Mechanical, thermal, and electrical properties of amine‐ and non‐functionalized reduced graphene oxide/epoxy carbon fiber‐reinforced polymers

Abstract Graphene and its related materials are increasingly applied in fiber‐reinforced polymers to tailor their material properties for high performance composites. Yet, the use of graphene derivatives that underwent a plasma functionalization process is not well understood. This study uses 1.50 wt.% of unfunctionalized (rGO) or plasma‐treated reduced graphene oxide with amine‐functionalities (frGO) in an epoxy matrix to prepare unidirectional pre‐impregnated carbon fibers. The material characteristics of the graphene‐modified carbon fiber‐reinforced polymers (g‐CFRP) are compared to the neat carbon fiber‐reinforced polymer (CFRP). Both g‐CFRP configurations exhibit a higher void content than the neat CFRP. No significant difference between the CFRP and the g‐CFRPs is observed with respect to the Young's modulus, glass transition temperature, storage modulus, specific heat capacity, thermal conductivity at room temperature, and in‐plane electrical conductivity. Yet, a reduction in ultimate tensile strength of up to −13% is noted. In addition, the apparent interlaminar shear strength and transverse electrical conductivity are increased by up to +12% for the rGO‐CFRP and +52% for the frGO‐CFRP. This knowledge will support the selection of additives for fiber‐reinforced polymers for, for example, lightning strike protection in aircrafts, sensory materials, electromagnetic interference shielding or heat transfer elements.