayer structures. Nat Mater, 2011, 10: 625–63010.1038/nmat3070 ↗
5. Lee SM, Kim H, Kim DH, et al. Tailored 2D/3D halide perovskite heterointerface for substantially enhanced endurance in conducting bridge resistive switching memory. ACS Appl Mater Interfaces, 2020, 12: 17039–1704510.1021/acsami.9b22918 ↗
6. Choi J, Park S, Lee J, et al. Organolead halide perovskites for low operating voltage multilevel resistive switching. Adv Mater, 2016, 28: 6562–656710.1002/adma.201600859 ↗
7. Gu C, Lee JS. Flexible hybrid organic-inorganic perovskite memory. ACS Nano, 2016, 10: 5413–541810.1021/acsnano.6b01643 ↗
8. Green MA, Ho-Baillie A, Snaith HJ. The emergence of perovskite solar cells. Nat Photon, 2014, 8: 506–51410.1038/nphoton.2014.134 ↗
9. Heo JH, Han HJ, Kim D, et al. Hysteresis-less inverted CH3NH3PbI3 planar perovskite hybrid solar cells with 18.1% power conversion efficiency. Energy Environ Sci, 2015, 8: 1602–160810.1039/C5EE00120J ↗
10. Shin SS, Yeom EJ, Yang WS, et al. Colloidally prepared La-doped BaSnO3 electrodes for efficient, photostable perovskite solar cells. Science, 2017, 356: 167–17110.1126/science.aam6620 ↗
11. Dou L, Yang YM, You J, et al. Solution-processed hybrid perovskite photodetectors with high detectivity. Nat Commun, 2014, 5: 540410.1038/ncomms6404 ↗
12. Gu L, Tavakoli MM, Zhang D, et al. 3D arrays of 1024-pixel image sensors based on lead halide perovskite nanowires. Adv Mater, 2016, 28: 9713–972110.1002/adma.201601603 ↗
13. Lian Z, Yan Q, Lv Q, et al. High-performance planar-type photodetector on (100) facet of MAPbI3 single crystal. Sci Rep, 2015, 5: 1656310.1038/srep16563 ↗
14. Cho H, Jeong SH, Park MH, et al. Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes. Science, 2015, 350: 1222–122510.1126/science.aad1818 ↗
15. Zhu H, Fu Y, Meng F, et al. Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors. Nat Mater, 2015, 14: 636–64210.1038/nmat4271 ↗
16. Zhu X, Lee J, Lu WD. Iodine vacancy redistribution in organic-inorganic halide perovskite films and resistive switching effects. Adv Mater, 2017, 29: 170052710.1002/adma.201700527 ↗
17. Azpiroz JM, Mosconi E, Bisquert J, et al. Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation. Energy Environ Sci, 2015, 8: 2118–212710.1039/C5EE01265A ↗
18. Game OS, Buchsbaum GJ, Zhou Y, et al. Ions matter: Description of the anomalous electronic behavior in methylammonium lead halide perovskite devices. Adv Funct Mater, 2017, 27: 160658410.1002/adfm.201606584 ↗
19. Zhao XG, Yang D, Sun Y, et al. Cu-In halide perovskite solar absorbers. J Am Chem Soc, 2017, 139: 6718–672510.1021/jacs.7b02120 ↗
20. Zhao XG, Yang JH, Fu Y, et al. Design of lead-free inorganic halide perovskites for solar cells via cation-transmutation. J Am Chem Soc, 2017, 139: 2630–263810.1021/jacs.6b09645 ↗
21. Lei H, Hardy D, Gao F. Lead-free double perovskite Cs2AgBiBr6: Fundamentals, applications, and perspectives. Adv Funct Mater, 2021, 31: 210589810.1002/adfm.202105898 ↗
22. Igbari F, Wang ZK, Liao LS. Progress of lead-free halide double perovskites. Adv Energy Mater, 2019, 9: 180315010.1002/aenm.201803150 ↗
23. Yin L, Wu H, Pan W, et al. Controlled cooling for synthesis of Cs2AgBiBr6 single crystals and its application for X-ray detection. Adv Opt Mater, 2019, 7: 190049110.1002/adom.201900491 ↗
24. Zhang Z, Liang Y, Huang H, et al. Stable and highly efficient photocatalysis with lead-free double-perovskite of Cs2AgBiBr6. Angew Chem Int Ed, 2019, 58: 7263–726710.1002/anie.201900658 ↗
25. Yang J, Bao C, Ning W, et al. Stable, high-sensitivity and fast-response photodetectors based on lead-free Cs2AgBiBr6 double perovskite films. Adv Opt Mater, 2019, 7: 180173210.1002/adom.201801732 ↗
26. Cheng XF, Qian WH, Wang J, et al. Environmentally robust memristor enabled by lead-free double perovskite for high-performance information storage. Small, 2019, 15: 190573110.1002/smll.201905731 ↗
27. Lao J, Xu W, Jiang C, et al. An air-stable artificial synapse based on a lead-free double perovskite Cs2AgBiBr6 film for neuromorphic computing. J Mater Chem C, 2021, 9: 5706–571210.1039/D1TC00655J ↗
28. Mao JY, Zheng Z, Xiong ZY, et al. Lead-free monocrystalline perovskite resistive switching device for temporal information processing. Nano Energy, 2020, 71: 10461610.1016/j.nanoen.2020.104616 ↗
