Functional Transition Metal Perovskite Oxides with 6s2 Lone Pair Activity Stabilized by High-Pressure Synthesis
Source abstract
Abstract
Perovskite ABO3 oxides that have Bi and Pb at the A site and transition metals at the B site, when stabilized by high-pressure synthesis at several gigapascals, provide a rich parameter space of fascinating properties. Stereochemical 6 s2 lone pairs of Bi3+ and Pb2+ induce polar or antipolar distortions. 6 s2 and 6 s0 (Bi5+ and Pb4+) charge degree of freedom enable intermetallic charge transfer transitions. The structural distortion and the charge degree of freedom are coupled with magnetism of transition metals, resulting in various functionalities. In particular, we highlight magnetization reversal by electric field and polarization rotation in BiFe1− xCo xO3, negative thermal expansion in modified BiNiO3 and PbVO3, and systematic charge distribution changes in Pb MO3 ( M = 3 d transition metal).
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Research context
OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Multiferroics and related materials · Thermal Expansion and Ionic Conductivity
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Laboratory for Materials and Structures, Tokyo Institute of Technology, Yokohama, Kanagawa 226-8503, Japan;
Kanagawa Institute of Industrial Science and Technology, Ebina, Kanagawa 243-0435, Japan
Department of Advanced Materials Science and Engineering, Faculty of Engineering Sciences, Kyushu University, Kasuga 816-8580, Japan
Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, Higashiosaka, Osaka 577-8502, Japan
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai, Miyagi, 980-8577, Japan
Institute of Innovation Research, Tokyo Institute of Technology, Yokohama, Kanagawa 226-8503, Japan
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