journal article·2018-12-31Open access

Perovskite solar cells: must lead be replaced – and can it be done?

Qi Zhang, Feng Hao, Jianbao Li, Yangying Zhou, Yaxuan Wei, Hong Lin

Abstract

Perovskite solar cells have recently drawn significant attention for photovoltaic applications with a certified power conversion efficiency of more than 22%. Unfortunately, the toxicity of the dissolvable lead content in these materials presents a critical concern for future commercial development. This review outlines some criteria for the possible replacement of lead by less toxic elements, and highlights current research progress in the application of low-lead halide perovskites as optically active materials in solar cells. These criteria are discussed with the aim of developing a better understanding of the physio-chemical properties of perovskites and of realizing similar photovoltaic performance in perovskite materials either with or without lead. Some open questions and future development prospects are outlined for further advancing perovskite solar cells toward both low toxicity and high efficiency.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Solid-state spectroscopy and crystallography · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of New Ceramics & Fine Processing, School of Materials Science and Engineering, Tsinghua University , Beijing, China

School of Materials and Energy, University of Electronic Science and Technology of China , Chengdu, China

State Key Laboratory of Marine Resource Utilization in South China Sea, Materials and Chemical Engineering Institute, Hainan University , Haikou, China

Funding

FP7 International Cooperation · Israel Science Foundation · Ministry of Science & Technology, P. R. China: Sino-Italy International Cooperation on Innovation · Natural Science Foundations of China · the Projects of International Cooperation and exchanges NSFC · the Ministry of Science & Technology, P.R.China: Sino-Italy International Cooperation on Innovation · the Natural Science Foundations of China

References (100+)

