journal article·2024-12

Controllable syntheses and magnetic and photoelectric properties modulations of CuFeS2 nanoplates

Ruixia Yang, Wenjiao Liu, Jinzhi Fu, Hui Zhang, Yanqing Hao, Yujia Li, Lanfang Wang, Fang Wang

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Abstract

As an antiferromagnetic material, chalcopyrite CuFeS 2 has both magnetic and semiconductor properties, which brings great prospects for the application of spintronics devices. Here, chalcopyrite CuFeS 2 nanoplates were successfully synthesized through a template mediated method. The CuFeS 2 exhibits a tetragonal phase while largely maintaining the hexagonal morphology of the CuS template, with particle sizes ranging between 90 and 120 nm. Specifically, the magnetic properties of CuFeS 2 can be tuned by varying the Fe content. The strong room-temperature ferromagnetism is attributed to the coexistence of the ferromagnetic Fe 7S 8 and the antiferromagnetic CuFeS 2, as well as to the unsaturated spin states of Fe on the surfaces of the nanoplates. Furthermore, the photoresponses of CuFeS 2 nanoplates were confirmed by I-V measurements under dark and light illumination. The stable photoresponse capability is attributed to its semiconductor properties. This novel room-temperature ferromagnetism and photoelectric effect promotes the development of CuFeS 2 nanoplates, and has great significance for the synthetic pathways of other ternary magnetic compounds.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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