journal article·2022-11

Determination of Suitable Transport Layers in Light of Interface Defect States in MASnX3‐Based Perovskite Solar Cell

Muhammad Mottakin, Khan Sobayel, Rizalafande Che Ismail, Md. Shahiduzzaman, Ghulam Muhammad, Mohd Adib Ibrahim, Md. Akhtaruzzaman, Erajder Sabbir Hossain

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Abstract

Interface defects are crucial to improve the perovskite solar cell stability. This study investigates and determines the suitable electron transport layer (ETL) for Sn‐based perovskite solar cells. The investigation finds that carriers capture cross‐sectional area greatly impacts photovoltaic performance, and the optimum value is 1 × 10−25 cm2. A low trap density of 1012 does not play a significant role, but an interface defect density of 1017 located near the valence band edge at the ETL/absorber interface has the most detrimental effect. In structure, defect states (Et) near the valence band edge of PCBM/CH3NH3SnI3/NiO and WO3/CH3NH3SnI3/NiO devices have a higher destructive impact compared to TiO2/CH3NH3SnI3/NiO. The study also finds that absorber bulk defects and the interface defects in the ETL/absorber layer are the most sensitive to device performance. This detrimental impact on cell performance can be avoided by reducing the capture cross‐sectional area and maintaining a low trap density.
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Research context

OpenAlex topics: Perovskite Materials and Applications · Chalcogenide Semiconductor Thin Films · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Solar Energy Research Institute The National University of Malaysia Bangi 43600 Malaysia

Department of Applied Chemistry and Chemical Engineering Bangabandhu Sheikh Mujibur Rahman Science and Technology University Gopalganj 8100 Bangladesh

Faculty of Electronic Engineering Technology Universiti Malaysia Perlis Arau 02600 Malaysia

Nanomaterials Research Institute Kanazawa University Kakuma Kanazawa 920-1292 Japan

Department of Computer Engineering College of Computer and Information Sciences King Saud University Riyadh 11543 Saudi Arabia

Graduate School of Pure and Applied Sciences University of Tsukuba Tsukuba Ibaraki 305-8573 Japan

Department of Electrical and Electronic Engineering Dhaka University of Engineering University Gazipur 1707 Bangladesh

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