29. Fang F, Li H, Fang S, et al. 2D Cs2AgBiBr6 with boosted light-matter interaction for high-performance photodetectors. Adv Opt Mater, 2021, 9: 200193010.1002/adom.202001930 ↗
30. Yang X, Zhou B, Liu C, et al. Unravelling a solution-based formation of single-crystalline kinked wurtzite nanowires: The case of MnSe. Nano Res, 2017, 10: 2311–232010.1007/s12274-017-1424-7 ↗
31. Ning W, Zhao XG, Klarbring J, et al. Thermochromic lead-free halide double perovskites. Adv Funct Mater, 2019, 29: 180737510.1002/adfm.201807375 ↗
32. Bousoulas P, Panagopoulou M, Boukos N, et al. Emulating artificial neuron and synaptic properties with SiO2-based memristive devices by tuning threshold and bipolar switching effects. J Phys D-Appl Phys, 2021, 54: 22530310.1088/1361-6463/abea3b ↗
33. Wang K, Hu Q, Gao B, et al. Threshold switching memristor-based stochastic neurons for probabilistic computing. Mater Horiz, 2021, 8: 619–62910.1039/D0MH01759K ↗
34. Wang J, Lv Z, Xing X, et al. Optically modulated threshold switching in core-shell quantum dot based memristive device. Adv Funct Mater, 2020, 30: 190911410.1002/adfm.201909114 ↗
35. Zhang C, Shang J, Xue W, et al. Convertible resistive switching characteristics between memory switching and threshold switching in a single ferritin-based memristor. Chem Commun, 2016, 52: 4828–483110.1039/C6CC00989A ↗
36. Seo JY, Choi J, Kim HS, et al. Wafer-scale reliable switching memory based on 2-dimensional layered organic-inorganic halide perovskite. Nanoscale, 2017, 9: 15278–1528510.1039/C7NR05582J ↗
37. Xu Z, Liu Z, Huang Y, et al. To probe the performance of perovskite memory devices: Defects property and hysteresis. J Mater Chem C, 2017, 5: 5810–581710.1039/C7TC00266A ↗
38. Choi J, Le QV, Hong K, et al. Enhanced endurance organolead halide perovskite resistive switching memories operable under an extremely low bending radius. ACS Appl Mater Interfaces, 2017, 9: 30764–3077110.1021/acsami.7b08197 ↗
39. Han JS, Le QV, Choi J, et al. Air-stable cesium lead iodide perovskite for ultra-low operating voltage resistive switching. Adv Funct Mater, 2018, 28: 170578310.1002/adfm.201705783 ↗
40. Yang JM, Choi ES, Kim SY, et al. Perovskite-related (CH3NH3)3Sb2Br9 for forming-free memristor and low-energy-consuming neuromorphic computing. Nanoscale, 2019, 11: 6453–646110.1039/C8NR09918A ↗
41. Cuhadar C, Kim SG, Yang JM, et al. All-inorganic bismuth halide perovskite-like materials A3Bi2I9 and A3Bi1.8Na0.2I8.6 (A = Rb and Cs) for low-voltage switching resistive memory. ACS Appl Mater Interfaces, 2018, 10: 29741–2974910.1021/acsami.8b07103 ↗
42. Kim SG, Van Le Q, Han JS, et al. Dual-phase all-inorganic cesium halide perovskites for conducting-bridge memory-based artificial synapses. Adv Funct Mater, 2019, 29: 190668610.1002/adfm.201906686 ↗
43. Wang H, Du Y, Li Y, et al. Configurable resistive switching between memory and threshold characteristics for protein-based devices Adv Funct Mater, 2015, 25: 3825–383110.1002/adfm.201501389 ↗
44. Xue W, Liu G, Zhong Z, et al. A 1D vanadium dioxide nanochannel constructed via electric-field-induced ion transport and its superior metal-insulator transition. Adv Mater, 2017, 29: 170216210.1002/adma.201702162 ↗
45. Lee JH, Kim GH, Ahn YB, et al. Threshold switching in Si-As-Te thin film for the selector device of crossbar resistive memory Appl Phys Lett, 2012, 100: 12350510.1063/1.3696077 ↗
46. Song J, Prakash A, Lee D, et al. Bidirectional threshold switching in engineered multilayer (Cu2O/Ag:Cu2O/Cu2O) stack for cross-point selector application Appl Phys Lett, 2015, 107: 11350410.1063/1.4931136 ↗
47. Lee MJ, Lee D, Cho SH, et al. A plasma-treated chalcogenide switch device for stackable scalable 3D nanoscale memory Nat Commun, 2013, 4: 262910.1038/ncomms3629 ↗
48. Park J, Hadamek T, Posadas AB, et al. Multi-layered NiOy/NbOx/NiOy fast drift-free threshold switch with high Ion/Ioff ratio for selector application. Sci Rep, 2017, 7: 406810.1038/s41598-017-04529-4 ↗
49. Sun Y, Tai M, Song C, et al. Competition between metallic and vacancy defect conductive filaments in a CH3NH3PbI3-based memory device. J Phys Chem C, 2018, 122: 6431–643610.1021/acs.jpcc.7b12817 ↗
50. Ghasemi M, Zhang L, Yun JS, et al. Dual-ion-diffusion induced degradation in lead-free Cs2AgBiBr6 double perovskite solar cells. Adv Funct Mater, 2020, 30: 200234210.1002/adfm.202002342 ↗