Organic Eu3+-complex-anchored porous diatomite channels enable UV protection and down conversion in hybrid material
Source abstract
Abstract
The organic Eu3+-complex [Eu(TTA)3Phen] has been incorporated into the channels of surface-modified frustules from diatoms as a key material to absorb and convert UV-photons to visible luminescence. Systematic investigation results indicate that the organic Eu3+-complex encapsulated in the functionalized diatomite channels exhibits enhanced luminescence and longer lifetime, owning to the Eu(TTA)3Phen complex interacting with its surrounding silylating agents. The organic Eu3+-complex-anchored porous diatomite hybrid luminescent material was compounded with polyethylene terephthalate (PET) by using a mini-twin screw extruder to prepare a self-supporting film of the hybrid material. Besides, the UV absorption properties of the composite films were investigated. These films will potentially be related to the UV protection of photovoltaic devices.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Radioactive element chemistry and processing · Lanthanide and Transition Metal Complexes · Chemical Synthesis and Characterization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Hybrid Materials, National Center of International Joint Research for Hybrid Materials Technology, National Base of International Sci. & Tech. Cooperation on Hybrid Materials, Qingdao University, Qingdao, P. R. China
Biomolecular and Organic Electronics, Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden
Funding
National Natural Science Foundation of China · State Key Project of International Cooperation Research · National High-End Foreign Expert of China
References (37)
Show source-provided references
1. 10.1007/s10570-019-02365-510.1007/s10570-019-02365-5 ↗
2. 10.1007/s10570-014-0367-310.1007/s10570-014-0367-3 ↗
3. 10.1021/acssuschemeng.6b0200310.1021/acssuschemeng.6b02003 ↗
4. 10.1038/s41467-019-10351-510.1038/s41467-019-10351-5 ↗
5. 10.1016/j.solmat.2011.08.00410.1016/j.solmat.2011.08.004 ↗
6. 10.1021/acsami.5b0825510.1021/acsami.5b08255 ↗
7. 10.1021/ic050317610.1021/ic0503176 ↗
8. 10.1002/app.2784610.1002/app.27846 ↗
9. 10.3390/nano1005094410.3390/nano10050944 ↗
10. 10.1016/j.colsurfa.2013.03.02110.1016/j.colsurfa.2013.03.021 ↗
11. 10.1007/s12221-018-7788-110.1007/s12221-018-7788-1 ↗
12. 10.1002/app.3061410.1002/app.30614 ↗
13. 10.1016/j.optmat.2017.11.02710.1016/j.optmat.2017.11.027 ↗
14. 10.1016/j.solmat.2015.09.03710.1016/j.solmat.2015.09.037 ↗
15. 10.1021/cr010309g10.1021/cr010309g ↗
16. 10.3390/nano1001008010.3390/nano10010080 ↗
17. 10.1021/acsami.5b0635010.1021/acsami.5b06350 ↗
18. 10.1007/s13204-019-01048-810.1007/s13204-019-01048-8 ↗
19. 10.1021/cr800398310.1021/cr8003983 ↗
20. 10.1039/C2CS35069F10.1039/C2CS35069F ↗
21. 10.1038/s41598-018-21810-210.1038/s41598-018-21810-2 ↗
22. 10.1039/C4DT00760C10.1039/C4DT00760C ↗
23. 10.1021/cm010223410.1021/cm0102234 ↗
24. 10.1039/b504707b10.1039/b504707b ↗
25. 10.1021/jp064509d10.1021/jp064509d ↗
26. 10.2217/nnm.11.2910.2217/nnm.11.29 ↗
27. 10.1021/acsami.5b0115910.1021/acsami.5b01159 ↗
28. 10.1002/adma.20170428910.1002/adma.201704289 ↗
29. 10.1021/la102083t10.1021/la102083t ↗
30. 10.1016/j.jenvman.2003.09.00510.1016/j.jenvman.2003.09.005 ↗
31. 10.1002/cplu.20150012810.1002/cplu.201500128 ↗
32. Canva M · Proc SPIE Int Soc Opt Eng · 1992 · 1758
33. 10.1039/JM996060051110.1039/JM9960600511 ↗
34. 10.1002/asia.20110056310.1002/asia.201100563 ↗
35. 10.1016/j.corsci.2017.09.01910.1016/j.corsci.2017.09.019 ↗
36. 10.1016/S0021-9673(01)83995-910.1016/S0021-9673(01)83995-9 ↗
37. 10.1016/j.jiec.2008.08.01010.1016/j.jiec.2008.08.010 ↗