Show source-provided references
1. 10.1126/science.122860410.1126/science.1228604 ↗
2. 10.1038/nature1234010.1038/nature12340 ↗
3. 10.1126/science.125405010.1126/science.1254050 ↗
4. Bai YB · Chin Sci Bull · 2016 · 61 · 48910.1360/N972015-00193 ↗
5. 10.1126/science.125476310.1126/science.1254763 ↗
6. 10.1088/1468-6996/16/3/03600410.1088/1468-6996/16/3/036004 ↗
7. 10.1002/adma.20160500510.1002/adma.201605005 ↗
8. 10.1039/C7TA00366H10.1039/C7TA00366H ↗
9. 10.1038/nature1413310.1038/nature14133 ↗
10. Best research-cell efficiencies. National Renewable Energy Laboratory (NREL). Available from: https://www.nrel.gov/pv/assets/images/efficiency-chart.png
11. 10.1080/14686996.2017.129897410.1080/14686996.2017.1298974 ↗
12. 10.1002/smll.20170095310.1002/smll.201700953 ↗
13. 10.1021/acsami.6b1337210.1021/acsami.6b13372 ↗
14. 10.1016/j.tsf.2015.11.00110.1016/j.tsf.2015.11.001 ↗
15. 10.1039/C5RA27434F10.1039/C5RA27434F ↗
16. 10.1039/C6TA01715 K10.1039/C6TA01715 K ↗
17. 10.1021/acsami.6b0052010.1021/acsami.6b00520 ↗
18. Dai XZ · ACS Appl Mater Interfaces · 2016 · 6 · 21156
19. 10.1039/C5TA02710A10.1039/C5TA02710A ↗
20. Assistance to newly arrived refugee children train the trainer presentation . Centers for disease control and prevention. Available from: https://www.cdc.gov/nceh/lead/publications/refugeetoolkit/powerpoint_files/medicalservice.ppt
21. 10.1107/S010876810803273410.1107/S0108768108032734 ↗
22. Perdew JP · J Phys Condens Mater · 1981 · 23 · 5048
23. 10.1103/PhysRev.136.B86410.1103/PhysRev.136.B864 ↗
24. 10.1088/0953-8984/21/39/39550210.1088/0953-8984/21/39/395502 ↗
25. 10.1103/PhysRevB.41.789210.1103/PhysRevB.41.7892 ↗
26. 10.1103/PhysRevB.43.199310.1103/PhysRevB.43.1993 ↗
27. 10.1103/PhysRevB.49.1425110.1103/PhysRevB.49.14251 ↗
28. 10.1103/PhysRevB.54.1116910.1103/PhysRevB.54.11169 ↗
29. 10.1016/0927-0256(96)00008-010.1016/0927-0256(96)00008-0 ↗
30. 10.1103/PhysRevLett.100.13640610.1103/PhysRevLett.100.136406 ↗
31. 10.1063/1.240466310.1063/1.2404663 ↗
32. 10.1103/PhysRevLett.77.386510.1103/PhysRevLett.77.3865 ↗
33. 10.1103/PhysRevB.50.1795310.1103/PhysRevB.50.17953 ↗
34. 10.1103/PhysRevB.73.04511210.1103/PhysRevB.73.045112 ↗
35. 10.1103/PhysRevLett.108.06870110.1103/PhysRevLett.108.068701 ↗
36. 10.1039/C4EE01076 K10.1039/C4EE01076 K ↗
37. 10.1039/C5TA05741H10.1039/C5TA05741H ↗
38. 10.1021/acs.chemmater.6b0322110.1021/acs.chemmater.6b03221 ↗
39. 10.1002/aelm.20150008910.1002/aelm.201500089 ↗
40. 10.1039/C5NR00041F10.1039/C5NR00041F ↗
41. 10.1021/acs.jpcc.5b1184510.1021/acs.jpcc.5b11845 ↗
42. 10.1016/j.progsolidstchem.2014.08.00110.1016/j.progsolidstchem.2014.08.001 ↗
43. 10.1107/S056774087200294810.1107/S0567740872002948 ↗
44. 10.1016/0022-2313(78)90026-110.1016/0022-2313(78)90026-1 ↗
45. 10.1016/0022-3697(90)90092-T10.1016/0022-3697(90)90092-T ↗
46. 10.1021/acs.jpclett.6b0037610.1021/acs.jpclett.6b00376 ↗
47. 10.1021/jacs.6b0964510.1021/jacs.6b09645 ↗
48. 10.1021/acsenergylett.6b0047110.1021/acsenergylett.6b00471 ↗
49. 10.1039/C6MH00053C10.1039/C6MH00053C ↗
50. 10.1080/00387010.2010.50585610.1080/00387010.2010.505856 ↗
51. 10.1016/j.cplett.2011.09.03310.1016/j.cplett.2011.09.033 ↗
52. 10.1016/j.jssc.2012.01.04710.1016/j.jssc.2012.01.047 ↗
53. 10.1088/0953-8984/14/36/30710.1088/0953-8984/14/36/307 ↗
54. 10.1088/0953-8984/18/26/03110.1088/0953-8984/18/26/031 ↗
55. 10.1021/acsenergylett.6b0049910.1021/acsenergylett.6b00499 ↗
56. 10.1021/acs.jpcc.5b0256110.1021/acs.jpcc.5b02561 ↗
57. 10.1126/science.aaf971710.1126/science.aaf9717 ↗
58. 10.1021/acs.chemmater.6b0305410.1021/acs.chemmater.6b03054 ↗
59. 10.1021/ic026147410.1021/ic0261474 ↗
60. 10.1038/nature1106710.1038/nature11067 ↗
61. 10.1021/cm503122j10.1021/cm503122j ↗
62. 10.1039/C5TA02950C10.1039/C5TA02950C ↗
63. 10.1107/S056774088000412810.1107/S0567740880004128 ↗
64. 10.1246/cl.1991.80110.1246/cl.1991.801 ↗
65. 10.1016/0022-4596(74)90088-710.1016/0022-4596(74)90088-7 ↗
66. 10.1021/ja301539s10.1021/ja301539s ↗
67. 10.1103/PhysRevB.77.23521410.1103/PhysRevB.77.235214 ↗
68. 10.1038/nenergy.2016.17810.1038/nenergy.2016.178 ↗
69. Marshall KP · J Phys Chem A · 2017 · 5 · 21836
70. 10.1038/nenergy.2015.710.1038/nenergy.2015.7 ↗
71. 10.1038/nenergy.2015.110.1038/nenergy.2015.1 ↗
72. 10.1002/adma.20140199110.1002/adma.201401991 ↗
73. 10.1039/C5RA22317B10.1039/C5RA22317B ↗
74. 10.1021/jp512662410.1021/jp5126624 ↗
75. 10.1021/jacs.5b1347010.1021/jacs.5b13470 ↗
76. 10.1002/adma.20160696410.1002/adma.201606964 ↗
77. 10.1002/aenm.20160113010.1002/aenm.201601130 ↗
78. 10.1021/ja508464w10.1021/ja508464w ↗
79. 10.1002/pssr.v10.810.1002/pssr.v10.8 ↗
80. 10.1016/j.solmat.2016.09.02210.1016/j.solmat.2016.09.022 ↗
81. 10.1021/jacs.5b0665810.1021/jacs.5b06658 ↗
82. 10.1021/jz500211710.1021/jz5002117 ↗
83. 10.1021/ja503325910.1021/ja5033259 ↗
84. 10.1039/C4TA06230B10.1039/C4TA06230B ↗
85. 10.1021/acs.jpclett.5b0173810.1021/acs.jpclett.5b01738 ↗
86. 10.1039/C5CP01991E10.1039/C5CP01991E ↗
87. 10.1038/nphoton.2014.8210.1038/nphoton.2014.82 ↗
88. 10.1002/adma.20140164110.1002/adma.201401641 ↗
89. 10.1039/C5RA21291 J10.1039/C5RA21291 J ↗
90. 10.1021/acs.jpclett.6b0011810.1021/acs.jpclett.6b00118 ↗
91. 10.1021/acs.jpclett.6b0032210.1021/acs.jpclett.6b00322 ↗
92. 10.1021/jacs.6b0925710.1021/jacs.6b09257 ↗
93. 10.1021/nl501299210.1021/nl5012992 ↗
94. 10.1021/jp411112 k10.1021/jp411112 k ↗
95. 10.1039/C5TA00190 K10.1039/C5TA00190 K ↗
96. 10.1021/jacs.6b0014210.1021/jacs.6b00142 ↗
97. 10.1002/adma.20160299210.1002/adma.201602992 ↗
98. 10.1002/adma.v28.4010.1002/adma.v28.40 ↗
99. 10.1007/s12274-016-1051-810.1007/s12274-016-1051-8 ↗
100. 10.1038/nature1830610.1038/nature18306 ↗